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31.
MDF materials are chemically bonded ceramic materials free of the macrodefects typical of hydraulic cement-based materials. MDF materials arising through reactions of sulfo-aluminate-ferrite belitic (SAFB) clinkers and/or Portland cements (PC) with two types of water-soluble polymer (hydroxy-propylmethyl cellulose {HPMC}, polyphosphate glass {poly-P}) are discussed. Mixes of low energy SAFB clinkers with Portland cement, HPMC and, especially poly-P comprise promising cross-linked compositions additional to the better known MDF materials formed from high alumina cement with polyvinylalcohol/acetate. The principles of co-ordination of P and C atoms (of the polymer) with Al and Fe atoms (originating from the cement) are highlighted from spectroscopic information on next-nearest-neighbour interactions, along with the effects of second co-ordination spheres. Polymers modify the interface through functional bonding/grafting of polymer chains onto the surfaces of cement grains. Both the cross-linked atomic structure and the interface coincide well with the model of functional polymers and represent a new type of atomic-level structure in polymer-modified cements. Interpretation is based on previous magnetic resonance and thermal analysis studies. The compactness of Al(Fe)-O-P cross-links reduces transport through the interfaces, increasing the interfacial interactions and resisting the unfavourable uptake of moisture and carbonation. 相似文献
32.
To improve aircraft crash safety, conditions critical to occupants survival during a crash must be known. In view of the importance of this problem, studies of post-crash dynamic behavior of victims are necessary in order to reduce severe injuries. In this study, crash dynamics program SOM-LA/TA, incorporating a dynamic model of the human body with a finite element model of the seat structure was used. Modifications were performed in the program for reconstruction of an occupant's head impact with the interior walls or bulkhead. A viscoelastic-type contact force model was used to represent the compliance characteristics of the bulkhead. Correlated studies of analytical simulations with impact sled test results were accomplished. A parametric study of the coefficients in the contact force model was then performed in order to obtain the correlations between the coefficients and the Head Injury Criteria. A measure of optimal values for the bulkhead compliance and displacement requirements was thus achieved in order to keep the possibility of a head injury as little as possible. This information could in turn be used in the selection of suitable materials for the bulkhead, instrument panel, or interior walls of an aircraft. 相似文献
33.
Bai-suo JIN~ 《中国科学A辑(英文版)》2007,50(9):1303-1315
In the factor analysis model with large cross-section and time-series dimensions,we pro- pose a new method to estimate the number of factors.Specially if the idiosyncratic terms satisfy a linear time series model,the estimators of the parameters can be obtained in the time series model. The theoretical properties of the estimators are also explored.A simulation study and an empirical analysis are conducted. 相似文献
34.
Rainer Picard 《Journal of Mathematical Analysis and Applications》2007,328(1):655-675
The Maxwell system in an anisotropic, inhomogeneous medium with non-linear memory effect produced by a Maxwell type system for the polarization is investigated under low regularity assumptions on data and domain. The particular form of memory in the system is motivated by a model for electromagnetic wave propagation in ferromagnetic materials suggested by Greenberg, MacCamy and Coffman [J.M. Greenberg, R.C. MacCamy, C.V. Coffman, On the long-time behavior of ferroelectric systems, Phys. D 134 (1999) 362-383]. To avoid unnecessary regularity requirements the problem is approached as a system of space-time operator equation in the framework of extrapolation spaces (Sobolev lattices), a theoretical framework developed in [R. Picard, Evolution equations as space-time operator equations, Math. Anal. Appl. 173 (2) (1993) 436-458; R. Picard, Evolution equations as operator equations in lattices of Hilbert spaces, Glasnik Mat. 35 (2000) 111-136]. A solution theory for a large class of ferromagnetic materials confined to an arbitrary open set (with suitably generalized boundary conditions) is obtained. 相似文献
35.
Dailly A. Schneider R. Billaud D. Fort Y. Ghanbaja J. 《Journal of nanoparticle research》2003,5(3-4):389-393
A novel chemical reduction method using an activated alkaline hydride (LiH or NaH-t-BuONa) in tetrahydrofuran solvent has been applied to antimony salt reduction. X-ray diffraction and transmission electron microscopy studies have been carried out to characterize the morphology and structure of the materials. Alkali hydride nature influence has been proved. In both cases the process allows to prepare antimony particles in nanometer range from few nanometers to about 20nm which could be used as anodic materials for lithium–ion batteries. With lithium hydride well-crystallized particles inclined to agglomeration were observed whereas finely dispersed amorphous particles were pointing out after activated sodium hydride reduction. 相似文献
36.
A. V. Kravtsov 《Computational Mathematics and Mathematical Physics》2007,47(11):1875-1884
A linear problem of parametric oscillations of a low-viscous two-layer fluid in a closed vessel partially filled with a porous medium is studied. An asymptotic solution is constructed on the basis of combined application of boundary functions and averaging methods. Approximate formulas for boundaries of instability domains in the case of subharmonic and harmonic resonances are derived. 相似文献
37.
Arman Melkumyan 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,58(2):330-349
The problem of electric and acoustic waves diffraction by a half-plane crack in a transversal isotropic piezoelectric medium
is investigated. The crack is assumed to be electric permeable and free of tractions. The so-called “quasi-hyperbolic approximation”
[15] is adopted. Applying Laplace transformations and Wiener–Hopf technique a closed form solution is obtained. By the means
of Cagniard–de Hoop method a detailed dynamic full electroacoustic wavefield’s investigation is conducted. Mode conversion
between electric and acoustic waves, effect of electroacoustic head wave, Bleustein–Gulyaev surface wave and the wavefield
structure depending on the type of the incident wave (acoustic or electric) and its angle of incidence are analyzed in details.
The dynamic field intensity factors at the crack tip depending on the angle of incidence and on time are derived explicitly.
Numerical analysis is presented. 相似文献
38.
Nanocrystalline FeS2 cathode material of lithium cell was synthesized from cheap materials of FeSO4, Na2S2O3, and sulfur by a hydrothermal process. The scanning electron microscopy analysis showed the obtained material was nano-sized,
about 500 nm. The X-ray powder diffraction analysis showed that the synthetic FeS2 material had two phases of the crystalline structure, pyrite and marcasite. The phase of marcasite seems to have no negative
effect on the electrochemical performance of the material. The synthetic FeS2 showed a significant improvement of electrochemical performance for Li/FeS2 cells. 相似文献
39.
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