全文获取类型
收费全文 | 31407篇 |
免费 | 3082篇 |
国内免费 | 3643篇 |
专业分类
化学 | 25987篇 |
晶体学 | 435篇 |
力学 | 1584篇 |
综合类 | 201篇 |
数学 | 3232篇 |
物理学 | 6693篇 |
出版年
2024年 | 66篇 |
2023年 | 381篇 |
2022年 | 974篇 |
2021年 | 886篇 |
2020年 | 1086篇 |
2019年 | 1033篇 |
2018年 | 919篇 |
2017年 | 1136篇 |
2016年 | 1227篇 |
2015年 | 1124篇 |
2014年 | 1413篇 |
2013年 | 2265篇 |
2012年 | 1729篇 |
2011年 | 1989篇 |
2010年 | 1638篇 |
2009年 | 2031篇 |
2008年 | 1852篇 |
2007年 | 1853篇 |
2006年 | 1688篇 |
2005年 | 1550篇 |
2004年 | 1584篇 |
2003年 | 1209篇 |
2002年 | 1496篇 |
2001年 | 884篇 |
2000年 | 716篇 |
1999年 | 580篇 |
1998年 | 504篇 |
1997年 | 457篇 |
1996年 | 506篇 |
1995年 | 470篇 |
1994年 | 449篇 |
1993年 | 312篇 |
1992年 | 319篇 |
1991年 | 191篇 |
1990年 | 149篇 |
1989年 | 149篇 |
1988年 | 159篇 |
1987年 | 124篇 |
1986年 | 95篇 |
1985年 | 81篇 |
1984年 | 81篇 |
1983年 | 30篇 |
1982年 | 77篇 |
1981年 | 102篇 |
1980年 | 114篇 |
1979年 | 118篇 |
1978年 | 94篇 |
1977年 | 70篇 |
1976年 | 64篇 |
1973年 | 30篇 |
排序方式: 共有10000条查询结果,搜索用时 2 毫秒
161.
Consider discrete storage processes that are modulated by environmental processes. Environmental processes cause interruptions in the input and/or output processes of the discrete storage processes. Due to the difficulties encountered in the exact analysis of such discrete storage systems, often Poisson flow and/or fluid flow models with the same modulating environmental processes are proposed as approximations for these systems. The analysis of Poisson flow and fluid flow models is much easier than that of the discrete storage processes. In this paper we give sufficient conditions under which the content of the discrete storage processes can be bounded by the Poisson flow and the fluid flow models. For example, we show that Poisson flow models and the fluid flow models developed by Kosten (and by Anick, Mitra and Sondhi) can be used to bound the performance of infinite (finite) source packetized voice/data communication systems. We also show that a Poisson flow model and the fluid flow model developed by Mitra can be used to bound the buffer content of a two stage automatic transfer line. The potential use of the bounding techniques presented in this paper, of course, transcends well beyond these examples.Supported in part by NSF grant DMS-9308149. 相似文献
162.
163.
E. Mieloszyk 《Periodica Mathematica Hungarica》1990,21(1):43-53
Applying Bittner's operational calculus we present a method to give approximate solutions of linear partial differential equations of first order
相似文献
164.
Likelihood estimation of soft-core interaction potentials for Gibbsian point patterns 总被引:3,自引:3,他引:0
Yosihiko Ogata Masaharu Tanemura 《Annals of the Institute of Statistical Mathematics》1989,41(3):583-600
The likelihood method is developed for the analysis of socalled regular point patterns. Approximating the normalizing factor of Gibbs canonical distribution, we simultaneously estimate two parameters, one for the scale and the other which measures the softness (or hardness), of repulsive interactions between points. The approximations are useful up to a considerably high density. Some real data are analyzed to illustrate the utility of the parameters for characterizing the regular point pattern. 相似文献
165.
