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81.
《Journal of Coordination Chemistry》2012,65(4):714-727
Four dioxomolybdenum(VI) complexes were synthesized by reaction of [MoO2(acac)2] with thiosemicarbazones derived from 5-allyl-2-hydroxy-3-methoxybenzaldehyde (1), 2-hydroxynaphthaldehyde (2), 2,3-dihydroxybenzaldehyde (3), or 5-tert-butyl-2-hydroxybenzaldehyde (4). The ligands were coordinated to molybdenum as tridentate ONS donors. X-ray crystallography showed that the distorted octahedral coordination of molybdenum is completed by methanol (D) in 1a, 3a, and 4a or H2O in 2a. The molecular structures of 1, 3, and 4, and the complexes were determined by single-crystal X-ray crystallography. Binding of the ligand and complexes with calf thymus DNA were investigated by UV, fluorescence titrations, and viscosity measurements. Gel electrophoresis revealed that all the complexes can cleave pBR322 plasmid DNA. The cytotoxic properties of the complexes against human colorectal (HCT 116) cell line showed strong antiproliferative activities in relative order 4a?>?3a?>?1a?>?2a with IC50 values of 1.6, 4.0, 4.8, and 6.7?μM, respectively. The complexes exhibited more activity than the standard reference drug, 5-fluorouracil (IC50 7.3?μM). These studies show that dioxomolybdenum(VI) complexes have potential use in chemotherapy. 相似文献
82.
《Journal of Coordination Chemistry》2012,65(5):407-415
The complexes [MI2(CO)3(NCMe)2] (M=Mo or W) react in CH2Cl2 at room temperature with two equivalents of 4,4'-diphenylenecarbonitrile (dpc) to afford the new seven-coordinate complexes, [MI2(CO)3(4,4'-dpc-N)2] (1 and 2) in good yield. Equimolar quantities of [MI2(CO)3(NCMe)2] and PPh3 give [MI2(CO)3(NCMe)(PPh3)], which react in situ with 4,4'-dpc to yield the mono-4,4'-diphenylenecarbonitrile complexes, [MI2(CO)3(4,4'-dpc-N)(PPh3)] (3 and 4). Treatment of the bis(alkyne) complexes, [WI2(CO)(NCMe)(η 2-RC2R)2] (R=Me and Ph) with one equivalent of 4,4'-dpc in CH2Cl2 at room temperature affords the acetonitrile displaced products, [WI2(CO)(4,4'-dpc-N)(η 2-RC2R)2] (5 and 6). Reaction of equimolar quantities of [WI2(CO)(NCMe)(η 2-PhC2Ph)2] and 2 in CH2Cl2 at room temperature gives the 4,4'-dpc-bridged complex, [WI2(CO){WI2(CO)3(4,4'-dpc-N)(4,4'-dpc- N,N')}(η 2-PhC2Ph)2] (7) in good yield. Similarly, equimolar amounts of [WI2(CO)(NCMe)(η 2-RC2R)2] (R=Me and Ph) and (4) react in CH2Cl2 to afford the bimetallic complexes, [WI2(CO){WI2(CO)(4,4'-dpc-N,N')(PPh3)}(η 2-RC2R)2] (8 and 9). The new bimetallic 4,4'-dpc-bridged alkyne complexes, [WI2(CO){WI2(CO)(4,4'-dpc-N,N')(η 2-MeC2Me)2}(η 2-MeC2Me)2] [(10), [WI2(CO){WI2(CO)(4,4'-dpc-N,N')(η 2-PhC2Ph)2}(η 2-PhC2Ph)2] (11) and [WI2(CO){WI2(CO)(4,4'-dpc-N,N')(η 2-MeC2Me)2}(η 2-PhC2Ph)2] (12) are also described. 相似文献
83.
