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41.
Naoki Yoshikawa Lushi Tan Nobuyoshi Yasuda Ralph P. Volante Richard D. Tillyer 《Tetrahedron letters》2004,45(39):7261-7264
Enantioselective syntheses of bicyclo[3.1.0]hexane carboxylic acid derivatives are described. The syntheses were achieved by an intramolecular cyclopropanation as the key step, starting from enantiomerically pure starting materials that are commercially available. 相似文献
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A. A. Karapetyan R. A. Tamazyan A. R. Mikaelyan N. P. Raganyan 《Journal of Structural Chemistry》2004,45(2):352-355
A method for the synthesis of (E,Z)-2-phenyl-1-chlorocyclopropane-1-carboxylic acid by the addition of ethyl trichloroacetate to styrene in the presence of copper(I) ammine complexes is suggested. The major isomer was isolated as the corresponding acid. The results of X-ray diffraction (XRD) analysis unequivocally prove that the benzene ring and the carboxylic group are in the cis-position and that the molecules form centrosymmetric dimers. (E)-2-phenyl-1-chlorocyclopropane-1-carboxylic acid can serve as a convenient synthon for transamine synthesis. 相似文献
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Shusuke Okamoto Atsushi Sudo Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2019,57(16):1723-1729
Radical ring‐opening polymerization of 1,1‐dicyano‐2‐vinylcyclopropane 1 was performed in benzonitrile to find the corresponding homopolymer 2 soluble in organic solvents was successfully obtained while that in other solvents gave crosslinked and thus insoluble homopolymer. In addition, 1 underwent radical copolymerization with 1‐cyano‐1‐ester‐2‐vinylcyclopropanes 3 and 4 to afford the corresponding copolymers 7 and 8 . By increasing the content of the 1 ‐derived unit in the resulting copolymers, the solubility of the copolymers in organic solvents became lower and the residual weights at 600 °C and their glass transition temperatures became higher. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1723–1729 相似文献
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The 1,3‐C–H insertion of magnesium carbenoid and related species was investigated via density functional theory (DFT) calculations. The 1,3‐C–H insertion occurred according to an SN2‐like mechanism wherein the nucleophilic C–H bond attacked the electrophilic carbenoid carbon atom. The activation energies for the 1,3‐C–H insertion of (1‐chloropropyl)magnesium chloride, (1‐methoxypropyl)magnesium chloride, and [1‐(methylthio)propyl]magnesium chloride were 20.0, 33.8, and 47.1 kcal/mol, respectively. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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The cyclopropane analogue of valine (1-amino-2,2-dimethylcyclopropanecarboxylic acid, c3Val) has been synthesised and incorporated into the model peptides tBuCO-l-Pro-l-c3Val-NHiPr and tBuCO-l-Pro-d-c3Val-NHiPr. In the solid state, both dipeptides accommodate a type II β-turn stabilised by an NHiPr to tBuCO hydrogen bond. Remarkably, the peptide incorporating l-c3Val also exhibits a distorted γ-turn around the cyclopropane residue, with Pro-CO and NHiPr intramolecularly hydrogen-bonded. 相似文献
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