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81.
Runqing Ou Rosario A. Gerhardt Robert J. Samuels 《Journal of Polymer Science.Polymer Physics》2003,41(8):823-841
The relationships of the structure and electrical properties of anisotropic HCl‐doped polyaniline (PANI) films cast from N,N′‐dimethylpropylene urea (DMPU) solutions and stretched to different draw ratios were studied. The anisotropic structure of the stretched PANI films was examined by X‐ray diffraction, near‐infrared wave‐guide coupling, and polarized infrared measurements. The PANI emeraldine base (EB) films cast from DMPU solutions had a single‐phase noncrystalline structure, and stretching of the films did not cause crystallization to occur. The transition moment angles of two weakly absorbing infrared bands were determined, and the Hermans' orientation functions for the PANI EB films were calculated. The PANI films were then doped with HCl, and the electrical properties were determined by impedance spectroscopy. With a specially designed test fixture, the in‐plane and through‐plane impedance was obtained. The conductivity along the stretch direction increased with orientation. The in‐plane conductivity was significantly higher than the through‐plane conductivity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 823–841, 2003 相似文献
82.
B. Hannoyer A. A. M. Prince M. Jean R. S. Liu G. X. Wang 《Hyperfine Interactions》2006,167(1-3):767-772
Crystalline LiFePO4 has been synthesized using solid-state, spray pyrolysis, and wet chemical methods. The crystal parameters were obtained from Rietveld’s refinement methods of the X-ray diffraction patterns. A detailed investigation of the Fe valency carried out using Mössbauer spectroscopy at room temperature indicates that Fe is predominantly present in its bivalent state. 相似文献
83.
Frank Rutz Martin Koch Shilpa Khare Martin Moneke Heike Richter Uwe Ewert 《International Journal of Infrared and Millimeter Waves》2006,27(4):547-556
We report on experiments that evaluate the potential of terahertz (THz) time-domain spectroscopy (TDS) for quality control
of polymeric compounds. We investigate specimens out of a polyethylene compound with silver-coated titanium dioxide nanospheres
and a glass-fiber reinforced epoxy composite. We further examine an industrial polymer product produced by injection molding.
Our data demonstrates that THz imaging is a powerful tool for contactless quality control in the polymer industry. 相似文献
84.
A. Paesano Jr. S. C. Zanatta S. N. De Medeiros L. F. CÓtica J. B. M. Da Cunha 《Hyperfine Interactions》2005,161(1-4):211-220
We have investigated the mechanosynthesis of gadolinium and yttrium iron garnets by high-energy ball-milling of α-Fe2O3 and Gd2O3 or α-Fe2O3 and Y2O3, respectively, followed by short thermal annealings conducted at moderate temperatures. The samples were characterized by X-ray diffraction and Mössbauer spectroscopy, in order to determine the influence of the milling time and annealing conditions on the final products. For as-milled samples of each rare-earth system, the results revealed the formation of perovskite phases, in relative amounts that depend on the milling time. The formation of garnet phases was observed in as-annealed samples treated at 1000°C for 2 h or 1100°C for 3 h, i.e., at very modest annealing requirements when compared with ordinary solid-state-reaction processes performed without previous high-energy milling. Also, the occurrence was verified of a milling time for which the relative amount of garnet phases formed by annealing was maximized. This time depends on the rare-earth composing the garnet phase and on the annealing temperature. 相似文献
85.
Andreas Wallner Margit Hölbling Judith Baumgartner Christoph Marschner 《Silicon Chemistry》2007,3(3-4):175-185
A number of cyclo-and bicyclosilanes have been prepared and structurally characterized by X-ray crystallography and Raman
spectroscopy. 1,1,4,4- and 1,1,3,3-tetrakis(trimethylsilyl)octamethylcyclohexasilanes were found to exhibit unusual twist- and twisted boat-conformations. The UV absorption properties of all compounds were studied and found to show absorption maxima red shifted
compared to the parent compound dodecamethylcyclohexasilane.
