量子线/绝缘层/p波超导体结的隧道谱

用Bogoliubov-de Gennes方程来研究量子线/绝缘层/p波超导体结(q/I/p)中的准粒子输运过程，利用推广的Blonder，Tinkham和Klapwijk模型计算绝对零度和有限温度下q/I/p的一级谐波隧道谱.和量子线/绝缘层/d波超导体结的一级谐波隧道谱不同的是q/I/p的一级谐波隧道谱中存在零偏压电导峰.随着q/I/p中绝缘层的势垒散射增强，q/I/p的一级谐波隧道谱中零偏压电导峰变高.     

光学读出微梁阵列红外成像及性能分析

在构建的光学读出微梁阵列(焦平面阵列FPA)非制冷红外成像系统中，实现了无硅基底FPA置于空气中对人体的热成像. 通过FPA在不同真空度环境条件下的成像结果进行比较，分析了热导和系统噪声值随气压变化的关系，以及对系统成像性能的影响，并对气体分子热运动自由程大于空气传热层特征尺度时的气体热传导模型进行了修正分析和实验验证. 实验结果表明：FPA置于空气中时，气体分子撞击微梁引起的微梁反光板无序振动产生的光学读出噪声成为系统噪声的主要来源. 当真空度小于1Pa时，总热导和光学读出噪声值的变化都趋于平缓；当真空度小于10^-2Pa时，空气热导的影响可忽略，总热导降低到微梁感热像素的辐射极限，光学读出噪声也降低到一极小值. 实验结果与理论分析相符合. 关键词： 非制冷红外成像 光学读出 双材料微梁阵列 热导     

水分子对碳链的输运性质影响的第一性原理研究

用基于密度泛函理论的非平衡格林函数方法研究了水分子对7个碳原子组成的一维原子链的输运性质的影响.碳原子链放在具有有限截面的Al(100)电极中.研究发现，碳原子链上的水分子的数目和放置的位置的不同将对体系输运性质产生很大的影响.特别是，单个H₂O分子对碳链平衡电导的影响随其摆放位置的不同而出现奇偶振荡，例如，当位于奇数编号的碳原子上时，电导取极大值，当位于偶数编号的碳原子上时，取极小值.将两个H₂O分子置于不同的碳原子正上方时，在不同的位置平衡电导相差很大，在某些特殊的情况下原本受到抑止的第三个本征通道也有较大的贡献.此外，还研究了放置两个水分子时，体系的电流-电压(I-V)特性，随着水分子的数目和放置的位置不同，某些情况可能出现较大幅度的负微分电阻，而在另一些情况下却没有出现. 关键词： 平衡电导 透射谱 负微分电阻     

Phase-shift analysis of electric conductance through nanostructure bridges

We present our theoretical studies of electric conductance through nanostructure bridges. A simple expression of the electric conductance is obtained by using the phase-shift analysis. The phase-shifts are given by solving the characteristic equation obtained by extending the method applied to the single impurity problem in the metal. It is shown that the importance of the effect due to multiple orbitals in nanostructures. The conductance of the chain consisting atoms with sp_z character such as Al is given.     

Thermal conductance in quantum wire with two obstacles

Based on the scattering-matrix method, the influence of obstacles on the thermal conductance in quantum wire was investigated. Three types of obstacles are employed in our calculation. We present a detailed study of the thermal conductance as a function of distance between two obstacles and temperature. The results show that there is qualitative difference in the dependence of the thermal conductance versus width between two obstacles for different temperatures. We also find that the calculated thermal conductance increases with the width W of quantum wire in all cases.     

Pervaporation in chemical analysis

Unlike thermal processes such as distillation, pervaporation relies on the relative rates of solute permeation through a membrane and is a combination of evaporation and gas diffusion. The analytical pervaporation systems consist of a membrane module suitable for liquid sample introduction and a vacuum (or a sweeping gas) on the permeate side. It has been used in a wide range of applications including the analysis of various organic and inorganic compounds, and sample concentration. It has been directly interfaced with gas chromatography, spectrophotometry, capillary electrophoresis, electrochemical detectors, liquid chromatography, and mass spectrometry. A wide range of liquids, slurries, and solids samples has been analyzed using these techniques. This review highlights the basic principles of the pervaporation and the state of its current development as applied to analytical chemistry.     

