Two different modeling techniques, the method of moments and Monte Carlo simulation, were compared for propylene polymerization with coordination catalysts including a new mechanistic step, site transformation by electron donors. We used the models to show how the molecular weight and tacticity distributions of several poly(propylene) chain populations were affected by changing the concentration of hydrogen, electron donor, and propylene in the reactor, under steady‐state or dynamic operating conditions. The Monte Carlo simulation describes the molecular weight and tacticity distributions for the whole polymer and chain populations with distinct microstructural characteristics. We have also applied the Monte Carlo model to simulate the pentad sequence distributions and its equivalent 13C NMR spectra.
Deformation induced softening is an inelastic phenomenon frequently accompanying mechanical response of soft biological tissues. Inelastic phenomena which occur in mechanical testing of biological tissues are very likely to be associated with alterations in the internal structure of these materials.In this study, a novel structural constitutive model is formulated to describe the inelastic effects in soft biological tissues such as Mullins type behavior, damage and permanent set as a result of residual strains after unloading. Anisotropic softening is considered by evolution of internal variables governing the anisotropic properties of the material. We consider two weight factors wi (softening) and sk (discontinuous damage) as internal variables characterizing the structural state of the material. Numerical simulations of several soft tissues are used to demonstrate the performance of the model in reproducing the inelastic behavior of soft biological tissues. 相似文献
The energy release rate criterion, being mono scale by definition, is incompatible with the failure behavior of solids that are inherently dual, if not, multiscale. Time span of reliability is scale sensitive and can be addressed with consistency only by use of transitional functions that are designed to transform a function from one scale to another. A pseudo transitional energy release rate G∗ is defined to address the cross-scaling properties of energy release rate. The reliability of such a function is found to fall quickly when the scale range deviates from that of micro-macro. In general, the time span of reliability based on G* shortens considerably within the nano-micro and pico-nano scale ranges, resulting in fast turnover of system usability. Prediction accuracy tends to be scale range specific. Stress or strain based criteria are also mono scale. They may be adequate for some situations at the macroscopic scale, but can be ambiguous for multiscale problems. These situations are analyzed by application of the principle of least variance in conjunction with the R-integrals.Accelerated test data for the equivalent of 20 years’ fatigue crack growth in 2024-T3 aluminum panels were analyzed using the mutliscale reliability model. A time span plateau within the micro-macro range is from 8 to 17 years. This corresponds to the reliable portion of prediction, while the terminal 3 years are regarded as unreliable. A similar time span plateau were also found from 4 to 6 years within the nano-micro scale range. And an even smaller plateau hovering around 1.2 years were found for the pico-nano scale range. Time span of reliable prediction narrows with down sized scale range. The overlapping ends of the scale ranges are rendered unreliable as anticipated. These regions can be suppressed by the addition of meso scale ranges. Reference can be made to past discussions related to multiscaling and mesomechanics. 相似文献
The present investigation studies the peristaltic flow of the Jeffrey fluid through a tube of finite length. The fluid is electrically conducting in the presence of an applied magnetic field. Analysis is carried out under the assumption of long wavelength and low Reynolds number approximations. Expressions of the pressure gradient, volume flow rate, average volume flow rate, and local wall shear stress are obtained. The effects of relaxation time, retardation time, Hartman number on pressure, local wall she... 相似文献
With the two-scale expansion technique proposed by Yoshizawa,the turbulent fluctuating field is expanded around the isotropic field.At a low-order two-scale expansion,applying the mode coupling approximation in the Yakhot-Orszag renormalization group method to analyze the fluctuating field,the Reynolds-average terms in the Reynolds stress transport equation,such as the convective term,the pressure-gradient-velocity correlation term and the dissipation term,are modeled.Two numerical examples:turbulent flow past a backward-facing step and the fully developed flow in a rotating channel,are presented for testing the efficiency of the proposed second-order model.For these two numerical examples,the proposed model performs as well as the Gibson-Launder (GL) model,giving better prediction than the standard k-ε model,especially in the abilities to calculate the secondary flow in the backward-facing step flow and to capture the asymmetric turbulent structure caused by frame rotation. 相似文献
It has been shown that the plastic response of many materials, including some metallic alloys, depends on the stress state. In this paper, we describe a plasticity model for isotropic materials, which is a function of the hydrostatic stress as well as the second and third invariants of the stress deviator, and present its finite element implementation, including integration of the constitutive equations using the backward Euler method and formulation of the consistent tangent moduli. Special attention is paid for the adoption of the non-associated flow rule. As an application, this model is calibrated and verified for a 5083 aluminum alloy. Furthermore, the Gurson-Tvergaard-Needleman porous plasticity model, which is widely used to simulate the void growth process of ductile fracture, is extended to include the effects of hydrostatic stress and the third invariant of stress deviator on the matrix material. 相似文献
The interpretation of sheet forming simulations relies on failure criteria to define the limits of metal deformation. The common requirements for these criteria across a broad range of application areas have not yet been satisfied or fully identified, and a single criterion to satisfy all needs has not been developed. Areas where existing criteria appear to be lacking are in the comprehension of the effects of non-proportional loading, general non-planar and triaxial stress loading, and process and material mechanisms that differentiate between necking and fracture. This study was mainly motivated to provide an efficient method for the analysis of necking and fracture limits for sheet metals. In this paper, a model for the necking limit is combined with a model for the fracture limit in the principal stress space by employing a stress-based forming limit curve (FLC) and the maximum shear stress (MSS) criterion. A new metal failure criterion for in-plane isotropic metals is described, based on and validated by a set of critical experiments. This criterion also takes into consideration of the stress distribution through the thickness of the sheet metal to identify the mode of failure, including localized necking prior to fracture, surface cracking, and through-thickness fracture, with or without a preceding neck. The fracture model is also applied to the openability of a food can for AA 5182. The predicted results show very good agreement with the experimentally observed data. 相似文献
Dielectric elastomer (DE) is one type of electro-active polymers (EAP) that responds to electrical stimulation with a significant shape and size change. As EAPs, dielectric elastomers are lightweight, inexpensive, pliable and can be fabricated into various shapes, all of which are attractive properties to justify the intense research in the field. This paper presents a nonlinear, electrical and mechanical coupled, large deformation finite element formulation for DEAs. Maxwell’s equations for the electroquasistatic fields were solved simultaneously with equation of linear momentum. The hyperelastic Ogden model and total Maxwell stress method were combined to describe the material. The formulation was based on the weak forms of Maxwell’s equation and linear momentum expressed in the reference configuration. The closed form consistent tangent moduli for dielectric elastomers were derived. The results of the simulation compared with the experiments have demonstrated the validity of the method from the computational aspect. 相似文献