"智能窗"大规模推广顺应可持续发展潮流,三氧化钨(WO_3)是生产"智能窗"的一种重要电致变色材料,但调控WO_3薄膜电致变色性能机制仍待进一步研究。采用旋涂法制备WO_3薄膜,重点研究了溶液浓度和旋涂次数对调控WO_3薄膜电致变色性能的影响。通过表面轮廓仪测量薄膜厚度,X射线衍射(XRD)测量薄膜结晶情况,原子力显微镜(AFM)和扫描电子显微镜(SEM)分析薄膜表面形貌,光谱仪测量薄膜初始态、着色态和褪色态的透射率。实验结果表明,随着溶液浓度增加(0. 2~1. 0 mol/L),薄膜厚度从9. 7 nm增加到33. 3 nm,透射率调制能力从0%提升到37. 0%;多次旋涂薄膜厚度线性增长,线性拟合优度(R~2)达0. 98,5次旋涂后透射率调制能力达51. 3%。改变溶液浓度和旋涂次数都是调控薄膜透射率调制能力的有效手段,精准调控薄膜透射率调制能力对设计不同应用场景的电致变色器件具有重大意义。 相似文献
84.
Jiahao Liu Weikang Li Dr. Yinwu Li Prof. Dr. Yan Liu Prof. Dr. Zhuofeng Ke 《化学:亚洲杂志》2021,16(20):3124-3128
The first implementation of a molybdenum complex with an easily accessible bis-N-heterocyclic carbene ligand to catalyze β-alkylation of secondary alcohols via borrowing-hydrogen (BH) strategy using alcohols as alkylating agents is reported. Remarkably high activity, excellent selectivity, and broad substrate scope compatibility with advantages of catalyst usage low to 0.5 mol%, a catalytic amount of NaOH as the base, and H2O as the by-product are demonstrated in this green and step-economical protocol. Mechanistic studies indicate a plausible outer-sphere mechanism in which the alcohol dehydrogenation is the rate-determining step. 相似文献
85.
Michèle Willson Jacques Navech Ramon Burgada 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):457-467
Abstract The PMR spectra of some spirophosphorans containing the P–C bond are analysed. The results allow us to determine the stereochemistry of these compounds (conformation, stereoisomerism). Le spectre de RMP de quelques spirophosphoranes à liaison P–C est analysé. Les résultats sont utilisés pour préciser la stéréochimie de ces composés (conformation, stéréoisomérie). 相似文献
86.
Steffen Blaurock Thomas Koch Olaf Kühl Peter Lönnecke Felicite Majoumo René Sommer 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1451-1456
Substituted bifunctional phosphorus-based ligands HX(CRR') n PR"H (or -PR" 2 ) [where X = O, S, NR', (substituted) cyclopentadienyl; n = 1, 2, 3; R, R', R" = alkyl, aryl, H] were employed as bridging ligands in the synthesis of early/late bridged transition metal complexes. Synthetic routes to the bifunctional ligands were also developed. First, mononuclear complexes, such as [TpZr(OCH 2 PPh 2 ) 3 ] (Tp = trispyrazolylborato), [Cp 2 Zr(1-O-2-PHR-C 6 H 10 )(Me)] (R = 2,4,6-Pr i 3 C 6 H 2 (Tipp)), [Cp 2 Zr(SCH 2 CH 2 PHR) 2 ] (R = Ph, Mes, Tipp), and phosphinoferrocene derivatives, were prepared. These complexes are suitable precursors for the introduction of a second metal (as in, for example, [TpZr( w -OCH 2 PPh 2 ) 3 Mo(CO) 3 ]). 相似文献
87.
Reaction of chiral allylic cyclic carbonates with Grignards reagent in the presence of NiCl2(dppe) as a catalyst afforded the alkylated (E)-allylic alcohols with high regio- and diastereoselectivity. 相似文献
88.
