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61.
Dong Xi XiaoPing Luo QiangHua Lu KaiLun Yao ZuLi Liu Qin Ning 《Journal of nanoparticle research》2008,10(3):393-400
Gold-coated iron oxide nanoparticle Hepatitis B virus (HBV) DNA probes were prepared, and their application for HBV DNA measurement
was studied. Gold-coated iron oxide nanoparticles were prepared by the citrate reduction of tetra-chloroauric acid in the
presence of iron oxide nanoparticles which were added as seeds. With a fluorescence-based method, the maximal surface coverage
of hexaethiol 30-mer oligonucleotides and the maximal percentage of hybridization strands on gold-coated iron oxide nanoparticles
were (120 ± 8) oligonucleotides per nanoparticle, and (14 ± 2%), respectively, which were comparable with those of (132 ± 10)
and (22 ± 3%) in Au nanoparticle groups. Large network aggregates were formed when gold-coated iron oxide nanoparticle HBV
DNA gene probe was applied to detect HBV DNA molecules as evidenced by transmission electron microscopy and the high specificity
was verified by blot hybridization. Our results further suggested that detecting DNA with iron oxide nanoparticles and magnetic
separator was feasible and might be an alternative effective method. 相似文献
62.
Niti Nipun Sharma 《Journal of nanoparticle research》2008,10(2):333-340
Emissive power per unit area of a blackbody has been modeled as a function of frequency using quantum electrodynamics, semi-classical
and classical approaches in the available literature. Present work extends the classical lumped-parameter systems model of
Brownian motion of nanoparticle to abstract an emissive power per unit area model for nanoparticle radiating at temperature
greater than absolute zero. The analytical model developed in present work has been based on synergism of local deformation
leading to local motion of nanoparticle due to photon impacts. The work suggests the hypothesis of a free parameter f′ characterizing the damping coefficient of resistive forces to local motion of nanoparticle and the manipulation of which
is possible to realize desired emissivity from nanoparticles. The model is validated with the well established Planck’s radiation
law. 相似文献
63.
The characters of self-assembly core/shell nanoparticles of amphiphilic hyperbranched polyethers (HP-g-PEO) as drug carriers
were investigated. The HP-g-PEO consisting of hydrophobic HP-g-PEO core and hydrophilic poly(ethylene glycol) arms was prepared
by the cation ring-opening polymerization. A series of HP-g-PEO samples with different degree of branching (DB) were synthesized
under various reaction temperatures. Nanoparticles (NP) were obtained by self-assembly of HP-g-PEO in aqueous media. The structure
of resulting HP-g-PEO was characterized by IR, 13CNMR and GPC. Dynamic light scattering and transmission electron microscopy were applied to characterize the sizes and size
distributions of NP. The results demonstrated that the mean diameters of NP were less than 100 nm, which exhibited uniform
spherical formations and narrow size distributions. Using hydrophobic drug Probucol (PRO) as model drug, the particle sizes
of drug loaded NP were larger than relative blank NP. The drug loading efficiency (LE) and incorporation efficiency (IE) of
these NP were achieved to 35 and 89%, respectively. The in vitro release of PRO from the NP exhibited a sustained release
and the cumulative drugs released for more than 600 h. The most important factor to affect drug release was the value of DB
of HP-g-PEO. With the DB of HP-g-PEO increasing, the size and size distribution of NP decreased as well as the release rate.
However, the small DB was beneficial to the LE of NP. Nanoparticle size and size distribution, LE, IE, and drug release rate
were slightly affected by the initial solution concentration of polyethers. The co-incorporated hydrophilic drug had influence
slightly on the release of drug from drug loaded NP. The results of in vitro drug release suggested that the core/shell NP
performed good controlled release behaviors with potential practice as novelty drug delivery vehicles. 相似文献
64.
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66.
Olin T. Mefford Robert C. Woodward Jonathan D. Goff T.P. Vadala Tim G. St. Pierre James P. Dailey Judy S. Riffle 《Journal of magnetism and magnetic materials》2007
Biocompatible, hydrophobic ferrofluids comprised of magnetite nanoparticles dispersed in polydimethylsiloxane show promise as materials for the treatment of retinal detachment. This paper focuses on the motion of hydrophobic ferrofluid droplets traveling through viscous aqueous media, whereby the movement is induced by gradients in external fields generated by small permanent magnets. A numerical method was utilized to predict the force on a spherical droplet, and then the calculated force was used to estimate the time required for the droplet to reach the permanent magnet. The calculated forces and travel times were verified experimentally. 相似文献
67.
Wuyou Fu Shikai Liu Wenhua Fan Haibin Yang Xiaofen Pang Jing Xu Guangtian Zou 《Journal of magnetism and magnetic materials》2007
Spinel CoFe2O4 coating on the surface of hollow glass microspheres of low density was synthesized by co-precipitation method. The phase structures, morphologies, particle size, shell thickness, chemical compositions of the composites have been characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and energy dispersive X-ray spectroscopy (EDS). The results show that CoFe2O4 coating on hollow glass microspheres can be achieved, and the coating layers are constituted by CoFe2O4 nanoparticles of mean size ca. 10 nm. The as-synthesized powder materials were uniformly dispersed into the phenolic cement, then the mixture was pasted on metal plate with the area of 200 mm×200 mm as the test plate. The test of microwave absorption was carried out by the radar-absorbing materials (RAM) reflectivity far field radar cross-section (RCS) method. The results indicate that the coated CoFe2O4/hollow glass microspheres composites can be applied in lightweight and strong absorption microwave absorbers. 相似文献
68.
Silver-decorated silica spheres of submicrometer-sized silica spheres with a core-shell structure were obtained based on a seed-mediated growth process, where silver nanoparticles were firstly formed from reducing Ag+ to Ag0 in N,N-dimethylformamide (DMF) in the presence of poly(vinylpyrrolidone) (PVP) as protective agent under ultrasound irradiation, followed by the growth of silver shell served silver nanoparticles as nucleation sites and formaldehyde as reducer. The results revealed that the terms of PVP addition and ultrasonic surroundings had great influence on the fabrication of silver seeds. 相似文献
69.
Recent studies demonstrated that the process to produce metal and oxide nanoparticles by laser ablation of consolidated microparticles is a convenient and energy-efficient way to prepare nanoparticles. In this work, the novel process is applied to nanoparticle synthesis in the liquid environment and the results are compared with those by the gas-phase process. Metal and oxide nanoparticles are synthesized by pulsed laser ablation of the compacted metal microparticles using a Q-switched Nd:YAG laser in water. It is shown that the process is effective for preparing nanoparticle suspensions having relatively uniform size distributions. While the laser fluence and the degree of compaction strongly influence the size of the produced nanoparticle in air, the sedimentation time is shown to be the most critical factor to determine the mean size of the suspended particles. 相似文献
70.
Chengyu Wang 《Applied Surface Science》2007,253(10):4768-4772
Hydrophobic vaterite nanoparticles were prepared via crystallization of CaCO3 with oleic acid in methanol by mimicking the process of biomineralization. The molar ratio of oleic acid to calcium ion was varied from 0.1 to 0.5. By changing the concentration of the oleic acid, CaCO3 particles with different shapes and polymorphism were obtained. High concentration of the oleic acid gave stable vaterite crystals, the polymorph of which did not change when the composite was kept in water for more than one week. Fourier transform infrared spectroscopy (FT-IR) and TGA analysis of the obtained product indicated that the oleic acid was bound to the crystalline CaCO3. The contact angle of the modified vaterite reached 122°. We have succeeded in crystallization of hydrophobic CaCO3 nanoparticles in situ. 相似文献