X-射线荧光光谱法测定钛铁中的硅、锰、磷、铝

介绍用X-射线荧光光谱仪测定钛铁中Si、Mn、P、Al含量的方法,通过试验确定了合适的研磨时间、压力和保压时间,用压片法制样,建立了各元素的工作曲线,各元素的测定范围分别为Si3.00%～6.00%,Mn1.00%～3.00%,P0.030%～0.070%,Al5.00%～9.00%。通过强度测量得到测定Si、Mn、P、Al的相对标准偏差分别为0.074%、0.308%、0.383%、0.040%,精密度满足测试要求。将该方法测定结果与化学法比对,准确度满足国家标准方法分析误差的要求。     

Copper Promoted Au/ZnO-CuO Catalysts for Low Temperature Water-gas Shift Reaction

IntroductionThe water-gas shift(WGS)reaction is an impor-tant step in many important chemical processes[1].Re-cently,the renewed interest in the removal of CO bythe WGS reaction has grown significantly because of theincreasing attention to pure hydrogen p…     

The structure of fullerene films and their metallocene doping

Hexagonal close-packed (HCP) C₆₀ and C₇₀ films have been prepared by the Langmuir method and examined by electron microscopy and electron-diffraction analysis. It has been shown that the vacuum deposition of a C₆₀+C₇₀ mixture results in the formation of a film with small sized grains and a distorted C₆₀-HCP structure. The simultaneous deposition of C₆₀ and ferrocene results in the formation of a film with a changed morphology and an electron-diffraction pattern that contains a variable amount of ferrocene depending on the experimental conditions. The electron-diffraction pattern corresponds to the presence of the known molecular complex C₆₀[(C₅H₅)₂Fe]₂. The analogous simultaneous deposition of fullerene C₆₀ and cobaltocene results in the formation of a C₆₀ film stable in air and water, which contains carbon and cobalt (from the data of X-ray fluorescence, electron microscopy and microdiffraction). It has a different morphology and different diffraction patterns than pure C₆₀ films and, depending on the cobaltocene content (relative to that of fullerene), appears to be a fullerite film doped with various amounts of cobaltocenium fullende, which is an ionic compound.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1379–1383, August, 1994.The work was financially supported by the Russian Foundation for Basic Research (Projects 93-03-4676 and 93-03-18368).     

含金属纳米粒子的层层自组装及单壁碳纳米管的催化生长

利用层间的静电吸附作用，重氮树脂和不同种类的含金属纳米粒子被依次吸附到硅片表面形成层层自组装膜。通过改变自组装膜的层数可以控制纳米粒子在表面吸附的量，同时利用重氮树脂的光敏特性可以实现纳米粒子在表面的图案化排布。以这些纳米粒子为催化剂，研究了单壁碳纳米管在硅片表面的化学气相沉积生长。     

N-TiO2/ZnO复合纳米管阵列的掺杂机理及其光催化活性

以ZnO纳米柱阵列为模板, 采用溶胶-凝胶法制备出TiO2/ZnO和N掺杂TiO2/ZnO的复合纳米管阵列. 扫描电镜(SEM)、X射线光电子能谱(XPS)和紫外-可见漫反射吸收光谱(UV-Vis)的结果表明: 两种阵列的纳米管均为六角形结构, 直径约为100 nm, 壁厚约为20 nm; 在N-TiO2/ZnO复合纳米管阵列中, 掺入的N离子主要是以N-Ox、N-C和N-N的形式化学吸附在纳米管表面, 仅有少量的N离子以取代式掺杂的方式占据TiO2晶格O的位置; 表面N物种形成的表面态能级和取代式掺杂导致带隙的窄化, 增强了纳米管阵列的光吸收效率, 促进了光生载流子的分离. 光催化实验结果表明, N离子的掺杂有利于N-TiO2/ZnO复合纳米管阵列光催化活性的提高.     

