The application of reed-vibration mechanical spectroscopy for liquids to detect chemical reactions of an acrylic structural adhesive

There remain a number of unsolved problems about chemical reactions, and it is significant to explore new detection methods because they always offer some unique information about reactions from new points of view. For the first time, the solidification course of a modified two-component acrylic structural adhesive is measured by using reed-vibration mechanical spectroscopy for liquids （RMS-L） in this work, and results show that there are four sequential processes of mechanical spectra with time. The in-depth analyses indicate that RMS-L can detect in real-time the generation and disappearance of active free radicals, as well as the chemical cross-link processes in the adhesive. This kind of real-time detection will undoubtedly facilitate the study of the chemical reaction dynamics controlled by free radicals.     

Preparation and characterization of organic–inorganic hybrids and coating films from 3‐methacryloxypropylpolysilsesquioxane

3‐Methacryloxypropylpolysilsesquioxane (MA‐PS) was prepared by acid‐ or base‐catalyzed hydrolytic polycondensation of 3‐methacryloxypropyltrimethoxysilane (MAS). MA‐PS coating film was prepared by dip‐coating on organic, metal and inorganic substrates, including poly(ethylene terephthalate), aluminum, stainless steel, and glass. The coating films on poly(ethylene terephthalate) and glass showed high adhesive strength. The hardness of coating films increased with increasing heat treatment temperature, whereas they decreased with increasing H₂O/MAS molar ratio. The refractive index of coating films increased with increasing heat treatment temperature. In addition, flat and transparent free‐standing films (0.24–0.27 mm thickness) were prepared from MA‐PS that were crack‐free after heat treatment at 1000 °C. Copyright © 2001 John Wiley & Sons, Ltd.     

Anisotropic elastic materials capable of a three-dimensional deformation (static or dynamic) with only one displacement component and uncoupling of all three displacement components

It is shown that there are anisotropic elastic materials that are capable of a non-uniform three-dimensional deformation with only one displacement component. For wave propagation, the equation of motion can be cast in the form of the differential equation for acoustic waves. For elastostatics, the equation of equilibrium reduces to Laplace’s equation. The material can be monoclinic, orthotropic, tetragonal, hexagonal or cubic. There are also anisotropic elastic materials that uncouple all three displacement components. The governing equation for each of the uncoupled displacement can be cast in the form of the differential equation for acoustic waves in the case of dynamic or Laplace’s equation in the case of static. The material can be orthotropic, tetragonal, hexagonal or cubic.     

胶粘剂对石英音叉剪切力控距的影响

粘接音叉和光纤探针的胶粘剂对由石英音叉和光纤探针构成剪切力控距体系的品质因数有明显的影响。通过对比不同胶粘剂的物理特性 ,选择了适合于粘接音叉和光纤探针的胶粘剂。研究发现 ,室温快速固化环氧树脂胶粘剂HY 91 4 ,GHJ光学用环氧型胶粘剂 (Opticalepoxy)和 50 2胶能满足实验要求。理论分析指出 ,对于同样的音叉和光纤探针来说 ,胶粘剂的密度和用量是影响音叉 探针体系品质因数的主要因素     

Interfacial strength of joints between fibers and dispersedly filled epoxy matrices

The concentration dependences of adhesive strength are investigated for fiber/dispersedly filled epoxy matrix systems. The measurements were carried out using an improved model of adhesiometer under normal conditions at a constant rate of loading. It is shown that the adhesive strength as a function of filler concentration has a maximum, which is more or less pronounced. The location of the maximum depends on the nature of filler and particle geometry. The increase in the adhesive strength at the maximum reaches 20–30% in comparison with that for the unfilled epoxy matrix. Since the interfacial strength between steel wire and all the mineral powders investigated is zero, the growth in the adhesive strength upon introduction of a finely divided filler in polymer binders is rather un expected. The possible reasons for the phenomenon observed are discussed. __________ Translated from Mekhanika Kompozitnykh Materialov, Vol. 43, No. 1, pp. 3–14, January–February, 2007.