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81.
Synthesis of thermally stable aromatic poly(spiroorthocarbonate)s having a Cardo or bent structure 下载免费PDF全文
Masaki Moritsugu Ryota Seto Kozo Matsumoto Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2016,54(10):1409-1416
Novel poly(spiroorthocarbonate)s [poly(SOC)]s having a Cardo or bent structure were synthesized by polycondensation of several bis‐catechols having fluorene (BCFL), spirobisindane (BCSPI), or spirobischromane (BCSPC) in the structure with 2,2,6,6‐tetrachlorobenzo[1,2‐d:4,5‐d’]bis[1,3]dioxole (4ClBD). Synthesis of poly(SOC)s was confirmed by NMR and IR spectrometry. The poly(SOC)s obtained from BCFL or BCSPC were soluble in common organic solvents. The glass transition temperature of the poly(SOC)s was not detected by differential scanning calorimetry (DSC) in the range of 50–300 °C. The 10 wt % decomposition temperature of the poly(SOC)s was found to be above 400 °C. These results indicated the high thermal stability of the poly(SOC)s. Soluble poly(SOC)s could be possessed to form a film on a glass plate by the spin coat method. The obtained polymer films were 0.2 μm in thickness with 95% light transmission in the optical wavelength range. These results suggested that the Cardo or bent structure may block the packing of the main‐chain of the structure, which improves the solubility of the polymers, increases transparency, and enhances the thermal stability of SOCs. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1409‐1416 相似文献
82.
Junpei Miyake Keita Fukasawa Masahiro Watanabe Kenji Miyatake 《Journal of polymer science. Part A, Polymer chemistry》2014,52(3):383-389
Five kinds of ammonium groups functionalized partially fluorinated poly(arylene ether) block copolymer membranes were prepared for investigating the structure–property relationship as anion exchange membranes (AEMs). Consequently, the pyridine (PYR)‐modified membrane showed the highest alkaline and hydrazine stability in terms of the conductivity, water uptake, and dry weight. The chloromethylated precursor block copolymers were reacted with amines, such as trimethylamine, N‐butyldimethylamine, 1‐methylimidazole, 1,2‐dimethylimidazole, and PYR to provide the target quaternized poly(arylene ether)s. The structures of the polymers, as well as model compounds and oligomers were well characterized by 1H NMR spectra. The obtained AEMs were subjected to water uptake and hydroxide ion conductivity measurements and stabilities in aqueous alkaline and hydrazine media. The pyridinium‐functionalized quaternized polymers membrane showed the highest alkaline and hydrazine stability with minor losses in the conductivity, water uptake, and dry weight. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 383–389 相似文献
83.
Shahram Mehdipour-Ataei Samal Babanzadeh 《International Journal of Polymer Analysis and Characterization》2020,25(3):147-157
AbstractA new monomeric building block was prepared via three consecutive reactions. 4-(4-Nitrobenzyl)pyridine was catalytically reduced to 4-(4-aminobenzyl)pyridine by converting the nitro to amino group. In second step, the later compound was reacted with 3,5-dinitrobenzoyl chloride to obtain a dinitro compound which finally was converted to a new diamine by reduction of nitro groups. Polycondensation reactions of the diamine with diacidchlorides led to preparation of novel cardo polyamides with high thermal stability and flame retardancy, as well as improved solubility. The structure-property relations were studied by varying the diacidchlorides to investigate the effect of symmetry and aromaticity on the polymers. 相似文献
84.
85.
Wei Peng Jie Dong Han‐Bin Li Christine Chow Qiao‐Sheng Hu 《Journal of polymer science. Part A, Polymer chemistry》2019,57(14):1606-1611
Room temperature Suzuki cross‐coupling polymerization of aryl dibromides/diiodides with aryldiboronic acids/acid esters with t‐Bu3P‐coordinated 2‐phenylaniline‐based palladacycle complex, [2′‐(amino‐kN)[1,1′‐biphenyl]‐2‐yl‐kC]chloro(tri‐t‐butylphosphine)palladium, as a general precatalyst is described. Such room temperature Suzuki cross‐coupling polymerization is achieved by employing six equivalents or more of the base and affords polymers within an hour, with the yields and the molecular weights in general comparable to or higher than reported results that required higher reaction temperature and/or longer polymerization time. Our study provides a general catalyst system for the room temperature Suzuki cross‐coupling polymerization of aryl dibromides/diiodides with aryldiboronic acids/acid esters and paves the road for the investigation of employing other monodentate ligand‐coordinated palladacycle complexes including other electron‐rich monophosphine‐coordinated ones for room temperature cross‐coupling polymerizations. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1606–1611 相似文献
86.