Dimosthenis L. Giokas Evangelos K. Paleologos Miltiades I. Karayannis 《International journal of environmental analytical chemistry》2013,93(2):167-171
Glossary On Air Pollution, Who Regional Publications European Series No. 9 (Director, Promotion of Environmental Health, WHO Regional Office for Europe, Scherfigsvej 8, DK-2100 Copenhagen θ) 1980, 114 pages (including an introduction, a list of reviewers and a list of the sources of definitions), stiff paper cover, format 239 ± 159 mm, ISBN 92-9020-109-6, WHO Health and Biomedical Information Programme, CH-1211 Geneva 27, SFr. 12. Spektroskopische Methoden in Der Organischen Chemie (in German), by Manfred Hesse, Herbert Meier and Bernd Zeeh, 478 pages, including 169 figures and 86 tables, flexible paper cover, ISBN 3-13-576101-0, Georg Thieme Verlag, Stuttgart 1979, price DM 26.80. Analysis of Polycyclic Aromatic Hydrocarbons in Environmental Samples, World Health Organisation/International Agency for Research on Cancer, IARC Publication No. 29 (Series: Environmental Carcinogens, Selected Methods of Analysis, Volume 3, edited by H. Egan, Laboratory of the Government Chemist, London, U.K. et al.) 1980, 240 pages (including 17 figures, 18 tables, many formulae, an annex with 8 methods of analysis and 29 pages of valuable references in two sections), linen, format 242 ± 186 mm, ISBN 92-8-321129-4, WHO Health and Biomedical Information Programme, CH-1211 Geneva 27, US$30 or SFr. 50. Toxic Metals and Their Analysis by Eleanor Berman, Cook County Hospital, Chicago, Illinois, U.S.A., 304 pages (including an index of 5 pages, 29 tables and 5 figures), linen, format 241 × 163 mm, ISBN 0-85501-468-7, published 1980 by Heyden International Topics in Science, Spectrum House, Hillview Gardens, London NW4 2JQ, U.K., prices £12, US$27 or DM 56. 相似文献
89.
利用一锅法制备了Dawson型钨磷酸和钼钒磷酸,并用红外光谱和X-射线衍射表征了其结构.采用沸腾法研究了合成的杂多酸对甲基丙烯酸甲酯(MMA)的催化阻聚性能,考察了杂多酸结构、杂多酸用量和反应温度等因素对MMA本体聚合反应的影响.结果表明:钒钼元素在杂多酸催化阻聚MMA的反应中具有明显的协同作用,而且,杂多酸对MMA的催化阻聚作用随钒原子数的增加而增强,杂多酸的用量和反应温度对MMA自聚反应的速率影响较大.在过氧化苯甲酰(BPO)为0.04 g,MMA为10 mL,H9P2Mo15V3O62质量为MMA的0.06%,反应温度为101.2℃或H9P2Mo15V3O62质量为MMA的0.03%,反应温度为89.4℃时,MMA自聚反应被抑制.与传统和常用酚阻聚剂相比,Dawson型钼钒磷酸具有阻聚效果好、后处理简单、无腐蚀和污染问题等优点,能够作为MMA的阻聚剂使用. 相似文献
90.
The ionic liquid 1‐butyl‐3‐methylimidazolium hydrogensulfate, [bmim]HSO4, turned out to be resistant even to strong oxidizers like SO3. Thus, it should be a suitable solvent for the preparation of polysulfates at low temperatures. As a proof of principle we here present the synthesis and crystal structure of K2(S2O7)(H2SO4), which has been obtained from the reaction of K2SO4 and SO3 in [bmim]HSO4. In the crystal structure of K2(S2O7)(H2SO4) (orthorhombic, Pbca, Z = 8, a = 810.64(2) pm, b = 1047.90(2) pm, c = 2328.86(6) pm, V = 1978.30(8) Å3) two crystallographically unique potassium cations are coordinated by a different number of monodentate and bidentate‐chelating disulfate anions as well as by sulfuric acid molecules. The crystal structure consists of alternating layers of [K2(S2O7)] slabs and H2SO4 molecules. Hydrogen bonds between hydrogen atoms of sulfuric acid molecules and oxygen atoms of the neighboring disulfate anions are observed. 相似文献