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971.
A different approach, aiming to achieve the constant blur status of point-spread function (PSF) at a certain defocused plane,
is described. The correlation between the two PSF is used to control the PSF blur similarity, and simultaneously the Strehl
ratio is also used to control the PSF blur minimization. By designing the PSF so that it is significantly insensitive to defocus
or related defocus quantity, for example, due to temperature change, all the constantly blurred images can be accurately de-blurred
by a simple inverse restoration filter for an adequate range of defocus. We refer to that as “software lens compensation”
and apply a design method to solve the athermalization of middle wavelength infrared (MWIR) imaging systems. The resultant
PSF is almost invariant in the temperature range from −10 to 50°C at the same focal plane. Consequently, the constant blur
spot can be removed by a simple digital signal processing. Thus, clear and sharp de-blurred images at different temperatures
are obtained. 相似文献
972.
《Biomedical chromatography : BMC》2017,31(8)
The degradation behavior of mangiferin, under various ICH Q1A(R2) recommended stress conditions, was studied using an isocratic elution with mobile phase (pH 2.4), composed of acetonitrile and 1% orthophosphoric acid (12:88 v/v) at a flow rate of 1.0 mL/min, with λ max 262 nm. It was suitably adapted for LC–MS studies by replacing with 1% acetic acid (ACN–1% acetic acid; 18:82) and the pH was adjusted to 3.0. Extensive degradation was found to occur during alkaline medium stress studies at 2.31 min of retention time at λ max of 235 nm. The mass spectrum of mangiferin, 3 h after treatment with 0.1 M NaOH, clearly shows the rupture of the tricyclic ring, indicating that a fragment at m /z − 269 was formed. Furthermore, the results were supported by nuclear magnetic resonance as well. However, no degradation was observed in other stress conditions. 相似文献
973.
First principles calculations were performed on the electronic, vibrational and Raman spectra of substitutional N-, B- and Pt-doped rutile titanium dioxide (TiO2), within the density functional theory (DFT), using the plane-wave pseudopotential method. From the calculated electronic band structure and density of states we concluded that the doping induces significant changes in the band structure of TiO2, highlighting B- and Pt-doped TiO2 as the best candidates for photocatalytic materials for visible light absorption. On the other hand, N-doped TiO2 appears to be active only for the photoreduction processes, although N doping introduces midstates into the band gap. Only N-doped TiO2 proved to have stable phonon dispersions and showed interesting band doubling. 相似文献
974.
《Journal of Coordination Chemistry》2012,65(3):467-478
Abstract The chemical and direct electrochemical syntheses of copper, cobalt, nickel and zinc chelates of 2-[N-tosylamine)benzaldoxime (L1H2) and 2-[N-tosylamine)benzal-O-methyloxime (L2H) are reported. On the basis of the elemental analyse IR and EPR spectra and magnetic properties, dimeric structures ML are suggested from L1H2 under the conditions of the chemical synthesis, while electrosynthesis leads to the monomeric complexes M(L1H)2. Using L2H as a ligand, only the chelates ML2 2 are formed, regardless of the method of synthesis. The copper dimers CuL1 have antiferromagnetic properties, while the chelates M(L1H)2 and ML2 have normal magnetic moments. In agreement with the magnetic properties and literature data on structures of four-coordinate complexes a tetrahedral structure is assigned. 相似文献
975.
976.
