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991.
A. L. Jadhav K. P. Naikwadi S. Rokushika H. Hatano M. Ohshima 《Journal of separation science》1987,10(2):77-81
Liquid crystalline polyacrylates (LCPAs) are evaluated as stationary phases for capillary gas chromatography (CGC). Aromatic hydrocarbons as well as polar isomeric compounds are used as test solutes to compare the polarity of the LCPAs with a conventional polysiloxane column and a Carbowax 20M column. The relative polarity of the columns with respect to change in the lateral and terminal substituents is also discussed. Lateral substitution, polarity of the terminal group, together with the solute size, affect the LCPA selectivity. 相似文献
992.
993.
994.
We consider a system of Newtonian particles, with a long-range repulsive pair potential, moving in a cavity whose surface temperature is spatially varying. When a particle hits the surface, it is thermalized at the temperature of the collision point. We prove that this system has a unique stationary ensemble, to which any initial distribution converges for large times. We show that this stationary ensemble depends continuously on the surface temperature profile. 相似文献
995.
B. Wunderlich 《Journal of Thermal Analysis and Calorimetry》2007,89(2):321-356
This review traces the development of thermal analysis over the last 50 years as it was experienced and contributed to by
the author. The article touches upon the beginning of calorimetry and thermal analysis of polymers, the development of differential
scanning calorimetry (DSC), single-run DSC, and other special instrumentations, up to the recent addition of modulation to
calorimetry and superfast calorimetry.
Many new words and phrases have been introduced to the field by the author and his students, leaving a trail of the varied
interests over 50 years. It began with cold crystallization and more recently the terms oriented, intermediate phase, glass
transitions of crystals, and decoupled chain segments were coined. In-between the following phenomena were named and studied:
extended-chain crystals, irreversible thermodynamics of melting of polymer crystals, zero-entropy-production melting, dynamic
differential thermal analysis (DDTA), the rule of constant increase of C
p per mobile bead within a molecule at the glass transition temperature, superheating of polymer crystals, melting kinetics,
crystallization during polymerization, chin-folding principle, molecular nucleation, rigid amorphous phase, system of classifying
molecules, macroconformations, amorphous defects, rules for the entropy of fusion based on molecular shape and flexibility,
single-molecule single-crystals, systems for classifying phases and mesophases including condis phases, and the globally metastable
semicrystalline polymers with reversible, local subsystems.
This review is update of a publication written in 1995 and published under the same title in the J. Thermal Anal., 46 (1996)
643. Parts F and G are fully new, and Part G is the basis for my lecture: ‘The development of the idea of thermodynamic decoupling
in macromolecules’. 相似文献
996.
The Laves phase structures (MgCu2 MgZn2 and MgNi2 types) are adopted by a large number of binary intermetallic compounds of composition AB2. These phases belong to the class of tetrahedrally closepacked alloys. Two of the structural features of the Laves phases which have aroused interest are, firstly the dependence of the structure adopted (especially the choice between the cubic MgCu2 and hexagonal MgZn2 types) on the number of valence electrons of the constituent metal atoms and, secondly the structural distortions observed in a number of the hexagonal MgZn2 type phases. By performing extended Hückel band calculations on model AB2 compounds with both the cubic and hexagonal structures and on the B sub-nets alone, structure electron-count and deformation-electron count correlations are derived. These correlations depend on the highly peaked nature of the density of states of the Laves phases, primarily due to the B network. 相似文献
997.
998.
Arthur J. Frank 《Molecular Crystals and Liquid Crystals》2013,570(1):341-352
Surface-attached polypyrrole films have been shown to produce a marked improvement in the stability of n-type single-crystal and polycrystalline Si against oxidation in an aqueous electrolyte. The current production of n-type polycrystalline Si coated with polypyrrole deteriorates less than 30% during 122 hr of irradiation whereas the unprotected bare electrode stops producing photocurrent within 30 s. The polymer protection of the n-type single-crystal Si is significantly less than that of the polycrystalline material because of differences in the adhesion of the polymer film to the electrode surfaces. The adhesion strength is shown to depend on various surface properties of Si and other electrode materials. Moreover, the surface morphology of the electrode affects the topography of the growing surface of the polypyrrole film. Requirements are discussed for the applications of organic conducting polymers to photoelectrochemical devices utilized for solar energy conversion. 相似文献
999.
T. Skotheim O. Inganäs J. Prejza I. Lundström 《Molecular Crystals and Liquid Crystals》2013,570(1):329-339
Abstract A new approach is given for obtaining fast electro-optical response and good angular-viewing characteristics in a liquid-crystal variable-retardation device. The improved characteristics make the new device well suited for use in field-sequential color systems. 相似文献
1000.
《Journal of separation science》2018,41(13):2710-2718
In this work, a novel single sulfoether‐bridged cationic per(3,5‐dimethyl)phenylcarbamoylated‐β‐cyclodextrin separation material was prepared by thiol‐ene click chemistry and characterized by using FTIR spectroscopy, solid‐state 13C NMR spectroscopy and elemental analysis, which confirmed the correct structure. The separation material exhibited a good achiral separation performance for benzene homologues and phenylamine analogs, especially o‐xylene and m‐xylene, and m‐phenylenediamine and o‐phenylenediamine can be discriminated by the (3,5‐dimethyl)phenylcarbamoyl cyclodextrins. The chiral resolving ability of the separation material was evaluated by discriminating various isoxazolines, flavonoids, and β‐blockers in reversed‐phase high‐performance liquid chromatography. For isoxazolines, the material showed the best chiral discrimination toward 3‐aryl‐5‐(2‐oxopyrrolidin‐1‐yl)‐isoxazolines, where the resolution for 3ClPh‐OPr reached 6.03. For flavonoids, it exhibited more efficient separation to the ones with more hydrophobic substituents, with a resolution of 5.93 for 6‐hydroxyflavanone. β‐Blockers were also enantioseparated satisfactorily on the material. The as‐prepared separation material is a good member of the thiol‐ene click derived cyclodextrin stationary phase family. 相似文献