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91.
通过溶剂热法控制合成了花生形氧化锌纳米材料,并利用扫描电子显微镜(SEM)、X射线粉末衍射仪(XRD)和傅里叶变换红外光谱(FTIR)对材料进行了表征和分析.循环伏安和Nyquist测试结果表明,该材料具有良好的电化学导电性,且对对硝基苯酚(p-NP)具有良好的选择性.侧分脉冲伏安法(DPV)测试结果表明,在p-NP浓度为0.8~24μmol/L和32~80μmol/L这2个浓度范围内,电流强度与浓度呈线性关系,通过3倍信噪比计算得出检测限分别为0.25和0.61μmol/L.该材料修饰的电极具有良好的稳定性和重现性,用于实际样品中p-NP含量的测定显示出优良的效果. 相似文献
92.
93.
In this paper, we report a facile solvothermal route capable of aligning MnOOH nanocrystals on graphene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) observations indicate that the exfoliated graphene sheets are decorated randomly by MnOOH nanocrystals, forming well-dispersed graphene-MnOOH nanocomposites. Dissolution-crystallization and oriented attachment are speculated to be the vital mechanisms in the synthetic process. The attachment of additives, such as MnOOH nanoparticles, are found to be beneficial for the exfoliation of GO as well as preventing the restack of graphene sheets. Moreover, cyclic voltammetry (CV) analyses suggest that the electrochemical reversibility is improved by anchoring MnOOH on graphene. Notably, the as-fabricated nanocomposites reveal unusual catalytic performance for the thermal decomposition of ammonium perchlorate (AP) due to the concerted effects of graphene and MnOOH. This template-free method is easy to reproduce, and the process proceeds at a low temperature and can be readily extended to prepare other graphene-based nanocomposites. 相似文献
94.
The reaction of the Na2MoO4 or Na2WO4 salt with organic amine and PCl5, SiCl4 or TiCl4 in hydrochloric acid medium under hydrothermal conditions yields organic–polyoxometallate hybrid compounds, with the following reaction formula: Na2MO4 + Lewis-base + XCln + HCl → (Lewis-baseH)m(XM12O40) + NaCl + H2O (M = Mo or W; X = P, Si, Ti,; n = 3–5). By using this method, four new complexes, [(CH3)2NH]3[H3PW12O40] (1), (C2H5OH)3(H3PMo12O40) (2), [DMDA]2[H4SiW12O40]·H2O (3) (DMDA = 1 N,3 N-dimethyl-1,3-diazolidine) and [(DAN)6][H4TiW12O40]·4H2O (DAN = 4,4′-dianiline) (4), were obtained, and their crystal structures are reported. Thermal analysis of 1, 2 and 4 has been carried out. The thermal analysis indicates that the Keggin anion skeleton begins to decompose at about 300 °C. The possibility of constructing hydrogen-bond interactions by association between the polyoxometallate and the organic compound is explored. The roles of solvents and organic groups in the formation of specific crystalline architectures are discussed. The crystal structure of [H4TiW12O40], a hetero-transition-metal Keggin polyoxometallate with a square-plane TiO4, has been reported. Four architectures developed by hydrogen-bond associations of different Keggin polyoxometallates and organic bearing N–H or O–H donor functions are described. The selected organic modules (4,4′-dianiline, 1,3-dimethylimidazolidine, dimethylamine and ethanol) possess hydrogen-donor functions to allow them to act as bridges between polyoxometallate groups. Depending on the nature of the donor group, the number of hydrogens available for bonding, the geometric features and the sizes of the organic modules, diverse assembling patterns have been observed ranging from one-dimensional to three-dimensional networks. For all the networks, H3O+ and H+ act as actual linkers between the molecular units. 相似文献
95.
This paper reports the synthesis of ZnS:Mn nanocrystals by the chemical route in which mercaptoethanol was used as the capping agent. The particle size of such nanocrystals was measured using XRD and TEM patterns and was found to be in between 3and 5 nm. It was found that the peak position of TL glow curve and the TL intensity of ZnS:Mn nanoparticles increases as the particle size is decreased. The isothermal decay technique is used to determine the trap-depth. The stability of the charge carriers in the traps increase with the decrease in size of the nanoparticles. The higher stability may be attributed to the higher surface/volume ratio and also to the increase in the trap-depth with decreasing particle size. When a ZnS:Mn nanocrystal is deformed the peak intensity Im increases linearly with the increasing height of the load. After Im, initially the ML intensity decreases at a fast rate, and later on it decreases at a slow rate. The ML in ZnS:Mn nanocrystals can be understood on the basis of the piezoelectrically induced electron detrapping model. 相似文献
96.