Dedicated to Prof. Mitsuo Kira on the occasion of his reception of the Wacker Silicon Award 2005 and in recongnition of his
numerous outstanding achievements in organosilicon chemistry. 相似文献
86.
R. I. Jalmakhanbetova V. A. Raldugin I. Yu. Bagryanskaya Yu. V. Gatilov M. M. Shakirov G. A. Atazhanova S. M. Adekenov 《Chemistry of Natural Compounds》2007,43(5):552-554
Adducts of dihalocarbenes generated from chloroform and bromoform were prepared by reaction with estafiatin guaianolide. Their
structures were established by XSA.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 453–455, September–October, 2007. 相似文献
87.
E. Manova C. Estournès D. Paneva J.-L. Rehspringer T. Tsoncheva B. Kunev I. Mitov 《Hyperfine Interactions》2005,165(1-4):215-220
Iron–nickel spinel oxide NiFe2O4 nanoparticles have been prepared by the combination of chemical precipitation and subsequent mechanical milling. For comparison, their analogue obtained by thermal synthesis is also studied. Phase composition and structural properties of iron–nickel oxides are investigated by X-ray diffraction and Mössbauer spectroscopy. Their catalytic behavior in methanol decomposition to CO and methane is tested. An influence of the preparation method on the reduction and catalytic properties of iron–nickel samples is established. 相似文献
88.
I. Souza Azevedo E. Baggio Saitovitch M. Hücker B. Büchner H. Micklitz 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(3):313-315
57Fe M?ssbauer effect studies of La1.65Eu0.20Sr0.15CuO4 doped with 0.5 at% 57Fe performed in the temperature region 300 K >
T
> 4.2 K give an onset temperature for magnetic ordering of K. This temperature practically is the same as that found in Nd doped La2-xSrxCuO4. It indicates that the magnetic ordering temperature in the LTT phase of rare earth (RE) doped La2-xSrxCuO4 is independent of the RE moment. The direction of the 57Fe magnetic moment in the magnetically ordered state is within the CuO2 plane, while it has been found to be parallel to the c-axis in Nd doped La2-xSrxCuO4.
Received: 23 June 1998 / Accepted: 14 July 1998 相似文献
89.
H. Hommel A. Touhami A. Halli A. P. LeGrand 《Journal of Polymer Science.Polymer Physics》1995,33(16):2189-2198
EPR spectroscopy of labeled poly(ethylene oxide) (PEO) grafted on silica has been used to characterize the conformation and local dynamics of the chains. Grafted molecules of MW 2000 with grafting ratios of 0.045, 0.057, 0.126, and 0.42 molecules/nm2 were in contact with benzene. The mobility of the label was compared with that observed for solution of PEO from very diluted to highly concentrated and even bulk PEO. Thus, the concentration inside the grafted layer could be evaluated and also the thickness, which evolves rather linearly with the grafting ratio. © 1995 John Wiley & Sons, Inc. 相似文献
90.
《Surface and interface analysis : SIA》2006,38(9):1257-1265
Four vanadium oxide layers on mineral TiO2(001)‐anatase supports with different thickness (3–33 Å) were prepared with reactive d.c. magnetron sputtering and were extensively studied with photoelectron spectroscopy. Al Kα radiation and 150 eV synchrotron radiation were used as excitation sources. The evolution of the 2p, 3s and 3p core level line shapes of V and Ti as a function of the vanadium oxide thickness was studied, as well as the O1s and O2s core lines and the valence band. All the V2p spectra of the deposited vanadium oxide layers consist of at least 60% V5+, the rest being V4+. The V3p region is complicated by multiplet splitting, which prevents the determination of the vanadium oxidation state. The V3p multiplet splitting is different for the two excitation energies. No reduction of the titania support surface due to the vanadium oxide deposition was observed. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献