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81.
Method of immobilization of carboxymethyl-dextran affects resistance to tissue and cell colonization 总被引:1,自引:0,他引:1
McLean KM Johnson G Chatelier RC Beumer GJ Steele JG Griesser HJ 《Colloids and surfaces. B, Biointerfaces》2000,18(3-4):221-234
Coatings from carboxymethylated dextrans (CMDs) were fabricated, analyzed by XPS, and investigated for their ability to inhibit corneal epithelial tissue outgrowth and bovine corneal epithelial cell attachment and growth. CMDs with differing degrees of carboxymethyl substitution and various molecular weights were synthesized by the solution reaction of dextrans with bromoacetic acid under different reactant ratios. The CMD compounds thus obtained were attached onto aminated surfaces produced in two ways: by the plasma deposition of a coating from n-heptylamine vapour, and by the plasma deposition of an acetaldehyde coating onto whose surface aldehyde groups the polyamine compounds polylysine, polyethyleneimine and polyallylamine were immobilized to provide platforms for CMD immobilization. XPS spectra showed that the latter route produced thicker coatings than the former approach. CMD molecules attached directly onto the plasma-fabricated amine surface supported some tissue migration; the extent of carboxymethyl substitution and the molecular weight of the CMDs had little influence. For CMDs immobilized via polyamine spacers, on the other hand, tissue outgrowth was completely inhibited, and again there were no discernible effects from the extent of carboxymethyl substitution and the molecular weight of the CMDs. In assays involving cell attachment and growth, analogous observations were found. Thus, the mode of immobilization of these polysaccharide coatings is the dominant factor in their anti-fouling performance, suggesting that optimization of the architecture of polysaccharide coatings may be an important factor for maximizing their cell-repellent abilities. 相似文献
82.
Tsuyoshi Nakajima 《Journal of fluorine chemistry》2007,128(4):277-284
Recent results on the surface modification of petroleum cokes and their electrochemical properties as anodes of secondary lithium batteries are summarized. The surface of petroleum coke and those heat-treated at 1860-2800 °C were fluorinated by elemental fluorine (F2), chlorine trifluoride (ClF3) and nitrogen trifluoride (NF3). No surface fluorine was found except only one sample when ClF3 and NF3 were used as fluorinating agents while surface region of petroleum coke was fluorinated when F2 was used. Transmission electron microscopic (TEM) observation revealed that closed edge of graphitized petroleum coke was destroyed and opened by surface fluorination. Raman spectra showed that surface fluorination increased the surface disorder of petroleum cokes. Main effect of surface fluorination with F2 is the increase in the first coulombic efficiencies of petroleum cokes graphitized at 2300-2800 °C by 12.1-18.2% at 60 mA/g and by 13.3-25.8% at 150 mA/g in 1 mol/dm3 LiClO4-ethylene carbonate (EC)/diethyl carbonate (DEC) (1:1, v/v). On the other hand, main effect of the fluorination with ClF3 and NF3 is the increase in the first discharge capacities of graphitized petroleum cokes by ∼63 mAh/g (∼29.5%) at 150 mA/g in 1 mol/dm3 LiClO4-EC/DEC. 相似文献
83.
1985年Bibby首次在非水体系中合成了纯硅方钠石,由此开创了一条合成分子筛的新途径。徐文旸等首次在Na_2O-SiO_2-Al_2O_3一有机胺非水体系中合成了丝光沸石(简称非水丝光沸石,用NAM表示)。晶化过程中液相无硅铝酸根离子,固相硅铝比始终保持不变,是典型的固相转化过程。利用非水体系这一特点,可以定向地合成出催化反应所需硅铝比的沸石。与水热体系相比,非水体系合成的丝光沸石在邻二甲苯异构化催化性能上要优于前者。 相似文献
84.
《Journal of separation science》2003,26(11):1057-1062
The use of glass fiber as a support material for a surface compound serving to generate gaseous standard mixtures of ethene is described. The technique is based on the process of thermal decomposition of the surface compound in a desorber connected on‐line via a multi‐port valve to the calibrated device. The surface compound undergoes thermal decomposition at 245°C, yielding known amounts of ethene. The method enables on‐line preparation of a standard mixture immediately before the calibration step. Consequently, it can be also applied for the generation of standard mixtures containing volatile, malodorous, unstable, and toxic compounds. 相似文献
85.
