首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   737篇
  免费   65篇
  国内免费   54篇
化学   325篇
晶体学   17篇
力学   156篇
综合类   4篇
数学   36篇
物理学   318篇
  2024年   4篇
  2023年   9篇
  2022年   12篇
  2021年   19篇
  2020年   36篇
  2019年   13篇
  2018年   9篇
  2017年   21篇
  2016年   28篇
  2015年   30篇
  2014年   28篇
  2013年   38篇
  2012年   30篇
  2011年   38篇
  2010年   43篇
  2009年   50篇
  2008年   40篇
  2007年   71篇
  2006年   45篇
  2005年   31篇
  2004年   29篇
  2003年   57篇
  2002年   36篇
  2001年   45篇
  2000年   14篇
  1999年   10篇
  1998年   13篇
  1997年   8篇
  1996年   8篇
  1995年   7篇
  1994年   11篇
  1993年   5篇
  1992年   5篇
  1991年   4篇
  1990年   2篇
  1989年   2篇
  1985年   1篇
  1984年   2篇
  1979年   1篇
  1957年   1篇
排序方式: 共有856条查询结果,搜索用时 20 毫秒
51.
The spin chain systems with one-dimensional magnetic ordering are promising candidates for quantum optical devices. This paper shows how the optical excitation can induce various phonon modes in an ideal Cu-O chain at various lengths. The calculation was carried out at different level theories including configuration interaction singles for excited states, density functional theory and second-order Möller-Plesset perturbation. In general, the number of modes increases with chain length due to growing asymmetry of atomic positions when chain exceeds 5 nm. There were, however, only two basic modes: one is associated with the symmetric oscillation of oxygen and another with the asymmetric motion of the same along the chain. At the length below 4.3 nm, the Raman activity of the symmetric mode (440 cm−1) dominates. From analysis of density of states, this mode may be associated with the excitation across the lowest LUMO bands with changing in spin state.  相似文献   
52.
We investigate finite temperature corrections to the Landauer formula due to electron–electron interaction within the quantum point contact. When the Fermi level is close to the barrier height, the conducting wavefunctions become peaked on the barrier, enhancing the electron–electron interaction. At the same time, away from the contact the interaction is strongly suppressed by screening. To describe electron transport we formulate and solve a kinetic equation for the density matrix of electrons. The correction to the conductance G is negative and strongly enhanced in the region 0.5 × 2e2/h ≤ G ≤ 1.0 × 2e2/h. Our results for conductance agree with the so-called “0.7 structure” observed in experiments.  相似文献   
53.
The propagation of acoustic disturbances in a porous medium crossed by numerous cracks (double porosity medium) is a complex problem that we here simplify by investigating the acoustics of a permeable channel. We consider a fluidfilled channel in two possible geometries, a slit or a cylindric pipe. The channel is surrounded by a porous medium (saturated with the same fluid) and is itself surrounded by an external medium. To simulate the average properties of the cracked rock, the external medium is either nonpermeable (few connections between cracks) or highly permeable (numerous connections). We present analytical and numerical results concerning acoustic disturbances of small amplitude generated in the channel, such as harmonic waves, step disturbanses and pulses.  相似文献   
54.
The concept, the present status, key issues and future prospects of a novel hexagonal binary decision diagram (BDD) quantum circuit approach for III–V quantum large-scale integrated circuits (QLSIs) are presented and discussed. In this approach, the BDD logic circuits are implemented on III–V semiconductor-based hexagonal nanowire networks controlled by nanoscale Schottky gates. The hexagonal BDD QLSIs can operate at delay-power products near the quantum limit in the quantum regime as well as in the many-electron classical regime. To demonstrate the feasibility of the present approach, GaAs Schottky wrap gate (WPG)-based single-electron BDD node devices and their integrated circuits were fabricated and their proper operations were confirmed. Selectively grown InGaAs sub-10 nm quantum wires and their hexagonal networks have been investigated to form high-density hexagonal BDD QLSIs operating in the quantum regime at room temperature.  相似文献   
55.
New type of spherical pore Al alloy foam with low porosity and high strength   总被引:15,自引:0,他引:15  
The Ultra Light Metal Structure with variouskinds of pores (open, close) realizes the lightness andmultifunction of structural material. The functionsinclude lightness (ρ < 1), high specific strength, highenergy absorption, sound insulation, heat insulationand electromagnetism shield. It is one of the hotspotsin material research nowadays[1— . The requirements 6]of high speed movement and high technology make Alalloy foam, which has higher specific st…  相似文献   
56.
The properties of multilayer metal-fiber coverings superimposed on plane base layers, which consist of various combinations of a copper mesh and different-length copper wires, are examined. Coverings from discrete copper microwires, two-layer coverings including a mesh and microwires, and three-layer coverings consisting of a mesh and two layers of microwire are investigated. The contacts between the fibers, the copper mesh, and the base layer are analyzed by using the metallography technique. Quantitative estimates for these contacts are presented. The side effects connected with the hydrogen disease of copper are discussed. The thermal properties of the porous structures are analyzed with the use of a termographic chamber. It is shown that the porous metal-fiber structures have good mechanical and heat-transfer properties.  相似文献   
57.
58.
We present 69,71Ga-NMR experiments on microcrystalline samples of the recently discovered supramolecular compound Ga 84 [ N ( SiMe 3 ) 2 ] 20 Li 6 Br 2 ( thf ) 20 . 2 toluene, which is composed of ligand-coordinated Ga84 metal clusters, packed together in a fully ordered crystalline matrix. The compound is highly conducting and even shows superconductivity below T c ~ 7.2 K. Our preliminary results between 10-300 K show a metallic-like behavior: the nuclear spin-lattice relaxation rate T 1 -1 follows the Korringa law 69 ( T 1 T ) -1 = 0.36 s -1 K -1 , but with a relaxation rate approximately three times smaller than in bulk -Ga metal. No quantum-size effects are observed, the Korringa law being followed down to 10 K, whereas the quantum-gaps for individual clusters should amount to ~ 10 3 K. These results therefore suggest a transport process based on intermolecular charge transfer, similar as in alkali-doped fullerenes and silicon-clathrates.  相似文献   
59.
We prove that in several classes of optimization problems, including the setting of smooth variational principles, the complement of the set of well-posed problems is -porous.

  相似文献   

60.
InSb nanostructures have been synthesized by the use of gas aggregation process. Nanoparticles with different shapes are obtained by controlling the growth and deposition temperature of the InSb nanoclusters. Triangular nanocrystals are commonly observed when the clusters are extracted from the condensation chamber of the source and deposited on the room temperature substrate at high vacuum. When the deposition is performed inside the condensation chamber at high temperature near the melting point of bulk InSb, nanoparticles formed on the substrate surface show several kinds of 3-dimensional morphologies, such as triangular or rectangular prisms, as well as hexagonal tablets. Keeping the same conditions for the cluster source operation and deposition, after long time growth, nanorods with hexagonal and quadrangular cross sections are formed through vapor-liquid-solid (VLS) process. The origin of the difference on the morphologies and shapes of the nanostructures is attributed to the anisotropic growth of InSb, which is temperature dependent.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号