新型Li4Ti5O12@石墨烯的微波辅助合成及电化学性能研究

将钛酸四丁酯和氧化石墨超声分散于叔丁醇,微波辐射下加入醋酸锂溶液制备尖晶石Li₄Ti₅O₁₂（LTO）前驱体/氧化石墨烯。一方面,微波作用促进了钛酸四丁酯水解,前驱体的形成能在15min内完成。另一方面,叔丁醇的“软模板”限域作用导致形成粒子极小且形貌单一的LTO前驱体。同时,细小的LTO前驱体粒子通过二次团聚将氧化石墨烯纳米片完全包埋。最后,LTO前驱体/氧化石墨烯在800℃下煅烧8h得到尖晶石LTO@石墨烯（LTO@G）。研究表明,LTO@G晶体尺寸在0.2~1.5μm之间,其振实密度达到1.7g·cm^-3。石墨烯位于晶体内部,并显著提高了材料的电子传导性。LTO@G的电导率为1.84×10^-3S·m^-1,远高于纯相LTO（1.1×10^-7S·m^-1）。1C和4C下,LTO@G首次充放电容量分别是170.1和97.5mAh·g^-1。可见,LTO@G具有高倍率性能和振实密度,可广泛应用于各种商品锂离子电池。     

Determination of quinolones by fluorescent excitation emission

In this work the viability of a fluorescent technique for the determination of quinolones is studied. This analytical technique allows one to analyze the effect of the increasing order of the analytical signal from a univariate calibration (zero order data) to partial least squares (PLS) calibration (first order). The comparison has been done through the figures of merit of the analytical procedure (technique and calibration) in accordance with the ISO norm and the 2002/657/EC European Decision about residuals.     

Numerical Determination of Damping in Metal Matrix Composites

Damping in metal matrix composites is mainly caused by inelastic matrix deformation induced by the great difference in the mechanical properties of the single constituents of the materials. In this study, the finite-element method in combination with a highly accurate material model is employed to examine the effects of both the fiber volume fraction and the external loading amplitude on the energy dissipation process in an Al/SiC composite under a cyclic mechanical load.     

回填材料膨润土对放射性气体滞留能力模拟研究

利用各种分析手段对膨润土的物理特性进行了表征.X射线衍射分析表明钠基膨润土呈典型的六方晶胞,晶胞参数是: a轴4.913, c轴5.405;差热分析曲线在低温区和高温区有明显的吸热峰出现;元素分析钠、钾离子的含量大于钙、镁离子的含量,在性能上表现为钠质膨润土具有较强的离子交换能力;显微分析表明其表面呈皱隙状,测定比表面积高达24.52 m2/g;吸水率测定表明膨胀率大,说明它具有密封功能,可有效阻滞地下水的渗入.利用SF6示踪技术,通过采集不同时间段取样池样品,分析样品中示踪气体浓度,绘制取样池示踪气体浓度随时间的变化关系曲线,根据费克扩散定律计算扩散系数.实验结果表明,随着压实膨润土密度的增大,示踪气体扩散系数迅速减小,当密度大于1.8 g/cm3时,扩散系数降至10-9 m2/s.研究结果表明,膨润土性能优化是通过在膨润土中添加适量的活性炭,可明显改善其对气体的阻滞能力;增加其对放射性气体滞留能力;添加少量的石英砂增加其机械性能、导热性和减少蠕变性,将引起对气体阻滞能力的下降.综合考虑,在膨润土中各添加5%活性炭和石英砂,既对气体具有较好的滞留能力,又具有较好的工程特性.     

NbSe2纳米材料的合成及减摩性能研究

将Se粉和Nb粉按一定的比例混合,然后密封在石英管中或压成片状后密封于石英管中,加热到一定温度,分别获得了NbSe2纳米纤维和NbSe2纳米颗粒.采用X射线衍射仪(XRD)、透射电子显微镜(TEM)和扫描电子显微镜(SEM)对所得产物进行了表征,分析了其微观形貌;采用MS-T3000摩擦磨损试验机测定了纳米颗粒作为基础润滑油N40添加剂的摩擦学性能.结果表明,制备的纳米纤维直径100～200nm,纳米颗粒直径40～300nm,二者都具有层状结构和良好的结晶性;NbSe2纳米颗粒作为润滑油添加剂具有明显优于基础润滑油的极压减摩性能;同纳米纤维相比,纳米颗粒的减摩性能较好.     

一种新型纳米TiO2涂膜及其光催化性能的研究

随着工业的发展及人类对环境保护的认识不足等原因 ,使人类赖以生存的环境受到严重的污染[1 ,2 ] .尤其是人类本来就非常短缺的水资源的污染 ,已引起有关部门、环保工作者及研究工作者的高度重视 .他们采用各种方法防止和控制水资源的继续污染及对污水的处理 .污水处理通常可分为三种类型 :即分离处理、稀释处理和转化处理 .前二种处理方法不能改变污染物的化学性质 ,使污染物得不到彻底分离 ,有时还产生二次污染等问题 .转化处理是通过化学方法和生化方法改变污染物的化学性质 ,使其转化成无害物质 .随着环保技术的发展 ,转化处理日益受到…     

Reverse blocking enhancement of drain field plate in Schottky-drain AlGaN/GaN high-electron mobility transistors

In this paper, we present the combination of drain field plate(FP) and Schottky drain to improve the reverse blocking capability, and investigate the reverse blocking enhancement of drain FP in Schottky-drain AlGaN/GaN high-electron mobility transistors(HEMTs). Drain FP and gate FP were employed in a two-dimensional simulation to improve the reverse blocking voltage(VRB) and the forward blocking voltage(VFB). The drain-FP length, the gate-FP length and the passivation layer thickness were optimized. VRBand VFBwere improved from-67 V and 134 V to-653 V and 868 V respectively after optimization. Simulation results suggest that the combination of drain FP and Schottky drain can enhance the reverse blocking capability significantly.     

Tutorial on estimating the limit of detection using LC-MS analysis,part II: Practical aspects

In part II of this tutorial, the investigated approaches of estimating the limit of detection (LOD) are applied to experimental data from LC-MS measurements. Important practical aspects specific to LC-MS and related to LOD are reviewed. The results of different tests of estimating linearity and scedasticity are compared. LOD estimates obtained with different approaches (for both simple characterization of the analysis method and accurate interpretation of the results) are applied to the data and the obtained values are compared. As a conclusion, a decision tree is proposed for estimating LOD for analytical methods using the LC-MS technique.     

Influences of Slope Gradient on Soil Erosion

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EFFECTIVENESS OF THE PROPELLENT CROSS-FEED TECHNOLOGY FOR LAUNCH VEHICLE

本文结合弹道优化,提出了估算和优化二级半构型运载火箭在不同发射模式和发射弹道下的近地轨道(low Earth orbit, LEO)最大运载能力的简单方法,并以长征七号为例进行了数值计算, 分析了使用推进剂交叉输送技术发射时的具体收效和最优弹道特点。数值计算表明：长征七号使用交叉输送技术发射时LEO最大运载能力能够比传统发射模式提高3 t(约20%), 同时降低发射过程中的最大轴向加速度近50%。该类型运载火箭采用推进剂交叉输送技术可以大幅提高运载能力。