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41.
Francisco Radler de Aquino Neto Jari Nobrega Cardoso Alberto dos Santos Pereira Maria Conceiao Zupo Fernandes Carlos Alberto Caetano Andre Luiz de Castro Machado 《Journal of separation science》1994,17(4):259-263
HTHRGC was found essential for optimizing representative preparation of high molecular weight samples and enabling fingerprinting of heavy fractions of crude oils and associated paraffinic deposits in production pipelines. Laboratory experiments aimed at simulating the process of paraffin deposition could also be easily evaluated. A comparative investigation of the performance of cold on-column and SPI (PTV type) injectors, in conjunction with high temperature capillary columns, for analysis of high molecular weight fractions, was also conducted during the course of this work. 相似文献
42.
Resolution of Mixed Site DNA Complexes with Dimer‐Forming Minor‐Groove Binders by Using Electrospray Ionization Mass Spectrometry: Compound Structure and DNA Sequence Effects 下载免费PDF全文
43.
The Measurement of the Gibbs Energy of Transfer Between Oil and Water Using a Nano‐Carbon Paste Electrode 下载免费PDF全文
The use of nano‐carbon paste electrodes for the measurement of Gibbs energies of transfer between oil and aqueous phases is reported. In this method the oil of interest is used as the binder for the nano‐carbon paste electrodes and the molecule of interest is dissolved in the organic or aqueous phase. Voltammetry is performed over a period of time and used to monitor the transfer of the molecule between the two phases. The method is illustrated for the transfer of ferrocenemethanol between water and oil using the ferrocenemethanol / ferroceniummethanol (FcCH2OH/FcCH2OH+) redox couple. Three pairs of voltammetric peaks were observed in a 0.1 M KCl solution when the nano‐carbon paste electrode was modified by dissolution of FcCH2OH in the binder oil: P1 [E=0.23 V, 0.17 V vs. Ag/AgCl (1 M KCl)], P2 [E=0.36 V, 0.32 V vs. Ag/AgCl (1 M KCl)] and P3 [E=0.55 V, 0.46 V vs. Ag/AgCl (1 M KCl)]. These are assigned to the FcCH2OH species existing in the aqueous solution [FcCH2OH(aq)/FcCH2OH+(aq)], originating in the oil (o) [FcCH2OH(o)/FcCH2OH+(aq)] and to oxidation of adsorbed (ads) material on the nano‐carbon [FcCH2OH(ads)] respectively. When supporting electrolyte containing the anions Cl?, NO3? or SCN? was used, an expulsion of the oxidised ferrocene occurred and the difference in midpoint potentials (Emid) between the peaks P1 and P2 observed in these experiments allowed the calculation of the Gibbs energy (ΔG°) of transfer of ferrocenemethanol from water to oil. The average ΔG° value thus obtained was (?12.7±0.2) kJ mol?1. For more hydrophobic anions (X?=PF6?, AsF6?), the electron transfer is coupled to the transfer of the anion into the oil and the ΔG° for the transfer of the ion pair of FcCH2OH+ and X? ions from water to oil was found to be ?1.3 and ?3.9 kJ mol?1 for PF6? and AsF6? respectively. 相似文献
44.
A series of binder‐free ZSM‐5 catalysts and a binder‐containing catalyst were prepared and characterized with X‐ray diffraction (XRD), X‐ray fluorescence (XRF), 27Al magic‐angle spinning (MAS) nuclear magnetic resonance (NMR), N2 sorption and ammonia temperature‐programmed deposition (TPD) methods. The catalytic activity and selectivity in the dehydration of crude methanol to dimethyl ether (DME) were evaluated in a fixed‐bed reactor for the catalysts. The outstanding structural characters such as high zeolite contents, sufficiently open channels and richness in mesopores have been proved on these binder‐free catalysts. The influence of the solid‐acidity, which is closely related to the framework silica alumina ratio (SAR) of the catalysts, on the catalytic properties has been discussed. A binder‐free catalyst with a better potential in application has been selected for its high activity and selectivity, long life‐time and non‐sensitivity to water contents in the feed. The reason for its excellent performance of the catalyst was discussed. 相似文献
45.