Sm3+ Potentiometric Membrane Sensor as a Probe for Determination of Some Pharmaceutics

The increase use of ion sensors in the fields of environmental, agricultural, and medical analysis is stimulating analytical chemists to develop new sensors for fast, accurate, reproducible, and selective determination of various ions. In this study a new samarium membrane sensor was constructed and for the first time, it was applied as a probe in indirect determination of hyoscine, homatropine, and tramadol drugs in their pharmaceutical formulation. The proposed membrane sensor was constructed based on a membrane containing 2% sodium tetraphenyl borate (NaTPB) as an anionic additive, 63% dibutyl phthalate (DBP) as solvent mediator, 5% ionophore, and 30% poly(vinyl chloride) (PVC). The proposed Sm(III) electrode exhibits a Nernstian response of 19.35±0.2 mV per decade of samarium concentration, and has a lower detection limit of 1.0×10^?7 M. The linear range of the sensors was 1.0×10^?7–1.0×10^?1 M. It works well in the pH range of 3.0–8.0.     

Study of the membrane effect on turbulent mixing measurements in shock tubes

The effect of the thin membrane on the time evolution of the shock wave induced turbulent mixing between the two gases initially separated by it is investigated using two different sets of experiments. In the first set, in which a single-mode large-amplitude initial perturbation was studied, two gas combinations (air/SF and air/air) and two membrane thicknesses were used. The main conclusion of these experiments was that the tested membrane has a negligible effect on the evolution of the mixing zone, which evolves as predicted theoretically. In the second set, in which similar gas combinations and membrane thicknesses were used, small amplitude random-mode initial perturbation, caused by the membrane rupture, rather than the large amplitude single-mode initial perturbation used in the first set, was studied. The conclusions of these experiments were: (1) The membrane has a significant effect on the mixing zone during the initial stages of its growth. This has also been observed in the air/air experiment where theoretically no growth should exist. (2) The membrane effect on the late time evolution, where the mixing zone width has reached a relatively large-amplitude, was relatively small and in good agreement with full numerical simulations. The main conclusion from the present experiments is that the effect of the membrane is important only during the initial stages of the evolution (before the re-shock), when the perturbations have very small amplitudes, and is negligible when the perturbations reach relatively large amplitudes. Received 29 August 1998 / Accepted 25 December 1998     

Stationary diffusion in the membrane systems with the ongoing reversible chemical reactions

The diffusion phenomena were analyzed using the phenomenological equations of the thermodynamics of irreversible processes. The diffusion coefficient was thought to be dependent on local concentrations and pressure, unlike it was done in the linear theories. The reversible chemical reactions were modeled as intermolecular interaction. The ideal and regular solutions and solutions, described by the Margules's and Sketchard–Hammer's equations, were investigated and analytical solutions were found.     

Hydrophobic effect for anionic dye - cationic surfactant interaction in aqueous and mixed solvent

Abstract

The interaction between anionic dyes [Reactive Orange 122 (R.O 122), Reactive Blue 19 (R.B 19), Reactive Violet 5 (R.V 5) and Acid Green 20 (A.G 20)] with cationic surfactant cetyltrimethylammoniun bromide (CTAB) has been investigated by spectrophotometry and conductance technique. The used dyes are characterized by tautomeric behavior which affects the mechanism of the interaction. Various parameters such as dye structure, surfactant composition, solvent composition, temperature and pH of the medium were studied. The spectral data were applied for calculating the binding constant between dye and surfactant (K_b), fraction of micellization (?_mic), and standard free energy change of binding (ΔG°_b) in 0,10,20 and 30 v/v % acetonitile (AN). Conductance technique was constructed to estimate the ion pairing constant (K_a) at different temperatures and v/v % AN. Thermodynamic parameters (ΔG°, ΔH° and ΔS°) for ion pair formation were evaluated. The role of hydrophobic and electrostatic effect on dye-surfactant interaction was discussed.