随着化石能源的日益短缺,可再生木质生物质资源的利用越来越受到重视,常压液化技术是生物质资源高效利用的主要方式之一。利用单因素方法,探讨液化温度、复配液化剂二甘醇(DEG)与1,2-丙二醇(PG)的混合比、液固比、催化剂磷酸的用量、反应时间等因素对玉米秸秆液化得率的影响,以便优化其液化工艺;然后采用热重分析仪(TGA)、气相色谱-质谱技术(GC-MS)和核磁共振(NMR)技术对此优化条件下所得生物油的挥发降解特性和主要组成成分进行了检测探讨。分析表明,玉米秸秆液化时优化工艺参数为:液化温度170 ℃,液化剂DEG与PG混合比1∶2,液固比5∶1,H3PO4用量10%,反应时间45 min;此时玉米秸秆液化得率高至99.50%。TGA结果表明,此条件下所得生物油含有80%以上碳数小于25的化合物,热解后最终残炭量约为15%。GC-MS表明,可以检测出此生物油中含有的39种有机物,其中,醇类有机物的含量最多,酚类有机物的含量次之,它们相对含量依次是70.70%和25.63%,其还含有一定量的有机酸(2.80%)、醚类(0.64%)、酯类(0.10%)和酮类(0.13%)等有机物;其组分十分复杂,高含氧量,稳定性较差。1H-和13C-NMR分析表明,不同化学位移δ与生物油中不同类型的质子和碳原子相对应,明确生物油中不同类型H和C的分布,有利于对其分子结构进行深入探讨。这些研究为非木材生物质高效液化条件的选择及液化产物制备化学品和生物燃油给予理论基础与应用支持,促进了生物质资源的有效转化利用及其生物质基产品的开发。 相似文献
977.
Miscible blends of poly(ethylene oxide) with brush copolymers of poly(vinyl alcohol)‐graft‐poly(l‐lactide)
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Ainhoa Lejardi Jose‐Ramon Sarasua Agustin Etxeberria Emilio Meaurio 《Journal of Polymer Science.Polymer Physics》2016,54(13):1217-1226
Even though poly(ethylene oxide) (PEO) is immiscible with both poly(l ‐lactide) (PLLA) and poly(vinyl alcohol) (PVA), this article shows a working route to obtain miscible blends based on these polymers. The miscibility of these polymers has been analyzed using the solubility parameter approach to choose the proper ratios of the constituents of the blend. Then, PVA has been grafted with l ‐lactide (LLA) through ring‐opening polymerization to obtain a poly(vinyl alcohol)‐graft‐poly(l ‐lactide) (PVA‐g‐PLLA) brush copolymer with 82 mol % LLA according to 1H and 13C NMR spectroscopies. PEO has been blended with the PVA‐g‐PLLA brush copolymer and the miscibility of the system has been analyzed by DSC, FTIR, OM, and SEM. The particular architecture of the blends results in DSC traces lacking clearly distinguishable glass transitions that have been explained considering self‐concentration effects (Lodge and McLeish) and the associated concentration fluctuations. Fortunately, the FTIR analysis is conclusive regarding the miscibility and the specific interactions in these systems. Melting point depression analysis suggests that interactions of intermediate strength and PLOM and SEM reveal homogeneous morphologies for the PEO/PVA‐g‐PLLA blends. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1217–1226 相似文献
978.
Accurate and efficient targets extraction from blurred trace infrared images has very important meaning for latent trace evidence collection in crime scene. Based on the superstring theory, a superstring galaxy template extraction algorithm for infrared trace target is presented. First, all of the pixels are divided into three classes: target pixels, background pixels and blurred pixels. Next, the superstring template characteristics for every pixel in a blurred infrared image are calculated as the features of each pixel. Finally, a galaxy covering algorithm is proposed, target pixels and background pixels are used for training the galaxy covering domain of every galaxy classifiers, and these classifiers will divide each blurred pixel into two classes: a target pixel or a background pixel. Experimental results indicate that the superstring galaxy template algorithm can improve the target extraction rate and reduce the extraction error rate. 相似文献
979.
《光谱学快报》2013,46(5):647-663
The normal coordinate analysis of the title complex, 1,2-bis(2-formylglycinebenzenesulfenyl) ethane Pd(II) dichloride has been carried out by using the Urey-Bradley force field. According to the molecular structure determined by x-ray crystallographic analysis, 182 internal coordinates were established and 112 theoretical vibration frequencies agree well with the observed values with the average difference of 2.53 cm?1 and the maximum deviation of 16.0 cm?1. 相似文献
980.
Frequencies of absorption band maxima for the first two electronic singlet transitions of coronene, triphenylene and 1,2,5,6-dibenzanthracene in vapor phase were calculated indirectly from solution spectral data. The calculations were based on two different models: the first one was a linear correlation between the solution absorption frequencies in nonpolar solvents and the solvent refractive indices. The accuracy of both methods was checked with anthracene and some of its derivatives: both methods gave a good agreement with the experimental values. 相似文献