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881.
The flexible chemical composition of the frameworks with tunable pore size and geometry of molecular dimensions makes zeolites widely used in chemical and petrochemical industry fields. The understanding of crystallization mechanism is important for a rational design of new zeolite with target structure and property, which however is still a big challenge in the field of material science. In this work, the specific spatial correlations/interactions between the SiO-···HO―Si hydrogen bonds within the charged framework of silicalite-1 (MFI topology) zeolite and the alkyl chains of tetrapropylammonium ion (TPA+) organic structure direction agents (OSDAs) were studied by one-dimensional (1D) and two-dimensional (2D) solid state-NMR spectroscopy in combination with other techniques, with the aim to shed light into the crystallization mechanism of silicalite-1. The "solvent-free" route was used to study the crystallization process. Silicalite-1 crystals were also prepared following the hydrothermal synthesis route. The structural properties of as-synthesized TPA-silicalite-1 samples during the crystallization were characterized by XRD and scanning electron microscopy (SEM) images, which showed the evolution of long-range periodic structure and cyrtal growth. The 1H-29Si CP/MAS NMR experiments showed that the reorganization of the silica or silicates occurred in the crystallization process. The lH-13C CP/MAS NMR experiments performed on the samples synthesized with different time indicated that the TPA+ ions in the amorphous samples experienced a constrained environment, forming the inorganic-organic composites. The splitting of the methyl carbon signal from TPA+ ions was observed in the 13C NMR spectra, which is the direct reflection of the interactions between the methyl groups and the silicate framework in the straight and zig-zag channels of silicalite-1. Two types of SiO-···H―OSi hydrogen bonds (SiO-···H―OSi hydrogen bond in-cage and SiO-···H―OSi hydrogen bond between lamellae) have been identified by 2D 1H double quantum (DQ)-single quantum (SQ) MAS NMR and 2H MAS NMR during the crystallization of silicalite-1. The SiO-···H―OSi hydrogen bonds between lamellae are formed and gradually transformed into the in-cage ones during the crystallization process. Their functions have been revealed in the formation of silicalite-1: the SiO-···H―OSi hydrogen bond in-cage provides the stereoscopic counterbalance for the positive charges from TPA+ ions and this stereoscopic electrostatic interaction is the key factor to transform inorganic-organic composites with the MFI structure property, even though the long-range periodic MFI structures have not been established yet; the SiO-···H―OSi hydrogen bond between lamellae acts as a connector to assemble the silicate species together to generate the zeolite framework. 2H MAS NMR spectra show that the SiOH nests exist in the zeolite framework even though the long-range periodic structures have been fully established. 相似文献
882.
《中国化学快报》2020,31(7):1951-1955
Zeolites have been widely applied in many chemical processes owing to their featured microporous framework structures. Organic structure-directing agents (OSDAs) play an important role during of the formation of zeolite frameworks via non-bonding host-guest interactions. Understanding these interactions is crucial to the design of OSDAs and the synthesis of target zeolites. Here, we report a molecular simulation study in the host-guest interactions between zeolite framework STW and 21 alkylated imidazolium and pyrazolium cations that have been used as the OSDAs for the synthesis of STW-type zeolites. We find that OSDAs that have successfully directed the formation of STW exhibit stronger host-guest interactions than unsuccessful ones. Furthermore, we find all successful OSDAs possess relatively more negative atomic charges on nitrogen atoms and smaller dipole moments. According to this finding, we have designed seven new alkylated imidazolium and pyrazolium cations that may be suitable for zeolite STW, and verified their structure-directing capability by molecular simulation calculations. 相似文献
883.
随着人们消费观念的升级,食品包装材料备受关注。从化学元素的视角介绍了新型食品外包装材料和食品表面可食性涂膜包装材料的组成、特点及发展趋势。食品外包装制品材料中的纳米材料和生物基材料因机械性能好、绿色环保等特点,深受消费者欢迎。而食品表面可食性涂膜材料,在“即时消费”兴起的今天,也因操作简便、投资低、安全性高等特点赢得了大众的喜爱。从新型食品包装材料的研制开发过程来看,其创新发展与化学元素的性质密切相关,未来食品包装材料性能的提升也必须依靠特征性化学元素的组合与利用。 相似文献
884.
Well-dispersed BaSO4 nanoparticles were synthesized in the presence of sodium polyacrylate (PAAS) by a simple precipitation method, with BaCl2 and (NH4)2SO4 as reactants. The different roles performed by PAAS in the synthesis of BaSO4 nanoparticles were investigated using X-ray diffractometry, Fourier transform infrared spectroscopy, and transmission electron microscopy. The results indicate that the assynthesized BaSO4 nanoparticles were spheres with an average diameter of 30 nm and that their surfaces were affected by the PAAS. Under a typical procedure employed, PAAS reacted with BaCl2 to yield an intermediate, serving as a control releasing agent and separating the nucleation and crystal growth processes of the BaSO4 nuclei. During formation of the BaSO4 nanospheres, the intermediate slowly dissolved and released barium and polyacrylate ions, inhibiting the growth and aggregation of newly formed BaSO4 seeds and resulting in particles of narrow diameter distribution and improved dispersibility. Moreover, these polyacrylate ions further modified the surfaces of the BaSO4 nanoparticles. 相似文献
885.
886.
