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991.
三基色荧光灯用绿色发光材料,其发光效率对总的光通量影响很大[1],因而探索不同体系的绿色发光材料的合成将意义重大.由于Tb3 离子具有较好的特征绿色发射,所以研究铽的不同体系绿粉一直是人们所感兴趣的课题[2].稀土磷酸盐发光材料具有发光亮度高,合成温度适中,色坐标x值大等优点,因而成为当前材料科学的热门[3-5].  相似文献   
992.
Nano-sized HfO2, C and C/HfO2 powders obtained through hydrothermal process have been investigated by XRD, TEM and FTIR, and Different precursors, namely Hafnium(Ⅱ) oleate and Hafnium(Ⅱ) hydroxide derived from homogeneous precipitation method, have been chosen for the synthesis of nanometric HfO2 via hydrothermal process. The results indicate that using the former material as the precursor under identically hydrothermal process can yield finer HfO2 nanoparticles, compared to using the latter. Nano-sized Carbon of about 100 nm with square morphology and narrow size distribution can be obtained through hydrothermal reaction of sucrose solution at 200 ℃ for 6 h. The addition of as-synthesised Carbon nanoparticles into the hydrothermal process of HfO2 powder can produce C/HfO2 composite powders with core-shell structure.  相似文献   
993.
用水热法合成了2个化合物[M2(L)(phen)2(H2P)2]·6H2O[M=Ni(1),Zn(2),H4L=4,4'-联吡啶-2,2',6,6'-四羧酸,phen=1,10-邻菲咯啉],并进行了元素分析、IR及X-射线单品结构测定等表征.晶体结构解析结果表明:配合物1和2的晶体都属于三斜晶系,P1空间群.配合物的中心金属离子都是六配位变形的八面体配位构型,配体4,4'-联吡啶-2,2',6,6'-四羧酸的羧基均以单齿形式配位.室温固体荧光测试结果显示配合物2具有较强的荧光.  相似文献   
994.
A new dinuclear complex [Tb2(BA)6(2,2′-bipy)2] (BA=4-(trifluoromethyl)benzoic acid, 2,2′-bipy=2,2′-bipyridine) has been synthesized. The complex was characterized by X-ray single-crystal structure analysis. The complex is a dimer with an inversion center. In the complex, two Tb3+ ions are linked by four carboxylate groups of BA ligands in bridging-bidentate coordination mode. Each Tb3+ ion is eight-coordinated with two nitrogen atoms from one 2,2′-bipy molecule, four oxygen atoms from four bridging-bidentate BA ligands and two oxygen atoms from one chelating-bidentate BA ligand. Intermolecular hydrogen bonds are formed in the crystal. The complex exhibits strong green fluorescence under ultraviolet light and the fluorescence spectrum consists of four lines peaking at 489, 545, 584 and 620 nm, which are corresponding to the 5D47Fj (j=6~3) transitions of Tb3+ ion, respectively. CCDC: 727763.  相似文献   
995.
The properties of resveratrol (3′, 4′, 5-trihydroxystlbene, RST) were for the first time evaluated as a potential substrate for horseradish peroxidase (HRP)-catalyzed fluorogenic reaction. The properties of RST for use as fluorogenic substrates for HRP and its application in immunoassays were compared with commercially available substrates such as p-hydroxyphenylpropionic acid (pHPPA), chavicol and Amplex red by a fluoroimmunosensing method in the use of Schistosomia japonicum antibody (SjAb) as a model analyte. The fluoroimmunosensing device was constructed by dispersing Schistosomia japonicum antigen (SjAg), nano-Ag/SiO2 particles and sol-gel at low temperature. In pH 5.8 Britton-Robinson buffer (B-R), HRP-SjAb conjugates can catalyze the polymerization reaction of RST by H2O2 forming fluorescent dimmers. The increase of the fluorescence intensity of the dimmers product at emission of 462 nm (excitation: 315 nm) is proportional to the concentration of HRP-SjAb binding to the SjAg entrapped in the nano-Ag/SiO2 particles-sol-gel matrix. A competitive binding assay has been used to determine SjAb in rabbit serum with the aid of SjAb labeled with HRP. Substrate RST showed comparable ability for HRP detection and its enzyme-linked immunosensing reaction system, in a linear detection ranging of 1.5×10-6-7.3×10-4 g/L and with a detection limit of 1.5×10-6 g/L. The immobilized biocomposites surface could be regenerated by simply polishing with an alumina paper, with an excellent reproducibility (RSD = 4.7%). The proposed method has been successfully used for analysis of the rabbit serum sample with satisfactory results.  相似文献   
996.
