全文获取类型
收费全文 | 938篇 |
免费 | 0篇 |
专业分类
化学 | 937篇 |
物理学 | 1篇 |
出版年
2023年 | 1篇 |
2020年 | 28篇 |
2019年 | 84篇 |
2018年 | 20篇 |
2017年 | 78篇 |
2016年 | 17篇 |
2015年 | 19篇 |
2014年 | 17篇 |
2013年 | 19篇 |
2012年 | 60篇 |
2011年 | 54篇 |
2010年 | 35篇 |
2009年 | 26篇 |
2008年 | 43篇 |
2007年 | 37篇 |
2006年 | 49篇 |
2005年 | 53篇 |
2004年 | 41篇 |
2003年 | 38篇 |
2002年 | 29篇 |
2001年 | 42篇 |
2000年 | 37篇 |
1999年 | 24篇 |
1998年 | 29篇 |
1997年 | 19篇 |
1996年 | 24篇 |
1995年 | 15篇 |
排序方式: 共有938条查询结果,搜索用时 15 毫秒
21.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(47):15206-15209
A synthesis of multiply arylated naphthalenes and anthracenes with eight different substituents has been accomplished. The key intermediates are tetraarylthiophene S ‐oxides, which are synthesized through a method involving sequential C−H arylation and cross‐coupling from 3‐methoxythiophene, followed by oxidation of the sulfur atom. The resulting tetraarylthiophene S ‐oxides can be converted into a tetraaryl benzynes or naphthalynes and then merged through [4+2] cycloaddition reaction with another tetraarylthiophene S ‐oxide, thereby resulting in the programmed synthesis of octaarylnaphthalenes and octaarylanthracenes. 相似文献
22.
23.
24.
Dr. Minh T. Nguyen Dr. Matthew D. Krzyaniak Dr. Magdalena Owczarek Dr. Daniel P. Ferris Prof. Michael R. Wasielewski Prof. J. Fraser Stoddart 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(21):5889-5894
We report the synthesis of a tetracationic macrocycle which contains two N,N′-bis(methylene)naphthalenediimide units inserted in between the pyridinium rings of the bipyridinium units in cyclobis(paraquat-p-phenylene) (CBPQT4+ or “blue box”) and describe the investigation of its potential use in materials for organic electronics. The incorporation of the two naphthalenediimide (NDI) units into the constitution of CBPQT4+, not only changes the supramolecular properties of the tetracation in the solid state, but also has a profound influence on the electrochemical and electronic behavior of the resulting tetracationic macrocycle. In particular, the solid-state (super)structure, investigated by single-crystal X-ray diffraction, reveals the formation of a three-dimensional (3D) supramolecular framework with ca. 2.8 nm diameter one-dimensional (1D) hexagonal channels. Electrochemical studies on solid-state thin films of the macrocycle show that they exhibit semiconducting properties with a redox-conductivity of up to 7.6×10−4 S m−1. Moreover, EPR and ENDOR spectroscopies show that charge is equally shared between the NDIs within the one-electron reduced state of the NDI-based macrocycle on the time scale of these techniques. 相似文献
25.
26.
27.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(34):10252-10256
With help of the DFT calculations and imposing of periodic boundary conditions the geometrical and electronic structures were investigated of two‐ and three‐dimensional boron systems designed on the basis of graphane and diamond lattices in which carbons were replaced with boron tetrahedrons. The consequent studies of two‐ and three‐layer systems resulted in the construction of a three‐dimensional supertetrahedral borane crystal structure. The two‐dimensional supertetrahedral borane structures with less than seven layers are dynamically unstable. At the same time the three‐dimensional superborane systems were found to be dynamically stable. Lack of the forbidden electronic zone for the studied boron systems testifies that these structures can behave as good conductors. The low density of the supertetrahedral borane crystal structures (0.9 g cm−3) is close to that of water, which offers the perspective for their application as aerospace and cosmic materials. 相似文献
28.
Nicole V. DelRosso Prof. Dr. Sarah Hews Prof. Dr. Lee Spector Prof. Dr. Nathan D. Derr 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(16):4514-4517
The predictable chemistry of Watson–Crick base-pairing imparts a unique structural programmability to DNA, enabling the facile design of molecular reactions that perform computations. However, many of the current architectures limit devices to a single operational cycle. Herein, we introduce the design of the “regenerator”, a device based on coupled enthalpic and entropic reactions that permits the regeneration of molecular circuit components. 相似文献
29.
30.
Jiaguo Huang Yan Lyu Jingchao Li Penghui Cheng Yuyan Jiang Kanyi Pu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):17960-17968
Despite its high morbidity and mortality, contrast‐induced acute kidney injury (CIAKI) remains a diagnostic dilemma because it relies on in vitro detection of insensitive late‐stage blood and urinary biomarkers. We report the synthesis of an activatable duplex reporter (ADR) for real‐time in vivo imaging of CIAKI. ADR is equipped with chemiluminescence and near‐infrared fluorescence (NIRF) signaling channels that can be activated by oxidative stress (superoxide anion, O2.?) and lysosomal damage (N‐acetyl‐β‐d ‐glucosaminidase, NAG), respectively. By virtue of its high renal clearance efficiency (80 % injected doses after 24 h injection), ADR detects sequential upregulation of O2.? and NAG in the kidneys of living mice prior to a significant decrease in glomerular filtration rate (GFR) and tissue damage in the course of CIAKI. ADR outperforms the typical clinical assays and detects CIAKI at least 8 h (NIRF) and up to 16 h (chemiluminescence) earlier. 相似文献