全文获取类型
收费全文 | 3970篇 |
免费 | 129篇 |
国内免费 | 197篇 |
专业分类
化学 | 856篇 |
晶体学 | 5篇 |
力学 | 47篇 |
综合类 | 21篇 |
数学 | 2034篇 |
物理学 | 1333篇 |
出版年
2023年 | 15篇 |
2022年 | 77篇 |
2021年 | 58篇 |
2020年 | 36篇 |
2019年 | 36篇 |
2018年 | 49篇 |
2017年 | 51篇 |
2016年 | 40篇 |
2015年 | 35篇 |
2014年 | 61篇 |
2013年 | 241篇 |
2012年 | 142篇 |
2011年 | 323篇 |
2010年 | 235篇 |
2009年 | 452篇 |
2008年 | 422篇 |
2007年 | 346篇 |
2006年 | 373篇 |
2005年 | 234篇 |
2004年 | 112篇 |
2003年 | 79篇 |
2002年 | 191篇 |
2001年 | 141篇 |
2000年 | 118篇 |
1999年 | 71篇 |
1998年 | 76篇 |
1997年 | 41篇 |
1996年 | 65篇 |
1995年 | 33篇 |
1994年 | 28篇 |
1993年 | 5篇 |
1992年 | 11篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 6篇 |
排序方式: 共有4296条查询结果,搜索用时 15 毫秒
31.
Ligia E. Zamora G. A. Perez Alcazar J. M. Greneche S. Suriñach 《Hyperfine Interactions》2006,168(1-3):1057-1063
Fe60Mn10Al20Nb10, (Fe60Mn10Al30)95Nb5 and (Fe60Mn10Al30)90Nb10 ball milled powdered alloys were investigated using X-ray diffraction, Mössbauer spectrometry, thermomagnetic (TGM) and magnetization measurements. We studied the influence of Nb content and of different milling times on the structural and magnetic properties. Two main features can be concluded: (1) the FeAlMn induces a BCC phase whatever the Nb content is, and (2) as both increasing Nb content and milling time give rise to an highly disordered state in conjunction with a decrease of the ferromagnetic behavior. 相似文献
32.
33.
34.
[Co(amp)2Cl2]2[ZnCl4]体系中两对称异构体的2D NMR研究 总被引:7,自引:0,他引:7
The two symmetrical isomers in [Co(amp)2Cl2]2[ZnCl4](amp=2-(Aminomethyl)pyridine) system were syn-thesized by general oxidation method and were separated by chromatography and recrystallization method. Their configurations were assigned by using 2D NMR techniques, particularly the NOESY NMR spectra. Solvent used was Me2SO-d6 with the central peak of the CD3 septet as the reference ( 13C,δ 39.37; 1H,δ 2.49 relative to SiMe4). Cation exchange media used was Dowex 50Wx 2(H+ form, 200~400mesh; Biorad). 相似文献
35.
36.
The geometries of the most stable isomers of gold telluride systems AuTe, Au2Te, and AuTe2 are determined using the MP2 method. The aspect of gold—telluride interaction, the electron correlation, and relativistic
effects on geometry and stability are investigated at the MP2 and CCSD(T) theoretical levels. The results show that the electron
correlation and relativistic effects are responsible not only for gold—gold attraction but also for additional gold—telluride
interaction. The gold—telluride interaction is strong enough to modify the known pattern of bare gold clusters. Both effects
are essential for determining the geometry and relative stability of this type of systems. 相似文献
37.
DFT calculations have been performed to determine the isomer shift for a series of iron(II) clusters with nitrogen-containing ligands which serve as models of coordination units in Fe(II) complexes with 1,2,4-triazoles possessing a 1 A 1 ? 5 T 2 spin transition. Good agreement has been found between the theoretical and experimental values of the isomer shift for both low-and high-spin phases. Our calculations confirmed the hypothesis about relationship between the experimentally observed differences in the isomer shift for the low-spin phases of the complexes and variations of the Fe-N mean bond length. 相似文献
38.
γ-芳基取代烯丙醇菊酯的合成及杀虫活性陈亚娟,黄润秋,马军安(南开大学元素有机化学研究所,天津,300071)关键词γ-芳基取代烯丙醇,拟除虫菊酯,杀虫活性第一个人工合成除虫菊酯烯丙菊酯保留了天然除虫菊酯醇部分的环戊烯醇酮结构,至今仍广泛用作卫生杀虫... 相似文献
39.
The stereochemistry of substituted cyclopent-2-en-1-ones was studied by NMR. The existence of non-planar rings is indicated and conformational analysis, based principally upon examination of the coupling constants enables the conformational population to be estimated; trans dihalogeno derivatives, for example, occur predominantly in the diaxial form. 相似文献
40.
An explicit expression for the analytical first derivative of the Z-averaged perturbation theory taken to second order energy, due to Lee and Jayatilaka, is presented for application to high-spin
systems described by a restricted open-shell Hartree–Fock wavefunction. The use of frozen core orbitals is incorporated into
the derivation.
Received: 23 April 2001 / Accepted: 31 August 2001 / Published online: 9 January 2002 相似文献