全文获取类型
收费全文 | 2826篇 |
免费 | 285篇 |
国内免费 | 306篇 |
专业分类
化学 | 2150篇 |
晶体学 | 9篇 |
力学 | 209篇 |
综合类 | 47篇 |
数学 | 124篇 |
物理学 | 878篇 |
出版年
2024年 | 6篇 |
2023年 | 48篇 |
2022年 | 111篇 |
2021年 | 98篇 |
2020年 | 108篇 |
2019年 | 67篇 |
2018年 | 69篇 |
2017年 | 160篇 |
2016年 | 186篇 |
2015年 | 184篇 |
2014年 | 173篇 |
2013年 | 236篇 |
2012年 | 164篇 |
2011年 | 165篇 |
2010年 | 160篇 |
2009年 | 147篇 |
2008年 | 140篇 |
2007年 | 151篇 |
2006年 | 161篇 |
2005年 | 108篇 |
2004年 | 119篇 |
2003年 | 98篇 |
2002年 | 77篇 |
2001年 | 59篇 |
2000年 | 63篇 |
1999年 | 57篇 |
1998年 | 45篇 |
1997年 | 36篇 |
1996年 | 30篇 |
1995年 | 23篇 |
1994年 | 26篇 |
1993年 | 24篇 |
1992年 | 12篇 |
1991年 | 17篇 |
1990年 | 18篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1987年 | 5篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有3417条查询结果,搜索用时 78 毫秒
21.
Hee Seok Choi Young Han Kim Shun Myung Shin 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2428-2439
An in‐line monitoring device using a quartz crystal resonator for thin film polymerization was proposed, and its performance has been evaluated by implementing in the UV polymerization of 2‐hydroxyethyl methacrylate with a photoinitiator of 1‐chloroanthraquinone. Because the variation of resonant resistance of the resonator is proportional to the square root of viscosity change that is closely related to the polymerization degree, the resistance can be used as a measure of the polymerization degree. The resistance measurements were compared with the outcome of instrumental analyses of polymerization degree using an FTIR spectrometer and a gel permeation chromatograph. The experimental results showed that the resistance measurements were consistent with the experimental outcome of the instrumental analyses, and this indicates the effectiveness of the proposed device. Owing to the simplicity and availability of the resonator system, its wide utilization in the monitoring of a variety of film polymerization processes, including photoresistor application, is expected. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2428–2439, 2006 相似文献
22.
王世元 《分析测试技术与仪器》1996,2(1):28-32
为解决在线氧含量分析测试仪表常被聚合物堵塞的问题,提出了自动反吹的时序分配和实施控制方案,从而为安全生产提供了保障。 相似文献
23.
IntroductionInthepastdecade ,itwasfoundthattwoaminoacidresidues ,SerandHis ,workastheactivesitesintheser ineprotease .1 3 Inourpreviouswork ,adipeptideseryl histidine (Ser His)wasfoundtohavetheproteinandnu cleosidescleavageactivity .4 7p Nitrophenylacetate (p NPA)w… 相似文献
24.
25.
X. H. Liu M. Sun J. J. Yue Y. X. Yin X. L. Liu F. M. Miao 《Journal of Molecular Structure》2003,620(2-3):227-230
In this paper, we carried out a theoretical study on the active site structures of the Mn-SOD with ab initio Hartree–Fock SCF method, and analyzed the molecular orbital energies, charges and atomic orbital contribution to the frontier molecular orbital. 相似文献
26.
Maiorova N. A. Khazova O. A. Tarasevich M. R. 《Russian Journal of Electrochemistry》2004,40(10):1060-1065
The kinetics of the hydrogen oxidation and the CO adsorption on a Pt (ultra)microelectrode is studied in a 0.5 M H2SO4 solution saturated with a mixture of gaseous H2 and CO at partial CO pressures p
CO = 10–500 ppm. The balance between rates of diffusion and adsorption of CO at different adsorption times is studied. Studied is the effect of CO impurities in H2 on steady-state polarization curves for the hydrogen ionization and nonsteady-state curves of the oxidation current decay with time at 0.02–0.05 V. Conditions under which in a certain time interval and at a certain CO concentration the slope of an I vs. t curve is proportional to p
CO are determined. The obtained dependence may be used when designing a technique for monitoring CO impurities in technical hydrogen. 相似文献
27.
28.
Jocelyn Jalbert Roland Gilbert Pierre Tétreault Brigitte Morin Denise Lessard-Déziel 《Cellulose (London, England)》2007,14(4):295-309
In this study, headspace gas chromatography/mass spectrometry has been used to assess the volatile by-products generated by
the ageing of oil-impregnated paper insulation of power transformers. Sealed-glass ampoules were used to age under oxidative
conditions 0.5-g specimens of insulating paper in 9 mL of inhibited mineral oil in a temperature range of 60–120 °C and moisture
of 0.5, 1 and 2% (w/w). A linear relationship between one of the oil-soluble degradation by-products, i.e. methanol, and the
number of ruptured 1,4-β-glycosidic bonds of cellulose, regardless of the type of paper (ordinary Kraft or thermally-upgraded
(TU) Kraft paper), was established for the first time in this field. Ageing at 130 °C of model compounds of the Kraft paper
constituents (α-cellulose, hemicellulose and lignin) and two cellulosic breakdown by-products (D-(+)-glucose and 1,6-anhydro-β-d-glucopyranose) confirmed that the α-cellulose degradation was mostly responsible for the presence of this molecule in the
system. Furthermore, additional 130 °C-tests with six different papers and pressboard samples under a tight control of initial
moisture indicated that at least one molecule of methanol is formed for each rupture of 1,4-β-glucosidic bond of the molecular
chains. Stability tests showed that the ageing indicator is stable under the oxygen and temperature conditions of open-breathing
transformers. The presence of methanol was detected in 94% of oil samples collected from over than 900 in-service pieces of
equipment, confirming the potential for this application. Lastly, the tests have shown that oil-oxidation by-products and
TU-nitrogenous agents modify the methanol partitioning coefficients in the paper/oil/air system, which makes their study essential
over a range of field conditions encountered by power transformers. Results are presented and discussed in comparison with
2-furfuraldehyde, which is the current reference in the domain. 相似文献
29.
Susumu Narita Takeshi Hamakawa Tetsuo Morikawa Tai-ichi Shibuya 《Monatshefte für Chemie / Chemical Monthly》2002,133(7):987-990
Summary. The generalized Pauling bond order was enumerated in the C60 fullerene cage molecule (truncated icosahedral symmetry). This index measures chemical similarity in fullerene derivatives
such as dihydrofullerene (C60H2), anionized monohydrofullerene (C60H−), N-substituted monohydrofullerene (C59NH), the fullerene dimer ((C60)2), and the dianionic fullerene dimer ((C60)2
2−). It is also useful in judging the chemical stability of isomers.
Received October 9, 2001. Accepted November 9, 2001 相似文献
30.
GC-MS法测定焦化厂气溶胶中多环芳烃 总被引:2,自引:0,他引:2
利用气相色谱-质谱(GC-MS),电子轰击离子化(EI)法测定焦化厂气溶胶中多环芳烃的含量。超声波抽提气溶胶样品,用GC-MS的选择离子监测(SIM)方式测定EPA提出的优先监测的16种多环芳烃的含量。该法的检出限为0.167pg·m~(-3),PAHs的回收率为85.1%~110.5%,相对标准偏差为4.62%~19.4%。应用该法测定气溶胶中PAHs获得满意的结果。 相似文献