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111.
V. V. Yanilkin V. I. Morozov F. F. Nigmadzyanov T. V. Gryaznova A. M. Kibardin 《Russian Chemical Bulletin》1998,47(8):1478-1480
Electrooxidation of 2-R-1,3-dibutyl-4,5-dimethyl-2,3-dihydro-1H-1,3,2-diazaphospholes with tri- and tetracoordinated phosphorus atoms were studied. Reversible one-electron oxidation gives
radical cations at potentials of −0.37 to +0.36 V. Magnetic parameters of the radical cations were measured.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1522–1524, August, 1998. 相似文献
112.
Karnataka state in India is very well known for its cotton cultivation and there are innumerable varieties of these cotton fibers. Although, the yield and other types of characterization have been carried out on these fibers, the structure-property relation is not well studied till today. We have examined four different raw cotton fibers using Wide Angle X-ray Scattering (WAXS) technique and also we have computed micro-crystalline parameters. This study brings out the structure-property relation in cotton fibers. 相似文献
113.
Constable EC Handel RW Housecroft CE Farràn Morales A Ventura B Flamigni L Barigelletti F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(13):4024-4034
A new series of V-shaped trinuclear metallorods and X-shaped pentanuclear metallostars has been prepared by the reaction of metal complexes bearing pendant phenolic functionalities with complexes containing electrophilic ligands. Specifically, {M(tpy)2} motifs (M=Ru or Os; tpy=2,2':6',2'-terpyridine) bearing one or two pendant 3,5-dihydroxyphenyl substituents at the 4-position of the central ring of the tpy have been reacted with the complexes [Ru(tpy)(Xtpy)]2+ (X=Cl or Br) to form new ether-linked species. The energy transfer from ruthenium to osmium in these complexes has been investigated in detail and the efficiency of transfer shown to be highly temperature dependent; the energy transfer is highly efficient at low temperature, whereas at room temperature nonradiative and nontransfer deactivation of the excited {Ru(tpy)2}* domains is most significant. 相似文献
114.
Tomoko Nii Akira Takamura Kiminori Mohri Fumiyoshi Ishii 《Colloids and surfaces. B, Biointerfaces》2003,27(4):436-332
We examined hydrogenated purified egg yolk lecithins, having practical advantages over non-hydrogenated ones, as liposomal membrane materials. Liposomes were prepared by the microencapsulation vesicle (MCV) method in which liposomes are formed through two-step emulsification and dispersion. Three types of purified egg yolk lecithins with different iodine values were examined after being dissolved in one of three lipid solvents. The liposome size increased as the temperature during the second emulsification increased, being closer to the boiling temperature of the solvent. The preparation temperature in relation to the transition temperature of each lecithin was also a factor affecting liposome sizes. As for the encapsulation efficiencies of the model compound calcein in liposomes, they differed mainly depending on the solubility of each lecithin in a lipid solvent and it was more obvious in hydrogenated lecithins. A high preparation temperature resulted in lower encapsulation efficiencies, suggesting that leakage of encapsulated calcein was facilitated at high temperature in the MCV methods. There was a significant correlation between liposome sizes and encapsulation efficiencies in non-hydrogenated purified egg yolk lecithin but not in hydrogenated ones. When using hydrogenated purified egg yolk lecithins as liposomal membrane materials, it was suggested that a lipid solvent should be chosen so that a lecithin completely dissolves under the preparation condition in order to achieve a higher encapsulation efficiency. Smaller liposome particles were obtained when the second emulsification was performed at a lower temperature compared with the boiling point of the lipid solvent. These findings can be applied to control encapsulation efficiencies and particle sizes in each particular liposome preparation enclosing therapeutic agents. 相似文献
115.
Pyrocarbon/silica gel adsorbents (carbosils, CS) with mesoporous Si-60 (Merck, granule size 0.2–0.5 mm) modified by pyrolysis of CH2Cl2 at 823 K and reaction time from 0.5 to 6 h and then hydrothermally treated at 473 K for 6 h were studied by means of TEM, adsorption and 1H NMR methods. Changes in the structural and adsorptive characteristics of hybrid adsorbents before and after hydrothermal treatment, which depend on pyrocarbon content (C
C), were analyzed on the basis of TEM micrographs and p-nitrophenol and nitrogen adsorption isotherms treated using a constrained regularization method. Interfacial water layers in aqueous suspension of CS were investigated by means of 1H NMR with freezing-out of bulk water at T < 273 K showing nonlinear changes in the Gibbs free energy of interfacial water with increasing C
C because of nonlinear dependence of the structural characteristics of pyrocarbon deposits and CS as a whole on C
C. 相似文献
116.
