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81.
P. Terech 《Il Nuovo Cimento D》1994,16(7):757-764
Summary Viscoelastic solutions of a binuclear copper(II) tetracarboxylate (Cu2S8) in tert-butylcyclohexane (TBC) have been investigated by rheology and small-angle neutron scattering techniques. The data
are analysed in the theoretical framework of the so-called ?living polymers?. The Cu2S8 aggregates are semi-rigid thin heterogeneous molecular threads undergoing scission/recombination reactions. Structural and
dynamical correlations have been made with the thermotropic columnar phase and some lyotropic swollen mesophases of the system.
The simplicity of the composition and structural constitution enables to avoid the usual salt and composition problems of
the aqueous analogues and also to deduce some most probable behaviours related to the scission mechanisms, chain flexibility
and dynamics of stress relaxation.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994.
Member of CNRS. 相似文献
82.
Prof. A. D. Drozdov 《Archive of Applied Mechanics (Ingenieur Archiv)》1995,65(2):99-109
Summary Dynamic stability of an elastic bar with voids is considered. Using the Lyapunov approach some new sufficient stability conditions are obtained and explicit expressions for the critical load are derived. 相似文献
83.
该文通过构造特殊形式的有效集来逼近KKT点处的有效集,给出了一个任意初始点下的序列线性方程组新算法,并证明了该算法在没有严格互补松驰条件的情况下具有全局收敛性和一步超线性收敛性。
相似文献
84.
刘春平 《数学物理学报(A辑)》2004,4(6):661-668
该文给出了一种构造非线性发展方程显式行波解的方法并用该方法得到了Hirota-Satsuma方程组,一类非线性常微分方程以及广义耦合标量场方程组的显式行波解. 相似文献
85.
时贞军 《数学物理学报(A辑)》2004,4(6):675-682
该文提出一种无约束优化非线性共轭梯度法,证明了精确线性 搜索下的全局收敛性。当目标函数为一致凸函数时,证明了算法具有线性收敛速度。数值实验表明算法对于求解实际问题是有效的。 相似文献
86.
87.
本文我们利用一个可微函数给出了一对高阶对称规划问题 ,其中目标函数包含了Rn 中一紧凸集的支撑函数 .在引入高阶F 凸性 (F 伪凸性 ,F 拟凸性 )后 ,证明了高阶弱、高阶强及高阶逆对称对偶性质 . 相似文献
88.
提出了一种新结构的X波段五腔渡越管振荡器,进行了理论和实验研究。根据场分布进行了一维非线性分析,结果表明该结构可以产生高功率微波,并判断了工作模式,为TM01模的3π/5模。采用粒子模拟验证了一维非线性分析的结论,并优化设计出五腔渡越管振荡器,优化结果为:输出功率约1 GW, 工作频率9.3 GHz,束波转换效率约22%。实验中,通过参数调节,得到频率约9.25 GHz,峰值功率约780 MW,脉宽(半高宽)21 ns的输出微波,束波转换效率约为16%。实验结果与模拟结果基本符合。 相似文献
89.
The parameters that affect the shape of the band profiles of acido‐basic compounds under moderately overloaded conditions (sample size less than 500 nmol for a conventional column) in RPLC are discussed. Only analytes that have a single pKa are considered. In the buffer mobile phase used for their elution, their dissociation may, under certain conditions, cause a significant pH perturbation during the passage of the band. Two consecutive injections (3.3 and 10 μL) of each one of three sample solutions (0.5, 5, and 50 mM) of ten compounds were injected on five C18‐bonded packing materials, including the 5 μm Xterra‐C18 (121 Å), 5 μm Gemini‐C18 (110 Å), 5 μm Luna‐C18(2) (93 Å), 3.5 μm Extend‐C18 (80 Å), and 2.7 μm Halo‐C18 (90 Å). The mobile phase was an aqueous solution of methanol buffered at a constant WWpH of 6, with a phosphate buffer. The total concentration of the phosphate groups was constant at 50 mM. The methanol concentration was adjusted to keep all the retention factors between 1 and 10. The compounds injected were phenol, caffeine, 3‐phenyl 1‐propanol, 2‐phenyl butyric acid, amphetamine, aniline, benzylamine, p‐toluidine, procainamidium chloride, and propranololium chloride. Depending on the relative values of the analyte pKa and the buffer solution pH, these analytes elute as the neutral, the cationic, or the anionic species. The influence of structural parameters such as the charge, the size, and the hydrophobicity of the analytes on the shape of its overloaded band profile is discussed. Simple but general rules predict these shapes. An original adsorption model is proposed that accounts for the unusual peak shapes observed when the analyte is partially dissociated in the buffer solution during its elution. 相似文献
90.
Two series of tensile relaxation tests are performed on natural rubber filled with high abrasion furnace black. To fit observations, constitutive equations are derived for the nonlinear viscoelastic behavior of a particle-reinforced elastomer. A filled rubber is modeled as a composite medium, where inclusions with low concentrations of junctions are randomly distributed in the host matrix. The inclusions are treated as equivalent networks of macromolecules, where strands can separate from temporary junctions as they are thermally agitated. The bulk medium is thought of as a permanent network of chains. Unlike conventional concepts of transient networks, the concentration of strands in inclusions is assumed to be affected by mechanical factors: under active loading, inter-chain interactions weaken and some strands that were prevented from detachment from their junctions in a stress-free compound become free to separate from the junctions in a deformed medium. Unloading strengthens interactions between macromolecules, which results in an increase in the number of permanent strands. By using the laws of thermodynamics, stress–strain relations for a particle-reinforced rubber are developed. Adjustable parameters in the constitutive equations are found by fitting the experimental data. It is demonstrated that mechanical pre-loading and annealing of specimens at an elevated temperature noticeably affect concentrations of inclusions with various activation energies for rearrangement of strands. 相似文献