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941.
This work employed numerical experiments simulating colloid and solute transport in single parallel-plate fractures, using the random walk particle tracking method, to demonstrate that (1) there exists an aspect ratio of the colloid radius to half the fracture aperture, δo, where the average velocities of colloids and solutes are similar. When δ > δo, the velocity distribution assumption is satisfied, and the fact that the ratio of the colloid transport velocity to the solute transport velocity, τp, decreases as δ increases is well documented in the literature. However, when δ < δo, the velocity distribution assumption is violated, and τp increases as δ increases and (2) the Taylor dispersion coefficient and its extension by James and Chrysikopoulos [S.C. James, C. V. Chrysikopoulos, J. Colloid Interface Sci. 263 (2003) 288] will overestimate the colloid dispersion coefficient significantly. Additionally, numerical experiments simulating colloid and solute transport in variable-aperture fractures demonstrated that τp and DL,coll/DL,solute decrease with increasing CoV, and the anisotropy ratio only plays a minor role compared to the CoV. These observations have important implications towards the interpretation of colloid transport in both porous and fractured media. 相似文献
942.
风沙两相流跃移层中沙粒相的速度分布 总被引:6,自引:1,他引:5
从单个跃移沙粒在气流中的运动方程出发导出了风沙两相流中沙粒相速度分布函数的Boltzmann方程,对风沙流研究中几种不同的分布函数及其相应的统计平均值等基本概念给出了严密的数学定义,指出了不同分布函数之间的区别和联系,在略去铅垂方向空气阻力的情况下,给出了沙粒相速度分布函数沿铅垂方向的边缘分布,作为风沙流中跃移理论的主要基础之一。利用结果对前人在风沙流研究中发现的某些重要规律和现象进行了解释。 相似文献
943.
944.
Sheng Jiang E. David Sudol Victoria L. Dimonie Mohamed S. El‐Aasser 《Journal of polymer science. Part A, Polymer chemistry》2008,46(11):3638-3647
The effect of the medium composition (monomer and solvent) on the kinetics of dispersion polymerization of methyl methacrylate (MMA) was studied via reaction calorimetry. It was found that increasing the monomer concentration increased the reaction rate; the exponent of the dependency of the initial reaction rate on the MMA concentration was found to be 0.93. Narrow particle size distributions were achieved at the lower monomer concentrations (0.24–0.81 mol/L) and a minimum size (2.45 μm) was found at an intermediate concentration (0.44 mol/L). The average molecular weight of the PMMA increased and the molecular weight distribution broadened with increasing monomer concentration. During a dispersion polymerization, the MMA concentration was found to decrease linearly with conversion in both phases, whereas the ratio of concentrations in the particles and continuous phase ([M]p/[M]c) remained constant (0.47) with partitioning favoring the continuous phase. The average number of free radicals per particle in MMA dispersion polymerization was estimated to be high from the nucleation stage onward (>5000). The increasing rate during the first ~ 40% conversion was primarily caused by the increasing volume of the polymer particle phase. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3638–3647, 2008 相似文献
945.
Error bounds for asymptotic expansions of the distribution of the MLE in a GMANOVA model 总被引:1,自引:0,他引:1
Yasunori Fujikoshi 《Annals of the Institute of Statistical Mathematics》1987,39(1):153-161
Summary In this paper we obtain asymptotic expansions for the distribution function and the density function of a linear combination
of the MLE in a GMANOVA model, and for the density function of the MLE itself. We also obtain certain error bounds for the
asymptotic expansions. 相似文献
946.
The distribution theory is developed for a generalized least squares estimator of the growth curve model. A special case of the estimator is the maximum likelihood estimator which is weighted by the sample covariance matrix. The distribution of two conditional forms of the estimator are derived and from these its density is obtained. Two general pivots and their distributions are derived from the conditional forms and special cases of these are investigated. The results obtained are linked to carlier work. 相似文献
947.
Xiao Qian WANG Shi Hong CHENG 《数学学报(英文版)》2005,21(5):1121-1130
In Part Ⅰ the concept of the general regular variation of n-th order is proposed and its construction is discussed. The uniqueness of the standard expression and the higher order regularity of the auxiliary functions are proved. 相似文献
948.
Monica E. Bad Dumitrescu 《Annals of the Institute of Statistical Mathematics》1987,39(1):211-218
Summary The Bayesian estimation problem for the parameter θ of an exponential probability distribution is considered, when it is assumed
that θ has a natural conjugate prior density and a loss-function depending on the squared error is used. It is shown that,
with probability one, the posterior density of the Bayesian—centered and scaled parameter converges pointwise to the normal
probability density. The weak convergence of the posterior distributions to the normal distribution follows directly. Both
correct and incorrect models are studied and the asymptotic normality is stated respectively. 相似文献
949.
Characterization of a Marshall-Olkin type class of distributions 总被引:1,自引:0,他引:1
Pietro Muliere Marco Scarsini 《Annals of the Institute of Statistical Mathematics》1987,39(1):429-441
Summary A class of bivariate distributions that generalize Marshall-Olkin's one is characterized through a functional equation which
involves two associative operations. The obtained distributions concentrate positive mass on the linex=y when the two associative operations coincide; otherwise a positive mass is concentrated on a continuous monotone function.
Work performed while the authors were members of CNR-GNAFA. 相似文献
950.
对蛋白质分子进行量子化学计算常采用如下方法:以肽基和残基侧链为基本计算单元,使对蛋白质分子的计算分解成各次单元的计算(图10)。计算时往往根据构象图选择代表点以减少工作量。例如,计算木瓜蛋白酶时,根据其构象图,212个肽基被分为10组,每组中选取1个代表点进行计算。用同样的方法处理残基侧链的计算。但该方法 相似文献