We formulate the super-KMS condition suggested by Connes and Kastler, in the context of entire cyclic cohomology of quantum algebras. We show that the Chern character of Jaffe, Lesniewski, and Osterwalder — associated by Kastler to a super-KMS functional — satisfies the entire growth condition. Hence, a super-KMS functional defines a cocycle for the entire cyclic cohomology of quantum algebras.Supported in part by the National Science Foundation. 相似文献
166.
Shun-Chen Niu 《Queueing Systems》1988,3(2):157-178
We give in this paper a detailed sample-average analysis of GI/G/1 queues with the preemptive-resume LIFO (last-in-first-out) queue discipline: we study the long-run state behavior of the system by averaging over arrival epochs, departure epochs, as well as time, and obtain relations that express the resulting averages in terms of basic characteristics within busy cycles. These relations, together with the fact that the preemptive-resume LIFO queue discipline is work-conserving, imply new representations for both actual and virtual delays in standard GI/G/1 queues with the FIFO (first-in-first-out) queue discipline. The arguments by which our results are obtained unveil the underlying structural explanations for many classical and somewhat mysterious results relating to queue lengths and/or delays in standard GI/G/1 queues, including the well-known Bene's formula for the delay distribution in M/G/l. We also discuss how to extend our results to settings more general than GI/G/1. 相似文献
167.
Chiral separations by host-guest complexation with cyclodextrin and crown ether in capillary zone electrophoresis 总被引:2,自引:0,他引:2
Summary Capillary zone electrophoresis using cyclodextrins and a chiral crown ether as buffer constituents was studied for the enantiomeric separation of drugs and amino acids. Based on results obtained from separation of racemic -amino acids both chiral selectors are compared with respect to resolution, efficiency and retention time. For (±)-Quinagolide effects of buffer composition and temperature are examined using -cyclodextrin as chiral agent. Optimum conditions were pH 2.5 at 30 mmol L–1 -cyclodextrin. A linear dependence of retention on -cyclodextrin concentration allowed calculation of formation constants of the host-guest complexes. Buffer concentration and temperature also influence resolution. The application of a chiral crown ether to the separation of optical isomers in capillary zone electrophoresis is described for the first time. Chiral recognition of solutes depends on the formation of protonated alkyl amines and separation is attributed to the formation of diastereomeric host-guest complexes with different interactions for each enantiomer. The effects of crown ether concentration on resolution are presented. 相似文献
168.
J. A. M. Janssen 《Journal of statistical physics》1989,57(1-2):187-198
The master equation for a complex chemical reaction cannot always be reduced to a simpler master equation, even if there are fast and slow individual reaction steps. Nevertheless the elimination of intermediates can be carried out with the help of the-expansion. This is illustrated with a well-known complex reaction: the dissociation of N2O5. It is shown that the intrinsic fluctuations in the N2O5 decay are larger than those implied by the master equation suggested by the macroscopic rate law. 相似文献
169.
苯部分加氢制环己烯的非晶态Ru-M-B/ZrO2催化剂的表征 总被引:13,自引:0,他引:13
采用化学还原法,制备了高活性,高选择性非晶态RU-M-B/ZRO2催化剂,并将其用于催化苯部分加氢制环己烯,在140℃、5.0Mpa氢压下,苯转化40%时,环己烯选择性达到85%左右。环己烯最高收率达到52.1%,用XRD、SEM、BET比表面积测定等手段对摧化剂进行表征,XRD和SEM测试表明,RU-U-B/ZRO2属于非晶态,活性组分高度分散,XRD结果证实,在加氢过程中,非晶分解,RU晶化;温度愈高,RU晶化愈快,催化剂的活性、选择性与RU微晶的粒径有关,RU微晶粒径应控制在5nm左右,BET比表面积测定表明,ZRO2的负载提高了催化剂的比表面积,从而有利于活性组分的高度分散,并可阻止RU微晶的长大,讨论了B和ZRO2对提高选择性的作用。 相似文献
170.
|