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Robin Guthardt Jan Oetzel Julia I. Schweizer Clemens Bruhn Robert Langer Martin Maurer Jan Vícha Pavletta Shestakova Max C. Holthausen Ulrich Siemeling 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(5):1401-1405
The N‐heterocyclic plumbylene [Fe{(η5‐C5H4)NSiMe3}2Pb:] is in equilibrium with an unprecedented dimer in solution, whose formation involves the cleavage of a strong C?H bond and concomitant formation of a Pb?C and an N?H bond. According to a mechanistic DFT assessment, dimer formation does not involve direct PbII insertion into a cyclopentadienyl C?H bond, but is best described as an electrophilic substitution. The bulkier plumbylene [Fe{(η5‐C5H4)NSitBuMe2}2Pb:] shows no dimerization, but compensates its electrophilicity by the formation of an intramolecular Fe?Pb bond. 相似文献
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