R. Vasanthakumari 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(4):463-468
Differential scanning calorimetry has been used to study the thermal crystallization of poly(L-lactic acid) (PLLA) and pentaerythrityl tetrabromide mixtures at different compositions. The melting temperature-composition phase diagram of the system reveals that PLLA forms a simple eutectic with pentaerythrityl tetrabromide, with a eutectic composition of 46% (w/w) of PLLA and a eutectic temperature of 422 K. Investigation of the microstructures obtained after removal of the diluent from the eutectic using scanning electron microscopy shows that the simultaneous crystallization of PLLA and the diluent proceeded in such a way that the diluent rods are the leading phases. 相似文献
87.
Poly(ether amide)s were prepared by polycondensation of 1,13‐diamino‐4,7,11‐trioxatridecane (DTT) with the bisimidazolide or with the bis N‐hydroxysuccinimide ester of sebacic acid. Four different solvents and three different temperatures were compared. The highest molecular weights were obtained with the bisimidazolide in dimethylsulfoxide (DMSO) at 60°C. MALDI‐TOF mass spectra revealed the existence of cyclic oligoamides and polyamides in all samples. The molar fraction of cycles considerably increased with higher molecular weights of the entire sample. The polycondensations were repeated under optimum conditions in the presence of α‐cyclodextrin to prepare polydisperse catenanes consisting of α‐cyclodextrin threaded on cyclic polyamides. Yet, despite broad variation of the reaction conditions, only cylic polyamides free of cyclodextrin were isolated. Furthermore, a pseudorotaxane was prepared from DTT and α‐cyclodetrin and polycondensed with bis‐(4‐chlorophenyl)sebacate. Again, only cyclic polyamides free of cyclodextrin were detectable. 相似文献
88.
The radiation-induced polymerization of ethyl vinyl ether was studied in n-pentane and neopentane solutions under super-dry conditions. The free ion yields of these solvents are reported to be 0.16 and 1.0, respectively. The rate of polymerization in neopentane was about twice as fast as in n-pentane. The dose-rate dependence of the rate of polymerization was found to be nearly 0.50 in both solutions. It seems clear that the free solvent ions do, indeed contribute to the initiation. Regenerative chain transfer to monomer played a more important role in n-pentane than in neopentane as revealed by the molecular weight of the polymers. 相似文献
89.
Five new optically active aromatic poly(amide-imide)s (PAIs) 5a–e were prepared from a direct polycondensation reaction of a new diacid of N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic)-bis-L-isoleucine 3 with various aromatic diamines 4a–e in a medium consisting of triphenyl phosphite (TPP), calcium chloride (CaCl2), pyridine (Py) and N-methyl-2-pyrrolidone (NMP). The polycondensation reaction produced a series of novel poly(amid-imide)s 5a–e in quantitative yields with inherent viscosities of 0.39–0.51 dL/g. The resulting polymers were fully characterized by means of 1H-NMR, FT-IR spectroscopy, elemental analyses, inherent viscosity, solubility test, specific rotation and thermal properties of them were investigated using TGA/DTG and differential scanning calorimeter (DSC). The diacid 4 was synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6- tetracarboxylic dianhydride 1 with L-isoleucine 2 in acetic acid solution. 相似文献
90.
Abstract Macroazoinitiator (MAI) was prepared from hydroxyl‐terminated polybutadiene (HTPB) and 4,4′‐azobis‐4‐cyanopentanoic acid by direct polycondensation in the presence of 1‐methyl‐2‐chloropyridinium iodide at room temperature. This MAI used for block copolymerization of AAm at 60°C gave the best results in chloroform but the formation of a crosslinked product could not be ruled out in dioxane. It was inferred that for production of a linear block copolymer, homogeneous reaction mixture was required. The resulting products were characterized by spectral studies IR and NMR, viscosity measurements. Distinct phase segregation of hydrophobic and hydrophilic blocks was evident through DSC analysis. 相似文献