YanXUE HaiYingYANG YongTanYANG 《中国化学快报》2005,16(1):67-70
A new method was developed for the determination of the size distribution of nano-particles by capillary zone electrophoresis (CZE). Scattering effect of nanoparticles was studied. This method for the determination of size distribution was statistical. 相似文献
117.
Baumgartner T Bergmans W Kárpáti T Neumann T Nieger M Nyulászi L 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(16):4687-4699
To explore their suitability for applications in molecular optoelectronics and as sensory materials, novel dithieno[3,2-b:2',3'-d]phospholes have been synthesized and their reactivity and properties investigated. An efficient two-step synthesis allowed for a modular assembly of differently functionalized compounds. The dithieno[3,2-b:2',3'-d]phosphole system exhibits extraordinary optoelectronic properties with respect to wavelength, intensity, and tunability. Owing to the nucleophilic nature of the central phosphorus atom, its significant electronic influence on the conjugated pi system can be altered selectively by chemically facile modifications such as oxidation or complexation with Lewis acids or transition metals. All the dithienophosphole species presented show very strong blue photoluminescence with excellent quantum yield efficiencies supporting their potential utility as blue-light emitting components in organic light emitting diodes (OLEDs). Furthermore, depending on the electronic nature of the phosphorus center, the materials exhibit distinctive optoelectronic properties suggesting that the dithieno[3,2-b:2',3'-d]phosphole system may be useful as sensory material. Theoretical calculations, including time-dependent DFT methods, revealed the excellent predictability of the structures and optoelectronic properties of the functionalized dithienophospholes allowing the design of future dithieno[3,2-b:2',3'-d]phosphole-based materials to be "stream-lined". By using tin-functionalized dithienophosphole monomers, a strategy, which involves Stille coupling, towards extended pi-conjugated materials with significantly redshifted optoelectronic properties is also presented. 相似文献
118.
以硫酸铝液为原料,以氨水、氢氧化钠和铝酸钠为碱沉淀剂,采用pH摆动法制备了高比表面积、大孔径、窄孔分布、大孔体积氧化铝,考察了沉淀剂、沉淀温度及沉淀时酸侧pH值对氧化铝物性的影响,并对pH摆动法与等pH沉淀法的结果进行了比较.结果表明,通过改变制备参数可以获得高比表面积、大孔体积的氧化铝,当沉淀温度为70℃,pH摆动3或4次时,氧化铝的孔体积可高达1.0ml/g,比表面积仍大于300m2/g.用pH摆动法制得的样品比用等pH沉淀法制得的样品容易酸溶,对挤压成型有利.不同样品在酸溶液中的分散性表明,用氨水沉淀剂可获得相对较小的沉淀粒子.改变沉淀时酸侧的pH值,可导致沉淀粒子的结构发生变化. 相似文献
119.
A method of ultrasonic treatment (UST) was first used to modify the structure and electrochemical performance of nickel hydroxide for the active material of nickel series alkaline batteries. The experimental results showed that UST was an effective method to improve the electrochemical performance of β-Ni(OH)2 such as specific discharge capacity, discharge potential, electrochemical reversibility and oxygen evolution over-potential. The results of electrochemical impedance spectroscopy, powder X-ray diffraction and particle size distribution indicated that the improvement of the performance of β-Ni(OH)2 through UST was attributed to the reduction of the charge-transfer resistance (Rt) and the diffusion impedance (Zw), which resulted from the decrease of the crystallite and particle size and the increase of interlayer spacing. Diffusion coefficient of proton DH of ultrasonic treated β-Ni(OH)2 gained by CV tests was 1.13 × 10^-11 cm^2/s, and the average discharge specific capacity of ultrasonic treated β-Ni(OH)2 electrode was 301 mAh/g. 相似文献
120.
Exfoliated polystyrene (PS)/laponite nanocomposites were prepared successfully. The characteristic doo1 diffraction peak of organo-laponite disappeared in the XRD patterns of nanocomposites, indicating that the laponite layers were exfoliated and the ordered crystal structure of laponite was destroyed because of the styrene polymerization. TEM observations showed that the exfoliated laponite primary particles were dispersed randomly in the PS matrix with lateral dimensions from 1 nm to 10 rim. SEM results showed that the PS/laponite nanocomposite particles were almost monodispersed spheres with the size of about 120 rim. Because of the interaction between PS and laponite nanolayers, the nanocomposites exhibited higher thermal stability and glass transition temperature when compared to pure PS. 相似文献