Colombini MP Carmignani A Modugno F Frezzato F Olchini A Brecoulaki H Vassilopoulou V Karkanas P 《Talanta》2004,63(4):839-848
The materials used in the decoration of three painted astragaloi (knucklebones) from the Koroneia cave (Greece) were investigated by means of sequential application of non-destructive and destructive techniques: optical microscopy, environmental scanning electron microscopy coupled with X-ray microanalysis (ESEM-EDX), Fourier transform infrared spectroscopy (FTIR) with micro-attenuated total reflection (μ-ATR) technique, high performance liquid chromatography (HPLC) coupled with UV-fluorescence and gas chromatography-mass spectrometry (GC-MS) were used.The main results highlighted that the three astragaloi were prepared with a ground of ochre or iron clay and painted with a proteinaceous matter such as binder egg tempera. Both FTIR and GC-MS agree in the detection of lipids that can be related to egg. Organic dyestuffs identified as madder lake and shellfish purple were used together with inorganic pigments. 相似文献
46.
锂离子电池是目前电脑、通讯、消费电子品以及未来电动车动力系统的主要能源。硅基负极材料因其具有较高理论比容量(4200 mAh·g-1,为石墨10倍以上),被视为最理想的下一代锂离子电池负极材料。然而硅负极在充放电过程中巨大的体积膨胀造成极片材料的粉化脱落、SEI膜的持续增长、正极锂离子的不断消耗,以及现有商业化粘结剂与硅表面较弱的相互作用等诸多缺陷,造成电池容量快速的衰减,阻碍了硅基材料在锂离子电池中的商业化应用。本文对硅基负极材料及其相关电池材料,如硅材料结构、粘结剂、电解液及添加剂等,进行了系统全面的总结。最后对硅基材料目前研究进展和未来发展方向做出总结与评述,以期为下一代硅基电池体系发展提供参考。 相似文献
47.
Lithium ion batteries which are an energy storage system have increasing attention owing to suitability and advantages for many applications. Although it has ideal specifications, the capacity properties still have to be developed. In this study, the electrical conductivity of the anode was increased by using a conductive polymer binder and the active material content of the anode was also enhanced without adding carbon additives. Silicon based anodes were manufactured by using poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT:PSS) and poly(3,4-ethylenedioxythiophene)/polythiophenesulfonyl chloride (PEDOT:PTS) conductive polymer binders. Si/PEDOT:PTS anode showed about 2000 mAh/g specific capacities after 60 cycles with decreasing impedance. 相似文献
48.
锂离子电池在高电压下会导致严重的电解液分解以及不稳定的正极与电解质界面问题,严重制约高电压正极材料的商业化.粘结剂不仅可以将正极活性材料和导电炭紧密粘结在集流体上,还对构建电解质与正极之间的多尺度相容性界面起积极作用,因此,粘结剂的优化可以有效解决上述难题.本文提出了高电压锂离子电池正极粘结剂需具备的必要条件,如:粘结性能和机械性能优异,具有出色的电化学稳定性和热力学稳定性以及良好的离子和电子传输能力等.综述了近些年来高电压正极粘结剂的研究及发展现状,通过天然粘结剂和合成粘结剂对目前已报道的高电压粘结剂进行了评述,介绍了各种粘结剂对电极的粘结性能和包覆以及对锂离子电池性能的影响机制,重点阐述了粘结剂分子结构中的极性基团与活性物质间的相互作用,如氢键和离子-偶极相互作用,并讨论了设计开发高电压正极粘结剂的途径以及展望了高电压正极粘结剂的发展前景. 相似文献
49.
Comparative characteristics of aramide fiber reinforced plastics (AFRP) made by laser cutting or machining are presented. It is found that the strength of the specimens cut out by laser is 4–25% higher, while the moisture absorption is at least 2 times lower as compared to those cut out by machining. The deviation of the cutting edge size for AFRP 2 mm thick does not exceed 0.4 mm. Calculated and experimental data are given. The possibilities and conditions of cutting the AFRP up to 6 mm thick are determined.Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 3, pp. 375–384, May–June, 1999. 相似文献
50.