Water confined in two-dimensions: Fundamentals and applications

The behavior of water in close proximity to other materials under ambient conditions is of great significance due to its importance in a broad range of daily applications and scientific research. The structure and dynamics of water at an interface or in a nanopore are often significantly different from those of its bulk counterpart. Until recently, experimental access to these interfacial water structures was difficult to realize. The advent of two-dimensional materials, especially graphene, and the availability of various scanning probe microscopies were instrumental to visualize, characterize and provide fundamental knowledge of confined water. This review article summarizes the recent experimental and theoretical progress in a better understanding of water confined between layered Van der Waals materials. These results reveal that the structure and stability of the hydrogen bonded networks are determined by the elegant balance between water-surface and water-water interactions. The water-surface interactions often lead to structures that differ significantly from the conventional bilayer model of natural ice. Here, we review the current knowledge of water adsorption in different environments and intercalation within various confinements. In addition, we extend this review to cover the influence of interfacial water on the two-dimensional material cover and summarize the use of these systems in potential novel applications. Finally, we discuss emerged issues and identify some flaws in the present understanding.     

Strong approximation of empirical kac processes

Summary A strong approximation result is derived for the Poisson sample size empirical characteristic process. Work done while the author was on leave from Szeged University and a Visiting Scientist at Carleton University, supported by Canadian N.R.C. operating grants of D. A. Dawson and J. N. K. Rao.     

Some bounds for partially balanced block designs

Bounds on eigenvalues of theC-matrix for a partially balanced block (PBB) design are given together with some bounds on the number of blocks. Furthermore, a certain equiblock-sized PBB design is characterized. These results contain, as special cases, the known results for variance-balanced block designs and so on.     

Factorizing multivariate time series operators

Motivated by problems occurring in the empirical identification and modelling of a n-dimensional ARMA time series X(t) we study the possibility of obtaining a factorization (I + a₁B + … + a_pB^p) X(t) = [Π_i=1^p (I ? α_iB)] X(t), where B is the backward shift operator. Using a result in [3] we conclude that as in the univariate case such a factorization always exists, but unlike the univariate case in general the factorization is not unique for given a₁, a₂,…, a_p. In fact the number of possibilities is limited upwards by $\text{(np)!}\text{(n!)}{}^{\mathrm{p}}$, there being cases, however, where this maximum is not reached. Implications for the existence and possible use of transformations which removes nonstationarity (or almost nonstationarity) of X(t) are mentioned.     

A note on realizing homomorphisms of category algebras

The complete Boolean homomorphisms from the category algebra $\text{C}$(X) of a complete matrix space X to the category algebra $\text{C}$(Y) of a Baire topological space Y are characterized as those σ-homomorphisms which are induced by continuous maps from dense G₈-subsets of Y into X. This result is used to deduce a series of related results in topology and measure theory (some of which are well-known). Finally a similar result for the complete Boolean homomorphisms from the category algebra $\text{C}$(X) of a compact Hausdorff space X tothe category algebra $\text{C}$(Y) of a Baire topological space Y is proved.     

Cellularity in polyhedra

A compact subset X of a polyhedron P is cellular in P if there is a pseudoisotropy of P shrinking precisely X to a point. A proper surjection between polyhedra f:P→Q is cellular if each point inverse of f is cellular in P. It is shown that if f:P→Q is a cellular map and either P or Q is a generalized n-manifold, n≠4, then f is approximable by homeomorphisms. Also, if P or Q is an n-manifold with boundary, n≠4, 5, then a cellular map f:P→Q is approximable by homeomorphisms. A cellularity criterion for a special class of cell-like sets in polyhedra is established.     

Krichever-Novikov algebras for more than two points

Krichever-Novikov algebras of meromorphic vector fields with more than two poles on higher genus Riemann surfaces are introduced. The structure of these algebras and their induced modules of forms of weight is studied.     

The twisted SU(N) group. On the C *-algebra C(S μ U(N))

It is proved that C(S U(N)) is a type I C ^*-algebra.     

Informationen

Studies on the workability of precise seeders by means of labelling methods has been possible due to the solution of the following problems: labelling of seeds, radiation collimation of labelled seeds being sown, elaboration of measuring and registering systems as well as processing systems of a measuring signal. The developed method allows for precise, quick and fully objective evaluation of the studied seeders to be done under natural conditions.     

A size-width inequality for distributive lattices

We show that every collection ofw sets such that none contains any other generates at least 3w-2 sets under the operations of taking intersections and unions. In particular, we prove that if the finite distributive lattice ? contains an antichain of sizew, then |?| ≧3w, forw≠1, 2, 3, 6, where the minimal exceptional cases arise from the Boolean algebras ?_n withn=0, 1, 2, 3, 4 atoms.