聚异丁烯高活性端基含量及相对分子质量测定方法的研究

综合使用核磁，VPO和近红外光谱分析技术对聚异丁烯活性端基含量以及相对分子质量的测定进行了详细研究，分别建立核测定聚异丁烯活性端基含量以及其他烯键含量和近红外光谱快速测量聚异聚丁烯活性端基含量。其他烯键含量和相对分子质量的分析方法。成对t检验结果表明，近红外光谱分析方法测定结果与核磁和VPO方法测定结果之间无显著性差异。     

空气中水含量的计算及其在色谱分析中的应用

本文介绍了空气中水含量的计算式并编制了空气中的水含量表。实验证明,表上的数据适用于色谱分析。     

Effect of carbon content on the microstructure and the cracking susceptibility of Fe-based laser-clad layer

The laser cladding of Fe-based alloys on a medium carbon steel substrate was performed using a CO₂ laser and Ar shielding gas that was blown into a molten pool. The microstructure and cracking susceptibility of the laser-clad layers were studied in terms of carbon additions. Results show that the small change of the carbon content in the alloy powders can obviously change the microstructure and properties of the layers. When the carbon content is in the range of 0.3–0.4 wt.%, the decrease of the carbon content in alloy powders will increase the hardness and toughness of the layers simultaneously under the same process parameters. As a result, crack-free coatings with high hardness can be obtained. As the carbon content increases from 0.2 wt.% to 0.4 wt.%, the segregation ratio of chromium increases, while the segregation ratios of nickel, manganese, and silicon first decrease and then increase. At the same time, a new designing principle concerning the composition and microstructure has been put forward, and the principal mechanisms of strengthening and toughening of the layers are fine-grain strengthening and low carbon martensitic phase transformation strengthening.     

Effect of External Acidity of Mordenite-Supported Catalysts on the 2,2-Dimethylbutane Content in Hydroisomerization Products of n-Hexane

We have used potentiometric titration with tetrabutylammonium hydroxide to determine the acid center content on the outer surface of dealuminated natural and synthetic mordenites. We have established a symbatic relationship between the 2,2-dimethylbutane content in the hydroisomerization products of n-hexane on dealuminated palladium-containing mordenites and the number of their external acid centers. We have studied the possibility of partial deactivation of such centers during ion-exchange deposition of palladium on the catalysts, using a tetraammine palladium solution.     

HPLC法测定阿奇霉素葡萄糖注射液中阿奇霉素的含量

利用高效液相色谱法，以VP-ODS型色谱柱，乙腈-异丙醇-水-氨水（60：25：15：0.1)为流动相，于210nm波长处测定了阿奇霉素葡萄糖注射液中阿奇霉素葡萄糖注射液中阿奇霉素的含量。阿奇霉素的浓度在0.75-1.75mg/mL线性关系良好，线性方程的A=881910.4c-16208.2，相关系数r=0.9999。阿奇霉素的平均回收率为99.59%，测定结果的相对标准偏差为1.31%。     

Time saving fluid dynamic predictions in a wetting-drying process: A hypothesis for vertisols

This paper is aimed at investigating the effect of the initial water content in a vertisol sample on the whole wetting-drying process leading the system to a change in volume. In order to do this, an experimental setup was realized and employed with very thin soil layers wetted from below (“per ascensum”). The results show that the effect of the initial water content on the swelling-shrinkage process is to shift the corresponding curve e-ϑ towards bigger-smaller values of the humidity but does not seem to affect the dynamics of the process. The text was submitted by the authors in English.     

慢速饮酒血液中酒精含量的数学模型

描述的是在一定时间内慢慢地匀速喝完一定数量酒的问题,并建立了相应的数学模型.同时也建立了快速饮酒的数学模型,以及证明了在各次饮酒后的某时刻酒精含量的可叠加性.     

Independence of the brittle–ductile transition from the rubber particle size for impact‐modified poly(vinyl chloride)

A series of acrylic impact modifiers (AIMs) with different particle sizes ranging from 55.2 to 927.0 nm were synthesized by seeded emulsion polymerization, and the effect of the particle size on the brittle–ductile transition of impact‐modified poly(vinyl chloride) (PVC) was investigated. For each AIM, a series of PVC/AIM blends with compositions of 6, 8, 10, 12, and 15 phr AIM in 100 phr PVC were prepared, and the Izod impact strengths of these blends were tested at 23 °C. For AIMs with particle sizes of 55.2, 59.8, 125.2, 243.2, and 341.1 nm, the blends fractured in the brittle mode when the concentration of AIM was lower than 10 phr, whereas the blends showed ductile fracture when the AIM concentration reached 10 phr. It was concluded that the brittle–ductile transition of the PVC/AIM blends was independent of the particle size in the range of 55.2–341.1 nm. When the particle size was greater than 341.1 nm, however, the brittle–ductile transition shifted to a higher AIM concentration with an increase in the particle size. Furthermore, the critical interparticle distance was found not to be the criterion of the brittle–ductile transition for the PVC/AIM blends. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 696–702, 2006     

Computation of moisture and temperature profiles in soil—The coupled model

The coupled model has been developed in this study for moisture transport and beat exchange in soil. The model is driven by atmospheric conditions measured in a field. The concept that soil has a surface resistance to evaporation is introduced in order to relate the evaporation from surface with the vapour flux in air. With the use of this concept, the simulation results agree quite well with the measured data.     

Photon interaction studies using 241Am γ-rays

We have carried out some photon interaction measurements using 59.54 keV γ-rays from a ²⁴¹Am source. These include γ attenuation studies as well as photoelectric absorption studies in various samples. The attenuation studies have been made using leaf and wood samples, samples like sand, sugar etc., which contain particles of varying sizes as well as pellets and aqueous solutions of rare earth compounds. In the case of the leaf and wood samples, we have used the γ-ray attenuation technique for the determination of the water content in fresh and dried samples. The variation of the attenuation coefficient with particle size has been investigated for sand and sugar samples. The attenuation studies as well as the photoelectric studies in the case of rare earth elements have been carried out on samples containing such elements whose K-absorption edge energies lie below and close to the γ-energy used. Suitable compounds of the rare earth elements have been chosen as mixture absorbers in these investigations. A narrow beam good geometry set-up was used for the attenuation measurements. A well-shielded scattering geometry was used for the photoelectric measurements. The mixture rule was invoked to extract the values of the mass attenuation coefficients for the elements from those of the corresponding compounds. The results are consistent with theoretical values derived from the XCOM package.