Steam Reforming Reactions of Methanol Over Nickel and Copper Catalysts

Steam-reforming reactions of methanol over NiO/Al₂O₃ and CuO/ZnO have been investigated. Over the nickel catalyst, the reaction rate is of zero kinetic order with respect to either methanol or steam, and the activation energy is 12.4 kJmol^?1, whereas with copper catalyst, the rate is expressed according to the literature as kP_a/(1 + K_aP_a + K_b+P_b) in which “a” and “b” are methanol and steam, respectively. The rate-controlling step of the reaction is assigned to the dissociation of O-H bond with dehydrogenation of C-H bond proceed rapidly to form carbon oxides. With copper catalyst the intrinsic participation of a water molecule during the dehydrogenation of C-H bond leads to the formation of carbon dioxide. With nickel catalyst, the dehydrogenation proceed more rapidly than the migration of a water molecule from an alumina site to a nickel site and causes almost exclusively the formation of carbon monoxide and hydrogen at a lower reaction temperature.     

N-TiO2/ZnO复合纳米管阵列的掺杂机理及其光催化活性

以ZnO纳米柱阵列为模板, 采用溶胶-凝胶法制备出TiO2/ZnO和N掺杂TiO2/ZnO的复合纳米管阵列. 扫描电镜(SEM)、X射线光电子能谱(XPS)和紫外-可见漫反射吸收光谱(UV-Vis)的结果表明: 两种阵列的纳米管均为六角形结构, 直径约为100 nm, 壁厚约为20 nm; 在N-TiO2/ZnO复合纳米管阵列中, 掺入的N离子主要是以N-Ox、N-C和N-N的形式化学吸附在纳米管表面, 仅有少量的N离子以取代式掺杂的方式占据TiO2晶格O的位置; 表面N物种形成的表面态能级和取代式掺杂导致带隙的窄化, 增强了纳米管阵列的光吸收效率, 促进了光生载流子的分离. 光催化实验结果表明, N离子的掺杂有利于N-TiO2/ZnO复合纳米管阵列光催化活性的提高.     

Study of short-lived silver isotopes with a laser ion source

The continuum part of the⁶Li (a,a)⁶Li (1.47–2.47 MeV) scattering data at E_a=50 MeV are extracted in two discretized bins. Coupled-channel calculations are carried out coupling the 1⁺ ground state of⁶Li with both the resonant, 3⁺ ₁ state, and two non-resonant continuum states. The discretized continuum of the⁶Li (p,p)⁶Li (1.75–3.25 MeV) scattering data at E_p=65 MeV are also analysed on the same footing. In both the cases the effect of coupling is found to be minimal.     

Production of helium fragments in197Au-emulsion collisions at 10.6 A GeV

We present a systematic analysis on the helium projectile fragments produced from 10.6 A GeV¹⁹⁷Auemulsion interactions in an experiment conducted at the Brookhaven AGS. Total charge changing and partial production cross-sections are measured experimentally on the basis of helium multiplicity. The multiplicity distribution of helium fragments which are produced collectively obey a KNO scaling. The transverse momentum distribution of these particles indicates that they are produced from two different independent sources.We are thankful to the BNL technical staff and specially to Dr. D. Beavis for his help in the exposure of emulsion stacks. Thanks are due to Profs. Y. Takahashi and G. Romano for their help in the preparation and development of the emulsion stacks. We appreciate the discussions with Prof. H. Stocker and J. Aichelin. This work was supported by D.O.E. under Grant No. DE-FGO2-90ER 40566.     

Enantioselective synthesis of hydroxy-substituted α-methyl-α-amino acids using Al and Mn derivatives of cyclo-(L-Ala-L-AIa) bis-Iactim ethers

Aluminum and manganese derivatives of lithiated bis-lactim ethers of cyclo-(L-Ala-L-Ala) were used for the enantioselective synthesis of -hydroxy and polyhydroxy -amino acids of the 2-methyIserine series. A new variant of the synthesis of these acids via 3-acyl-2, 5-dialkoxy-3, 6-dimethyl-3, 6-dihydropyrazines is proposed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 590–595, March, 1993.