Two simple modification methods for ordered mesoporous silicas were examined and compared. MCM-41 molecular sieve was physically coated with 4-cyano-4-biphenyl [4(4-pentenyloxy)]benzoate (CBPB) and chemically modified using trimethylethoxysilane. The structural and surface properties of the obtained materials were characterized using elemental analysis, thermogravimetry and nitrogen adsorption over a wide pressure range.It was shown that the pore size of the MCM-41 material was not decreased significantly after the coating procedure, even for high loadings of CBPB. Moreover, low pressure adsorption measurements indicated that significant fractions of the MCM-41 surface were not covered by CBPB, even for high CBPB loadings, which suggests that the attained coverage may be very nonuniform. The chemical bonding procedure led to a marked decrease in the pore size and change of surface properties.It was demonstrated that nitrogen adsorption measurements provide a means of a thorough characterization of modified MCM-41 materials, allowing to estimate the surface area, pore volume and pore size distribution. Moreover, low pressure adsorption data can be used to qualitatively or semiquantitatively assess the surface coverage of the coated/bonded organic groups, which may be used to estimate the uniformity of the coverage and therefore, the usefulness of the modification procedure. 相似文献
86.
The potential of quaternized wood (QW) chips in removing hexavalent chromium from synthetic solution and chrome waste under
both batch and continuous-flow conditions was investigated. Sorption was found to be dependent on pH, metal concentration,
and temperature. QW chips provide higher sorption capacity and wider pH range compared with untreated wood chips. The equilibrium
data could be fitted into the Langmuir isotherm model, and maximum sorption capacities were calculated to be 27.03 and 25.77
mg/g in synthetic chromate solution and chrome waste, respectively. The presence of sulfate in high concentration appeared
to suppress the uptake of chromium by QW chips. Column studies showed that bed depth influenced the breakthrough time greatly
whereas flow rate of influent had little effect on its sorption on the column. 相似文献
87.
研究了聚偏氟乙烯 (PVDF)自由基引发的氯化反应。考察了各种因素 ,如氯化剂、引发剂的种类及浓度 ,反应介质、反应温度和反应时间的影响 ,确定了合成氯化PVDF的最佳反应条件。采用碱熔法测定氯含量 ,用HNMR进行了结构表征 ,并用溶度参数法、接触角法、DTA TG等方法对PVDF氯化前后的溶解性、附着力、熔点等性能进行了测试。结果表明 ,氯原子成功地引入到了PVDF上 ,当氯含量增加到 8 3 %时 ,氯化PVDF的熔点由 1 63℃降至 1 3 0℃左右 ,附着力也有了明显的改善 ,与水的接触角由 90°降至 5 4°,由不溶于丙酮变为溶于丙酮 ,对甲醇和四氯化碳的溶度参数的变化也说明了氯化PVDF的溶解性能变好 ,由TG曲线可知 ,氯化PVDF的热稳定性比改性前虽有一定的降低 ,但其分解温度仍在 3 0 0℃以上 相似文献
88.
Summary The effect of pre-adsorbed benzene and ethanol on the adsorptive properties of natural zeolite (clinoptilolite) has been studied
by gas-solid chromatography. It has been shown that modification of the solid surface by volatile organics has a significant
influence on the adsorptive properties. The modification is of the same order as the more difficult modification by inorganics,
as illustrated here by clinoptilolite modification with Co2+. Energy distribution of surface adsorptive sites appears to be continuous and confirms previous finding that only a small
proportion of active sites is responsible for most adsorbate retention.
Part II reference [4] 相似文献
89.
Synthesis and Characterization of a Novel Biomaterial: Maleic Anhydride-modified Poly(dl-lactic acid) 总被引:2,自引:0,他引:2
YanFengLUO YuanLiangWANG XuFengNIU JunPAN LiangPingSHI 《中国化学快报》2004,15(5):521-524
A novel modified poly(dl-lactic acid) (PDLLA) was obtained by covalently grafting of maleic anhydride onto the backbone of PDLLA, attempting to improve PDLLA‘s hydrophilicity and cell affinity and to provide reactive groups for further chemical modification. FTIR, ^13 C NMR and DSC were used to characterize the maleic anhydride-modified PDLLA. 相似文献
90.
Synthesis of the Biomimetic Polymer: Aliphatic Diamine and RGDS Modified Poly(d,l-lactic acid) 总被引:4,自引:0,他引:4
Xu Feng NIU Yuan Liang WANG Yan Feng LUO Jun PAN Li Xia GUO 《中国化学快报》2005,16(8):1035-1038
A novel poly(d, /-lactic acid) (PDLLA) based biomimetic polymer was synthesized by grafting maleic anhydride, butanediamine and arg-gly-asp-ser (RGDS) peptides onto the backbone of PDLLA, aiming to overcome the acidity and auto-accelerating degradation of PDLLA during degradation and to improve its biospecificity and biocompatibility. The synthetic copolymer was characterized by FTIR, ^13C NMR and amino acid analyzer (AAA). 相似文献