张霞  陈莉  周春彬 《无机化学学报》2010,26(11):1934-1938
借助于PANI的还原性质,PANI/Fe2O3复合载体与AgNO3发生表面氧化还原反应,合成了Ag/PANI/Fe2O3复合纳米粒子。TEM和XRD结果表明,立方晶系纳米银的平均粒径10nm。FTIR结果表明,Ag与PANI及Fe2O3复合载体之间不存在化学键合作用,但由于PANI与Ag之间的电子相互作用,Ag/PANI/Fe2O3复合纳米粒子的FTIR吸收峰发生蓝移。Ag/PANI/Fe2O3复合纳米粒子对于间硝基苯磺酸钠的硼氢化钠还原反应表现出良好的催化活性,30min内间硝基苯磺酸钠的转化率达到86.77%。  相似文献   
997.
朱翔  黄薇  何成  段春迎 《无机化学学报》2010,26(12):2138-2142
由缩氨基脲和2-喹啉醛合成了席夫碱配体H2L,并与过渡金属离子Cd2+组装得到了四边形配合物CQ。用X射线衍射对配合物的晶体结构进行了测定,发现其具有I41/a空间群。通过荧光测试发现该配合物在CH3CN溶液中具有较强的荧光,加入间苯二甲酸、对苯二甲酸阴离子后荧光发生淬灭,而加入邻苯二甲酸阴离子荧光无变化,可以将邻苯二甲酸阴离子从其他2种二酸阴离子中区分出来。  相似文献   
998.
基于局域表面等离子体共振效应的光学生物传感器*   总被引:1,自引:0,他引:1  
肖桂娜  蔡继业 《化学进展》2010,22(1):194-200
贵金属纳米粒子表现出许多常规块体材料所不具备的优异性能,其中局域表面等离子体共振 (LSPR) 特性是研究热点之一。LSPR 的形状和位置与纳米粒子的组成、大小、形状、介电性质以及局域介质环境密切相关。基于这一特性,贵金属纳米粒子已广泛应用于光学生物传感器、光过滤器和表面增强光谱等领域。本文对各种结构的贵金属纳米粒子的制备方法及其在光学生物传感器中的应用进行了综述,并对 LSPR 纳米传感器的未来发展前景做了展望。  相似文献   
999.
宗水珍  崔荣静  费蕾  李巍巍  鞠熀先 《分析化学》2010,38(11):1533-1537
研究了在氧化镍纳米粒子改性石墨电极(GE)上肌红蛋白(Mb)的直接电化学行为, 并制备了新型H2O2 传感器.在0.1 mol/L 磷酸盐缓冲溶液(PBS, pH 7.0)中, 肌红蛋白有稳定而明确的氧化还原峰,电子转移速率常数为6.48/s;式量电位为-0.34 V(vs·SCE), 表面覆盖量8.06×10-10 mol/cm2.二甲亚砜(DMSO)的存在对加速肌红蛋白分子与电极之间的电子传递起了重要作用.光谱分析表明: 固定在Mb/NiO/DMSO膜中肌红蛋白能保持其生物活性,对H2O2有电催化活性,电催化响应与H2O2浓度呈线性关系,线性范围为0.8~24 μmol/L;检出限为0.039 μmol/L. 对H2O2的表观米氏常数为0.21 mmol/L, 灵敏度为417 mA cm2 L/mol, 呈现出高亲和性.  相似文献   
1000.
A comprehensive review of the development of assays, bioprobes, and biosensors using quantum dots (QDs) as integrated components is presented. In contrast to a QD that is selectively introduced as a label, an integrated QD is one that is present in a system throughout a bioanalysis, and simultaneously has a role in transduction and as a scaffold for biorecognition. Through a diverse array of coatings and bioconjugation strategies, it is possible to use QDs as a scaffold for biorecognition events. The modulation of QD luminescence provides the opportunity for the transduction of these events via fluorescence resonance energy transfer (FRET), bioluminescence resonance energy transfer (BRET), charge transfer quenching, and electrochemiluminescence (ECL). An overview of the basic concepts and principles underlying the use of QDs with each of these transduction methods is provided, along with many examples of their application in biological sensing. The latter include: the detection of small molecules using enzyme-linked methods, or using aptamers as affinity probes; the detection of proteins via immunoassays or aptamers; nucleic acid hybridization assays; and assays for protease or nuclease activity. Strategies for multiplexed detection are highlighted among these examples. Although the majority of developments to date have been in vitro, QD-based methods for ex vivo biological sensing are emerging. Some special attention is given to the development of solid-phase assays, which offer certain advantages over their solution-phase counterparts.  相似文献   
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