Equation of state for aqueous electrolyte systems based on the semirestricted non-primitive mean spherical approximation

The semirestricted non-primitive mean spherical approximation (npmsa) is used in combination with the PC-SAFT equation of state to model completely dissociating aqueous alkali halide systems. The salts are described using ion-specific parameters from tables and correlations. Upon analyzing aqueous electrolyte systems at infinite dilution of the salt it was concluded that for the arithmetic mean ion diameter of anion and cation, the semirestricted npmsa contribution gives no reliable results. Therefore, this parameter is adjusted in this work. The model was applied to aqueous alkali halide systems up to the solubility limit at T = 298.15 K. Mean ionic activity coefficients and osmotic coefficients were correlated with good results. The model was subsequently applied to temperatures up to T = 373.15 K and compared to liquid densities and to system pressures up to the solubility limit of the salts in water. The agreement between experimental data and the proposed equation of state is satisfactory for the liquid densities and excellent in case of the system pressures.     

衍生化分光光度法测定依诺沙星和诺氟沙星

碱性介质中,依诺沙星和诺氟沙星均能与1,2-萘醌-4-磺酸钠(NQS)发生反应而生成橙红色的物质,并使最大吸收波长发生大幅度的红移。据此建立了测定这两种药物的分光光度新方法。依诺沙星和诺氟沙星的浓度分别在0.8~16 mg.L-1和0.9~18 mg.L-1范围内符合比耳定律;衍生物在454 nm和462 nm波长处的表观摩尔吸光系数分别为1.86×104L.mol-1.cm-1和1.93×104L.mol-1.cm-1;两种药物的检出限分别为0.13 mg.L-1和0.19 mg.L-1。该方法已成功用于药物制剂中依诺沙星和诺氟沙星含量的测定。其回收率为96.63%~99.55%,相对标准偏差为0.56%~0.89%。     

Lifshitz black holes in the Hořava–Lifshitz gravity

We investigate the Lifshitz black holes from the Ho?ava–Lifshitz gravity by comparing with the Lifshitz black hole from the 3D new massive gravity. We note that these solutions all have single horizons. These black holes are very similar to each other when studying their thermodynamics. It is shown that a second order phase transition is unlikely possible to occur between z=3,2$z=3,2$ Lifshitz black holes and z=1$z=1$ Ho?ava black hole.     

Intermediate statistics as a consequence of deformed algebra

We present a formulation of deformed oscillator algebra which leads to intermediate statistics as a continuous interpolation between Bose-Einstein and Fermi-Dirac statistics. It is deduced that a generalized permutation or exchange symmetry leads to the introduction of the basic number and it is then established that this in turn leads to the deformed algebra of oscillators. We obtain the mean occupation number describing the particles obeying intermediate statistics which thus establishes the interpolating statistics and describe boson-like and fermion-like particles obeying intermediate statistics. We also obtain an expression for the mean occupation number in terms of an infinite continued fraction, thus clarifying successive approximations.     

Pricing European options with a log Student’s t-distribution: A Gosset formula

The distributions of returns for stocks are not well described by a normal probability density function (pdf). Student’s t-distributions, which have fat tails, are known to fit the distributions of the returns. We present pricing of European call or put options using a log Student’s t-distribution, which we call a Gosset approach in honour of W.S. Gosset, the author behind the nom de plume Student. The approach that we present can be used to price European options using other distributions and yields the Black-Scholes formula for returns described by a normal pdf.     

Evidence for energy regularity in the Mendeleev periodic table

We show that the dependence of the total energy of the atoms on their atomic number can follow a q-exponential (as proposed by C. Tsallis), for practically all elements of the periodic table. The result is qualitatively explained in terms of the way the atomic configurations are arranged to minimize energy.     

Variability of scaling parameters in non-conservative systems: Geophysical aspect

Newly obtained data on the critical dynamics of the drifting/fracturing sea ice in the Arctic Ocean were analyzed and compared with published data on the dynamic processes in the Earth’s crust. Substantial similarities were found in the scaling behavior of both geophysical systems; the most important of them is the b-value space/time variability including a pre-failure drop of this parameter. The b-value pattern of the ensemble of drifting ice floes is an analogue of the b-value distribution over areas and depths in tectonic structures. A common feature of the pre-failure state in the cryosphere and in the Earth’s crust is the increased degree of the energy conservation that manifests itself both in the sea ice consolidation prior to basin-wide ice pack fragmentations, and in involving harder geological formations in the fracture process before earthquakes, respectively. From the viewpoint of the conservative SOC concept, this relation between the system’s conservativity and the occurrence of large-scale fracture events means that the expected scale level of failure is determined by the system’s closeness to “true” SOC behavior.     

Prospects of reactor neutrino experiments

Since the energy of a reactor neutrino is a few MeV, all , and oscillations are accessible by reactor neutrino experiments. KamLAND observed the oscillation and currently Double Chooz, RENO and Dayabay experiments are under construction aiming to detect oscillation. There are still good prospects for future reactor neutrino experiments after them. For example, there is room to further improve sin²2θ₁₃ accuracy at a baseline of ∼1.5 km, a very precise sin²2θ₁₂ measurement and the determination of mass hierarchy may be possible at a baseline ∼50 km, and if KamLAND is enlarged to the SuperKamiokande size, better measurement of and sin²2θ₁₂ will be anticipated. It is important to take into account such possibilities when planning future neutrino program after θ₁₃ is measured by current experiments.     

Mean wind: Its velocity and temperature fluctuation in low-Prandtl-number thermal convection

Large-scale circulation in the confined thermal turbulence of mercury is studied experimentally. The instantaneous velocity profile at 128 points is directly measured using ultrasonic velocimetry and the temperature fluctuation is simultaneously obtained by a small thermistor at the cell center. The periodic velocity oscillation is observed for aspect ratios Γ=1,2, but for Γ=0.5. The temperature oscillation is confirmed only in the Γ=2 cell. It is found that the flow patterns depending on the aspect ratio are characterized sufficiently by the joint probability density function up to Ra=4×10⁸.