For astrophysical processes nuclear reactions close to the particle emission threshold are of particular importance. As representative examples we investigate pairing resonances and new low-energy multipole modes in light and heavy exotic nuclei with a large charge asymmetry. As a common theoretical background, density functional theory and Fermi Liquid Theory are used. In particular, we consider the spectroscopy particle unstable systems, carrying the properties of open quantum systems. Results for the continuum spectroscopy of 10Li, the neutron-rich carbon isotopes, and the electromagnetic response of Sn-isotopes 138Ba are presented. 相似文献
97.
HU Fang ZHANG Chun-hua ZHANG Song MING Xing CHEN Gang WEI Ying-jin WANG Chun-zhong . School of Materials Science Engineering Shenyang University of Technology Shenyang P. R. China . College of Physics State Key Laboratory of Superhard Materials Jilin University Changchun . College of Physical Science Technology Huanggang Normal University Huanggang 《高等学校化学研究》2011,(3):528-530
1 Introduction Low-dimensional nanostructures, such as nanorods, nanowires, and nanotubes, have received much attention for their superior optical, electrical, catalytic and magnetic properties. 相似文献
98.
A need for rapid toxicity techniques has seen recent research into developing new microbiological assays and characterising their toxicity responses using a range of substances. A microbiological bioassay that determines changes in ferricyanide-mediated respiration for toxicity measurement (FM-TOX) shows particular promise. The development and optimisation of an improved FM-TOX method, incorporating novel features, is described using Escherichia coli as the biocatalyst. Omission of an exogenous carbon source, used in previously described FM-TOX assays, substantially improves the assay sensitivity. In addition, the development of a two-step procedure (toxicant exposure followed by determination of microbial respiratory activity) was found to enhance the inhibition of E. coli by 3,5-dichlorophenol and four other toxicants, compared to single-step procedures. Other assay parameters, such as the ferricyanide concentration, exposure times and optical density of the biocatalyst were also optimised, sometimes based on practical aspects. Toxicity tests were carried out using the adopted technique on both organic and inorganic toxicants, with classic sigmoid-shaped dose-response curves observed, as well as some non-standard responses. IC50 data is presented for a number of common toxicants. The optimised assay provides a good foundation for further toxicity testing using E. coli, as well as the potential for expanding the technique to utilise other bacteria with complementary toxicity responses, thereby allowing use of the assay in a range of applications. 相似文献
99.
Li-Xian Sun A.Mahipal Reddy Akiko Takatsu Tatsuhiro Okada 《Analytica chimica acta》2003,487(1):109-116
A slab optical waveguide (SOWG) has been used for study of adsorption of both methylene blue (MB) and new methylene blue (NMB) in liquid-solid interface. Adsorption characteristics of MB and NMB on both bare SOWG and silanized SOWG by octadecyltrichlorosilane (ODS) were compared. The simultaneous determinations of both MB and NMB were explored by flow injection SOWG spectrophotometric analysis and artificial neural networks (ANNs) for the first time. Concentrations of MB and NMB were estimated simultaneously with the ANNs. Results obtained with SOWG were compared with those got by conventional UV-visible spectrophotometry. 相似文献
100.
Yuan-ming Wang 《计算数学(英文版)》1998,(4)
1.IntroductionInstudyingsomeproblemsarisinginelectromagnetism,biology)astronomy,bound-arylayerandothertopics,weoftenmeetnonlineartwo--pointsboundaryproblem,i.e.,findingyECo[0,11nC2(0,1)suchthatwhereor,garecertainconstants,andf(x,z)EC'(0,1)xC'(--co,co).Undersomeconditionsonf(x,z),wecanusetheframeworkof[1]toinvestigatetheexistenceanduniquenessofitssolutions.Alsotherearealotofliteratureconcerningitsnumericalsolutio.s[2--'].Inparticular,N..ero.15]proposedafamousfinitedifferenceschemewiththeaccu… 相似文献