全文获取类型
收费全文 | 270篇 |
免费 | 2篇 |
国内免费 | 52篇 |
专业分类
化学 | 163篇 |
晶体学 | 3篇 |
力学 | 24篇 |
数学 | 35篇 |
物理学 | 99篇 |
出版年
2023年 | 11篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 9篇 |
2016年 | 15篇 |
2015年 | 11篇 |
2014年 | 8篇 |
2013年 | 16篇 |
2012年 | 14篇 |
2011年 | 22篇 |
2010年 | 13篇 |
2009年 | 22篇 |
2008年 | 14篇 |
2007年 | 12篇 |
2006年 | 31篇 |
2005年 | 10篇 |
2004年 | 11篇 |
2003年 | 12篇 |
2002年 | 4篇 |
2001年 | 12篇 |
2000年 | 7篇 |
1999年 | 11篇 |
1998年 | 4篇 |
1997年 | 8篇 |
1996年 | 2篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有324条查询结果,搜索用时 78 毫秒
321.
322.
We have studied current flow through a single π conjugate molecule weakly adsorbed to, and sandwiched between, two electrodes, focusing specifically on carrier injection through an organic/metal interface. This is the first calculation to investigate the effects of the orientation of the molecule and the electrode material on current using a first-principles method: in the past, most calculations of current were based on the assumption of covalent bonding of a molecule to electrodes. We modeled two systems in which a naphthalene molecule is sandwiched between gold (Au) or aluminum (Al) electrodes. First, in both systems, the current through the molecule depends on the orientation of the molecule. This indicates that electrons mainly transfer through the π channel, which is the overlap between the molecular π orbital and the electrode orbital. Next, the current in the Au-naphthalene-Au system is higher than that in the Al-naphthalene-Al system. This shows that Au is more suitable as an electrode material than Al. Therefore, the orientation of the molecule at an organic/metal interface and the materials comprising the electrodes play a key role in carrier injection through the interface. 相似文献
323.
The preparation of the poly(3-hexylthiophene) (P3HT) stripe structure with oriented nanofibrils prepared by controlled inclining evaporative technique is reported. The distance of the adjacent stripes could be controlled from 40 μm to 100 μm by decreasing the inclining angle. The oriented nanofibrils in the stripes can be obtained because the P3HT lamellae diffuse directionally and form 1D crystals at the three-phase contact line of the drop. In order to get the oriented P3HT stripes, the proper solvent evaporation rate which is controlled by the inclining angle and the wettability of the substrate must be carefully chosen to match the P3HT 1D crystallization rate. It is found that large inclining angle and the hydrophilic substrate (for example: glass and PEDOT) are beneficial to get P3HT stripe structure with oriented nanofibrils. 相似文献
324.
The orientation of a lysozyme immobilized with a monoclonal antibody was evaluated based on determination of the uppermost surface structure using time-of-flight secondary ion mass spectrometry (TOF-SIMS). Specific peaks of the oriented lysozyme immobilized with monoclonal anti-lysozyme antibody were obtained in comparison with reference samples, non-oriented immobilized lysozyme and immobilized anti-lysozyme antibody. All samples were freeze-dried before TOF-SIMS measurement, and then each sample was measured using TOF-SIMS with a bismuth cluster ion source. TOF-SIMS spectra were analyzed to select peaks specific to the oriented immobilized lysozyme as well as to identify their chemical formula and ensemble of amino acids. The possible chemical formulae of the lysozyme fragments were then investigated with an element matching program and a residue matching program. The results from TOF-SIMS spectra analysis were compared to the amino acid sequence of the lysozyme and its three-dimensional structure registered in the protein data bank. Finally, the fragment-ion-generating regions of the oriented immobilized lysozyme were determined based on the suggested residues and the three-dimensional structure. 相似文献