全文获取类型
收费全文 | 13989篇 |
免费 | 1390篇 |
国内免费 | 876篇 |
专业分类
化学 | 3468篇 |
晶体学 | 164篇 |
力学 | 582篇 |
综合类 | 51篇 |
数学 | 213篇 |
物理学 | 11777篇 |
出版年
2024年 | 12篇 |
2023年 | 84篇 |
2022年 | 196篇 |
2021年 | 182篇 |
2020年 | 238篇 |
2019年 | 201篇 |
2018年 | 259篇 |
2017年 | 429篇 |
2016年 | 530篇 |
2015年 | 478篇 |
2014年 | 1092篇 |
2013年 | 992篇 |
2012年 | 694篇 |
2011年 | 1208篇 |
2010年 | 806篇 |
2009年 | 999篇 |
2008年 | 1026篇 |
2007年 | 1040篇 |
2006年 | 831篇 |
2005年 | 704篇 |
2004年 | 633篇 |
2003年 | 554篇 |
2002年 | 481篇 |
2001年 | 453篇 |
2000年 | 368篇 |
1999年 | 351篇 |
1998年 | 310篇 |
1997年 | 223篇 |
1996年 | 187篇 |
1995年 | 146篇 |
1994年 | 102篇 |
1993年 | 76篇 |
1992年 | 68篇 |
1991年 | 63篇 |
1990年 | 51篇 |
1989年 | 36篇 |
1988年 | 26篇 |
1987年 | 32篇 |
1986年 | 15篇 |
1985年 | 9篇 |
1984年 | 18篇 |
1983年 | 8篇 |
1982年 | 4篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
改性PAN纤维与铁离子的配位结构及其对染料降解的催化作用 总被引:8,自引:0,他引:8
在室温条件下应用偕胺肟改性聚丙烯腈纤维(AO-PAN)与FeCl3反应制备了聚丙烯腈纤维铁配合物(Fe-AO-PAN), 并分别使用X射线光电子能谱(XPS)、傅立叶红外光谱(FTIR)、动态热机械分析(DTMA)和电导法对Fe-AO-PAN进行了表征以确定其组成结构. 然后将Fe-AO-PAN作为非均相Fenton 催化剂应用于两种常用偶氮染料C.I.活性红195(RR 195)和C.I.酸性黑234(AB 234)的光催化氧化降解反应中, 考察了其对降解反应的催化作用. 结果表明, Fe-AO-PAN中的Fe3+能够与AO-PAN表面三个偕胺肟(AO)链节单元的三个氨基氮原子和三个羟基氧原子进行配位反应, 配位数为6. 在Fe-AO-PAN和辐射光存在下, 两种染料的氧化降解反应速度显著加快, 染料结构中的偶氮键和芳香环结构都遭到破坏. PAN纤维腈基转化率的提高不仅能够明显增加Fe-AOPAN表面结构中Fe3+含量, 而且可显著促进其对染料氧化降解反应的催化作用. 相似文献
992.
高能强流电子束的束参数测量是加速器研制过程中重要的一项测量工作,由于光学渡越辐射具有时间响应快、分辨率高等特点而被用于测量电子束的具有时间分辨能力的束剖面、发散角、能量等多个参数;通过电子束束参数的时间分辨测量则能够了解电子束产生、输运中的问题,非常有利于加速器的研究与调试。一种具有时间分辨能力的、利用光学渡越辐射进行高能强流电子束束斑测量的系统在中国工程物理研究院被建立起来,并在12 MeV LIA的电子束束斑的测量中用于电子束传输研究,该系统拍摄图像的间隔时间最小为10 ns,最小的曝光时间为3 ns,具有一次可以拍摄8幅图像的能力,并获得了12 MeV LIA约100 ns内相应的时间分辨的束斑变化情况,观察到了一些过去未观察到的现象,为加速器的研究提供了又一个新测试方法。 相似文献
993.
994.
The optical constants (absorption coefficient, refractive index, extention coefficient, real and imaginary part of dielectric constant) have been studied for a-Se80Te20−xPbx (where x = 0, 2, 6, 10) thin films as a function of photon energy in the wave length range (500–1000 nm). It has been found that the optical band gap increases while the refractive index and the extinction coefficient (k) decreases on incorporation of lead in Se–Te system. The value of absorption coefficient (α) and the extinction coefficient (k) increases, while the value of refractive index (n) decreases with incident photon energy. The results are interpreted in terms of the change in concentration of localized states due to the shift in fermi level. 相似文献
995.