Kirschner R Varga-Szemes A Brott BC Litovsky S Elgavish A Elgavish GA Simor T 《Magnetic resonance imaging》2011,29(5):650-658
Introduction
A substantial, common shortcoming of the currently used semiautomated techniques for the quantification of myocardial infarct with delayed enhancement magnetic resonance imaging is the assumption that the whole myocardial slab that corresponds to the hyperenhanced tomographic area is 100% nonviable. This assumption is, however, incorrect. To resolve this conflict, we have recently proposed the signal intensity percent-infarct mapping method and validated it in an ex vivo, canine experiment. The purpose of the current study has been the validation of the signal intensity percent-infarct mapping method in vivo, using a porcine model of reperfused myocardial infarct.Methods
In swines (n=6), reperfused myocardial infarct was generated occluding for 90 min by an angioplasty balloon either the left anterior descending or the left circumflex coronary artery. To obtain DE images, Gd(DTPA) enhanced inversion-recovery fast gradient-echo acquisitions were carried out on day 28 after myocardial infarction. Scanning started 15 min after intravenous injection of 0.2 mmol/kg Gd(DTPA). At the end of the MRI session, the animal was sacrificed and 2,3,5-triphenyltetrazolium chloride staining was used to validate the existence and to determine the accurate size of the myocardial infarct. Tissue samples were taken and stained with hematoxylin-eosin and Masson's trichrome for histological assessment of the infarct and the periinfarct zone. The signal intensity percent-infarct mapping data were compared with corresponding data from the delayed enhancement images analyzed with SIremote+2S.D. thresholding, and with corresponding triphenyltetrazolium-chloride staining data using Friedman's repeated measure analysis of variance on ranks.Results
The infarct volume determined by the triphenyltetrazolium chloride, SIremote+2S.D. and signal intensity percent-infarct mapping methods was 3.04 ml [2.74, 3.45], 13.62 ml [9.06, 18.45] and 4.27 ml [3.45, 6.33], respectively. Median infarct volume determined by SIremote+2S.D. significantly differed from that determined by triphenyltetrazolium chloride (P<.05). The Bland-Altman overall bias was 12.49% of the volume of the left ventricle. Median infarct volume determined by signal intensity percent-infarct mapping, however, did not differ significantly (NS) from that obtained by triphenyltetrazolium chloride. Signal intensity percent-infarct mapping yielded only a 1.99% Bland-Altman overall bias of the left ventricular volume.Conclusions
This in vivo study in the porcine reperfused myocardial infarct model demonstrates that signal intensity percent-infarct mapping is a highly accurate method for the determination of the extent of myocardial infarct. MRI images for signal intensity percent-infarct mapping are obtained with the pulse sequence of conventional delayed enhancement imaging and are acquired within clinically acceptable scanning time. This makes signal intensity percent-infarct mapping a practical method for clinical implementation. 相似文献887.
采用溶胶-凝胶法,以聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物(P123)为模板剂,合成了纳米孔硅灰石(np-WT),用np-WT载盐酸万古霉素研制了一种新型的载药抗菌止血材料,并对其止血性能进行了研究。结果表明:np-WT具有排列有序的纳米孔道结构,其孔径在2 nm左右,高比表面积的np-WT能够明显地缩短体外部分凝血活酶时间(APTT)和凝血酶原时间(PT)。载药np-WT能够在磷酸缓冲溶液(PBS)中缓慢地释放药物,载药np-WT对其凝血性能没有明显的影响。载药np-WT对大肠杆菌有很好的抗菌作用,细胞毒性实验表明:载药np-WT无细胞毒性。载药np-WT具有很好的止血性能,能够阻止兔背部伤口的流血和缩短其流血时间。 相似文献
888.
制备了正极中只含有一种导电剂(KS-6或Super-P)的锂离子电池,比较了它们的倍率放电性能并对放电过程进行了模拟。以Super-P为正极导电剂的电池15C放电容量为1C容量的84.3%,以KS-6为正极导电剂的电池15C放电容量为1C容量的21.8%,前者的倍率放电性能明显优于后者。数学模拟结果显示,以KS-6为导电剂的正极的Bruggeman系数为3.1,以Super-P为导电剂的正极的Bruggeman系数为2.76,前者明显大于后者,认为这是由于KS-6的片状形貌使其容易相互平行排列造成的。大电流放电时,以KS-6为导电剂的正极中出现了电解质耗竭而导致该区域内电化学反应停止的现象,从而导致电池放电容量急剧降低。 相似文献
889.
Vivek K. Srivastava Madhuchhanda Maiti Raksh V. Jasra 《European Polymer Journal》2011,47(12):2342-2350
The cyclodimerization of 1,3-butadiene was performed to synthesize 1,5-cyclooctadiene by using nickel-phosphite based catalyst system. The optimization of cyclodimerization reaction was done to achieve up to 80% selectivity towards 1,5-cyclooctadiene. 1,5-Cyclooctadiene, thus synthesized, was subsequently employed as a chain transfer agent (CTA) for controlling the molecular weight (M.W.) of cis-polybutadiene rubber (BR) in cobalt-complex catalyzed 1,3-butadiene polymerization reaction. The M.W. of BR was reduced from 6.7 to 1.88 × 105 g/mol by escalating the concentration of 1,5-cyclooctadiene from 0% to 0.5% with respect to 1,3-butadiene (monomer) concentration. Similar reducing trend was observed for the Mooney viscosity and gel content of BR with increasing 1,5-cyclooctadiene concentration. The efficacy of 1,5-cyclooctadiene as a CTA for 1,3-butadiene polymerization reaction was further explored by conducting polymerization reaction in various solvents and at higher monomer conversion (∼70%). The effect of 4-vinyl cyclohexene, which was a dominant byproduct during cyclodimerization of 1,3-butadiene, was also investigated. The presence of 4-vinyl cyclohexene has shown adverse effect in the polymerization reaction and was not functioning as a chain transfer agent. Finally, a feasibility of replacement of commercially used gaseous CTA, 1,2-butadiene, by in-house synthesized liquid CTA, 1,5-cyclooctadiene, was also investigated. 相似文献
890.