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921.
Cp*Me5P6C5: A New Carbaphosphane with a Structure Unit of Hittorf-Phosphorus The thermolysis of 1,2,3-tris(pentamethylcyclopentadienyl)cyclotriphosphane [(Cp*P)3, 1 ] or 2,3,4,6-Tetrakis(pentamethylcyclopentadienyl)bicyclo[3.1.0]hexaphosphane [Cp*4P6, 2 ] leads in addition to the known 3,4-bis(pentamethylcyclopentadienyl)tricyclo[3.1.0.02, 6]hexaphosphane [Cp*2P6, 3 ] to the pentacyclic carbaphosphanes 3,4,5,6,11-pentamethyl-endo-9-pentamethylcyclopentadienyl- 3,4,5,6,11-pentacarba-pentacyclo [6.1.11,8.13,6.02,7010,11]-4-en-undecaphosphane and 3,4,5,6,11-pentamethyl-exo-9-pentamethylcyclopentadienyl-3,4,5,6,11-pentacarba-pentacyclo [6.1.11,8.13,6.02,7010,11]-4-en-undecaphosphane [Cp*Me5P6C5, 4a, 4b ]. Furthermore, other polyphosphanes are formed, like 1,2,3,4-tetrakis(pentamethylcyclopentadienyl)cyclotetraphosphane [(Cp*P)4, 5 ] and 2,4-bis(pentamethylcyclopentadienyl)-tetraphosphabicyclo[1.1.0]butane [(Cp*P)2P2, 6 ]. The structure of 4a and 4b is determined by NMR-spectroscopy. The molecule contains a P5C3-cunean-unit, to which a C2Me2-brigde and a PCp*-brigde is bonded.  相似文献   
922.
薛慰灵  吴萼 《有机化学》1986,6(3):201-203
本文报道由3-氯-1,2-丙二醇(1)经七步反应,合成二羟基丙酮磷酸酯缩乙酮(7)的方法,总收率43%。在温和条件下,7可以水解为游离的二羟基丙酮磷酸酯(8)。  相似文献   
923.
1INTRODUCTIONIthasbeenarousedmoreandmoreinterestsinces-tetrazinewasfirstsynthesizedbyHautgschin1900[1].Thesynthesisofdihydroderivativeof3,6-dimethyl-s-tetrazinewasreportedindetailbySkorianetz[2].UsingX-ray,Jennison[3]foundthat1,6-dihydro-s-tetrazinehashom…  相似文献   
924.
对氟苯酚在辣根过氧化物酶(HRP)的催化下可被H2O2氧化,生成本酚及F-。测定对氟苯酚荧光猝灭程度及用铝-钙指示剂荧光体系检测酶促反应释放的F-,可分别建立HRP及其标记物的两种分析方法。铝-钙指示剂偶合法测定HRP的线性范围为0.031~31U/L,检测限(3δ)为0.0093U/L。两种方法分别用于测定人血清中乙肝表面抗原及抗体,结果令人满意。  相似文献   
925.
A preparative procedure is proposed for the synthesis of α-aminophosphonates of natural porphyrins by the microwave-assisted Kabachnik—Fields reaction.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 256–259, January, 2005.  相似文献   
926.
A simple method for the synthesis of procyanidin B3 substituted with a galloyl group at the 3 and 3″ position is described. Condensation of a benzylated catechin-3-O-gallate electrophile with a nucleophile, catechin and catechin-3-O-gallate, proceeded smoothly and stereoselectively to afford the corresponding dimer gallates, procyanidin B3-3-O-gallate and procyanidin B3-3,3″-di-O-gallate, in good yields. Further, their antioxidant activities on UV-induced lipid peroxide formation, DPPH radical scavenging activity and inhibitory activity of DNA polymerase were also investigated. Among three procyanidin B3 congeners (procyanidin B3, 3-O-gallate and 3,3″-di-O-gallate), the 3,3″-di-O-gallate derivative showed the strongest antioxidant and radical scavenging activity. Interestingly, the 3-O-gallate derivative was the strongest inhibitor of mammalian DNA polymerase with IC50 value of 0.26 μM, although it showed the weakest antioxidant and radical scavenging activity. It became apparent that the presence of a galloyl group at the C-3 position in the proanthocyanidin oligomer was very important for biological activity, however, the antioxidant activity of these compounds was not parallel to the DNA polymerase inhibitory activity.  相似文献   
927.
观察到肉桂基荧光酮(略作CF)在pH≈8与Fc(Ⅲ)配位后荧光增强,CPB的加入使荧光更强,络合物与试剂荧光强度之比F_(FeR)/F_R随0~0.01μg/ml Fe(Ⅲ)线性变化,λ_(ex)=410nm,λ_(ex)=480nm;而CF在pH≈10与Co(Ⅲ)配位后荧光却减弱,乳化剂OP存在时使试剂荧光增强,若以荧光熄灭Co(Ⅲ)灵敏度便提高,试剂与络合物荧光强度之比F_R/F_(CoR)对0~0.016 μg/ml Co(Ⅲ)呈直线关系,λ_(ex)=300nm,L_(em)=352nm。控制化学条件和激发、发射波长,可不经分离测定葡萄酒(微波溶样)中铁和钴。  相似文献   
928.
Intramolecular cyclization of acyl(ethoxycarbonyl)keteneN-benzoylaminals in boiling Ph2O gives 5-acyl-4-amino-2-phenyl-1,3-oxazin-6-ones.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1322–1323, July, 1995.This study was financially supported by the Russian Foundation for Basic Research (Grant No. 94-03-08964).  相似文献   
929.
本文用一步法合成了新合物RbEuI3与CsEuI3,测定了化合物的组成,结构,熔点,密度,荧光光谱,极谱电位及磁矩,确定了化合物中Eu的价态为正二价。  相似文献   
930.
Four new stationary phases for HPLC were prepared by modifying silica gel with a trifrnctional aminoalkyl silane. A conjugated π-electron system was linked to the amino group either directly or with a carboxylic anhydride as a spacer in between. Characterization and dynamic measurements of the new stationary phases were performed by solid state NMR spectroscopy. The results of the 29si and 13C CP/MAS techniques were compared with the recently developed 1H MAS-only technique. Despite strong homonuclear dipole-dipole interactions it was possible to obtain well resolved 1H MAS spectra of those stationaru phases with a high degree of crosslinking. Limited mobility of the aromatic ligand fragments is common for all examined stationaryu phases. The chromatographic properties of the new phases were tested by their ability tio sepatate a mixture of eight PAHS. It could be shown that the π-π interaction mechanism is responsible for the separation of the eight PAHs, because the elution order of the PAHs did not changem despite the use of both a nonpolar mobile phase (n-heptane) and a polar mobile phase (methanol/ water mixture).  相似文献   
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