996.
双轴应力状态下正交异性动态光弹性应力——光性定律研究 总被引:2,自引:0,他引:2
基于静态下Hyer和Liu表述的正交异性应力-光性定律,在前文中,提出了正交异性光弹性复合材料的动态应力-光性定律并证明了其在单轴应力状态下的正确性。本文旨在进一步考察在双轴应力状态下正交异性动态应力-光性定律的适用性,采用的方法是对纤维增强光弹性复合材料制作的平板模型施加冲击荷载,加载方向与材料纤维方向分别成0°、90°及45°角,同时进行正交异性动态光弹性实验和动态应变测量,另外,对该模型进行相应的各向异性介质时域边界元计算。把动态应变测量推算出的应力分量以及时域边界元计算出的应力分量分别代入正交异性动态应力-光性定律,得到随时间变化的双折射条纹级数历程,将其与正交异性动态光弹性实验的结果进行比较。实验及计算结果表明,在三个加载方向下,由这三种方法得到的双折射条纹级数历程均吻合良好,从而证明了前文提出的正交异性动态应力-光性定律在双轴应力状态下的正确性。 相似文献
997.
998.
Attenuation and depolarization of millimeter waves due to incoherent scattering in tropical rainfall
Moses Oludare Ajewole Tomohiro Oguchi 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,83(2):149-158
The radiative transfer equation has been applied to investigate the effects of multiple scattering on communication at the millimeter wavelength in tropical rain. Horizontal linearly polarized incident waves are assumed. The scattering characteristics are calculated using the Mie theory at frequencies of 16, 34.8, 82, 140 and and at rainfall rates of 12.5, 50 and . Some results of the directional patterns of the incoherent intensities at various points in the rain medium are presented. The frequency dependence of the propagation distance, attenuation coefficient and the variation of incoherent specific intensities in tropical rainfall are investigated. The incoherent power at the receiver relative to the coherent power, which is important in assessing the quality of signal in the receiver, is also investigated. It is observed that the maximum incoherent copolarized received power is about in tropical rainfall at rainfall rate. Also the difference between the copolarized incoherent power in tropical and temperate rainfall is about at frequencies higher than , and about for the cross-polarized incoherent power components. It may therefore be safely said that multiple scattering may not result in serious degradation of the coherent wave component even in the most intense tropical precipitation. It also appears that it is independent of regional rainfall climatology. 相似文献
999.
P.S Erdman M Fajardo K.M Sando W.C Stwalley 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,88(4):447-481
Experimental results are reported for a unique spectroscopic device called the Plasma Spectroscopy Cell. Optical absorption of lithium metal vapor was observed at high density and temperature. Absorption spectra are analyzed using theoretical calculations of absorption cross sections for lithium-helium interactions, and singlet and triplet state transitions of diatomic lithium in the visible spectral range. This is believed to be the most complex example yet calculated in which absolute bound-bound, bound-free, free-bound, and free-free contributions for all possible optically allowed transitions are all included, in quite respectable agreement with experiment. 相似文献
1000.
A Jayanth Kumar N M Gowri R Venkateswara Raju G Nirmala B S Bellubbi T Radha Krishna 《Pramana》2006,67(2):383-387
Over the last two decades, the fiber optic technology has passed through many analytical stages. Some commercially available
fiber optic sensors, though in a small way, are being used for automation in mechanical and industrial environments. They
are also used for instrumentation and controls.
In the present work, an intensity-modulated intrinsic fiber optic sugar sensor is presented. This type of sensor, with slight
modification, can be used for on-line determination of the concentration of sugar content in sugarcane juice in sugar industry.
In the present set-up, a plastic fiber made of polymethylmethacrylate is used. A portion of the cladding (1 cm, 2 cm, 3 cm)
at the mid-point along the length of the fiber is removed. This portion is immersed in sugar solution of known concentration
and refractive index. At one end of the fiber an 850 nm source is used and at the other end a power meter is connected. By
varying the concentration of sugar solution, the output power is noted. These studies are made due to the change in refractive
index of the fluid. The device was found to be very sensitive which is free from EMI and shock hazards, stable and repeatable
and they can be remotely interfaced with a computer to give on-line measurements and thus become useful for application in
sugar industries. 相似文献