Control of wavepacket dynamics in mixed alkali metal clusters by optimally shaped fs pulses

We have performed adaptive feedback optimization of phase-shaped femtosecond laser pulses to control the wavepacket dynamics of small mixed alkali-metal clusters. An optimization algorithm based on Evolutionary Strategies was used to maximize the ion intensities. The optimized pulses for NaK and Na₂K converged to pulse trains consisting of numerous peaks. The timing of the elements of the pulse trains corresponds to integer and half integer numbers of the vibrational periods of the molecules, reflecting the wavepacket dynamics in their excited states. Received 4 December 2001     

Recent Trends in the Chemistry of Thienopyridines

The nomenclature, synthesis, and reactions of various isomeric thienopyridines as well as their applications are reviewed.     

Synthesis of Novel 1-(substituted phenyl)-2-phospholene 1-Oxide Derivatives

Several novel 1-(substituted phenyl)-2-phospholene 1-oxide derivatives, which are analogs of sugars having a phosphorus atom in place of the ring oxygen of normal sugars, were synthesized from the corresponding 2-phospholenes as the starting materials. Structures of all the synthesized compounds were unequivocally confirmed by IR, 1 H, 13 C, and 31 P NMR spectral, elemental, and X-ray crystallographic analyses.     

Continuum shell-model calculation for 14C including core excitations

Elastic and inelastic cross sections for neutron scattering on ¹³C have been calculated up to 10 MeV including excitations of the ¹²C core. The core properties are taken from experiment while the additional neutrons are described in a shell-model basis. Antisymmetrization between the valence particles and the core is taken into account as a second-order perturbation effect. All results including those for the target and the bound states of ¹⁴C are compared to experimental data. The differences between a gaussian and a δ interaction for the valence particles is investigated. The calculation was only feasible with a modified continuum shell model, i.e. approximating the single-particle resonances by bound states. The remaining modified continuum states are damped in amplitude within the resonance region. The residual interaction between modified continuum states is neglected.     

Preparation and structure of pyrazolo[3,4-d]pyrimidinones

By means of the reactions of 5-amino-1-phenyl-4-pyrazolecarbohydrazide 1 with aroylalkane- and (bi)cycloalkanecarboxylic acids, the tri-, tetra- and pentacyclic pyrazolo[3,4-d]pyrimidines 2–6 were prepared. The acetylhydrazide 1a reacted with levulinic acid to yield a pyrazoloazepinone 7, together with the pyrrolopyrazolopyrimidinone 8, by acylation of the primary amine following intramolecular cyclization involving either the pyrazole carbon or the hydrazide imino group. After separation, the structures of the new compounds were established by means of NMR measurements.     

Explicit treatment of internucleon P- and D-states in the calculation of the nucleon optical potential

Usual calculations of the nucleon optical potential using the Brueckner t-matrix treat the internucleon P- and D-states in a nuclear matter approximation. We use the method of Kisslinger to obtain the potential when P- and D-states are treated more precisely. We show phenomenologically that the effect of an explicit treatment of P-states is small, consistent with calculations indicating that the total P-state contribution to the t-matrix is small. This result provides additional verification that the Brueckner method is reasonably satisfactory. The potential obtained from an explicit treatment of the D-states is such that, although large, it can be reduced approximately to the form usually used. We show that the error in this approximation is not large though non-negligible when comparing calculated cross sections with experimental data. We also show that the P- and D-states corrections do not substantially affect phenomenological fits to experimental data.     

Response functions of 58Ni, 116Sn AND 208Pb to the excitation of intermediate-energy α-particles

Inelastic scattering of 340 MeV and 480 MeV α-particles has been measured on ⁵⁸Ni, ¹¹⁶Sn and ²⁰⁸Pb up to 60 MeV excitation energy. Consistent background subtraction and multipole analysis has provided the repartition of multipole strength for all three nuclei. The so-obtained response functions show the already known low-energy giant resonances in a detailed way, as well as new giant resonances at high energy.     

Catalytic Ferrier rearrangement of unsaturated nucleosides

The attempted intermolecular addition of malonyl radicals to 1′,2′-unsaturated nucleosides has led to the unexpected formation of furanones. Thus, only catalytic amounts of ceric(IV) ammonium nitrate (CAN), induce a Ferrier rearrangement. The unsaturated lactone was isolated in good yield and can serve as a precursor for the synthesis of optically active products.     

Observation of two-hole states at high excitation energy in (p,t) reactions

Bumps of two-hole states at high excitation energies were observed systematically in the triton spectra from (p, t) reactions with 52 MeV protons on nuclei in a broad range of masses. The cross sections of the bumps are almost equal for various targets with the same deep major shells. These cross sections vary discontinuously with variation of the corresponding deep major shell. About 20 to 50 % of the total expected strength is observed experimentally, if the bumps are assumed to arise from two-neutron pickup from the deep major shells. The centres of gravity of the bumps are located at excitation energies of about 7 to 9 MeV in all cases. On the other hand, the widths of the bumps change from about 3 MeV for ⁶⁶Zn to about 9 MeV for ²³⁰Th.     

High-spin yrast and non-yrast bands in 176Os, 178Os and 180Os

High-spin yrast and non-yrast states have been identified in ¹⁷⁶Os, ¹⁷⁸Os and ¹⁸⁰Os using (¹⁶O, xn) reactions, and γ-ray techniques. Band crossing anomalies are observed in each of the positive-parity yrast bands. The magnitude of these anomalies decreases with decreasing neutron number, an effect attributed to the change in the moment of inertia of the ground state rotational bands. A 23 ns isomer, predominantly K^π = 7^?, is identified at 1930 keV in ¹⁸⁰Os. The configuration of this isomer is discussed on the basis of the properties of its rotational band. Negative parity, odd and even spin, sideband sequences are observed in each isotope. Their relationship to rotation-aligned octupole and 2-quasiparticle bands is discussed from their excitation energies, band spacings, and decay properties. Detailed calculations for Coriolis mixed bands are carried out for the likely 2-quasiproton and 2-quasineutron configurations. An anomaly observed at spin 17 in the odd-spin negative-parity sequence in ¹⁸⁰Os is attributed to a band crossing with a fourquasiparticle configuration.