中频小型矢量水听器设计研究

中频小型同振式矢量水听器采用低密度复合材料作为矢量通道外壳、压电加速度计作为内部振动传感器，以拾取水下声场中的矢量信息。与以往同振式矢量水听器设计不同的是每个矢量通道中只放置一只压电加速度计，这样，不仅减小了矢量水听器的体积，降低了水听器的整体平均密度，而且消除了以往同振式矢量水听器设计中矢量通道采用两只配对传感器而引起的相位不一致给矢量水听器定向带来的影响。而声压通道采用PVDF压电薄膜作为敏感元件，以拾取水下声场中的标量信息。     

弹性介质中圆柱壳动力响应研究的现状和展望

一、引言在地震动情况下,地下结构与地面结构相比较其动力响应是十分不同的。以桥梁和水堤为例,对这类结构的设计,水平惯性力是一个极为重要的因素。可是,对于地下结构,以埋管为例,惯性荷载主要由其周围的土介质所承受。地下管道系统的地震破坏,     

Testing Aluminum Alloy from Quasi-static to Dynamic Strain-rates with a Modified Split Hopkinson Bar Method

An aluminum alloy¹ was tested at quasi-static to dynamic strain-rates (from 10⁻¹ to 5 10³ s⁻¹), using a single measuring device, a modified Split Hopkinson Bar. A wave separation technique [Bussac et al., J Mech Phys Solids 50:321–350, 2002] based on the maximum likelihood method was applied to process the strain and velocity measurements recorded at various points on each bar. With this method, it is possible to compute the stress, strain, displacement and velocity at any point on the bar. Since the measurement time is unlimited, the maximum strain measured in a given specimen no longer decreases with the strain-rate, as occurs with the classical Split Hopkinson Bar method. ¹The authors wish to thank the automobile manufacturer who provided samples of the alloy used in this study. For reasons of commercial and industrial confidentiality, we were not informed about the composition of this alloy.     

Synthesis, spectroscopic characterization, DFT studies and biological assays of a novel gold(I) complex with 2-mercaptothiazoline

A new gold(I) complex with 2-mercaptothiazoline (MTZ) with the coordination formula [AuCN(C₃H₅NS₂)] was synthesized and characterized by chemical and spectroscopic measurements, DFT studies and biological assays. Infrared (IR) and ¹H, ¹³C and ¹⁵N nuclear magnetic resonance (NMR) spectroscopic measurements indicate coordination of the ligand to gold(I) through the nitrogen atom. Studies based on DFT confirmed nitrogen coordination to gold(I) as a minimum of the potential energy surface with calculations of the hessians showing no imaginary frequencies. Thermal decomposition starts at temperatures near 160 °C, leading to the formation of Au⁰ as the final residue at 1000 °C. The gold(I) complex with 2-mercaptothiazoline (Au-MTZ) is soluble in dimethyl sulfoxide (DMSO), and is insoluble in water, methanol, ethanol, acetonitrile and hexane. The antibacterial activities of the Au-MTZ complex were evaluated by an antibiogram assay using the disc diffusion method. The compound showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive) and Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. Biological analysis for evaluation of the cytotoxic effect of the Au-MTZ complex was performed using HeLa cells derived from human cervical adenocarcinoma. The complex presented a potent cytotoxic activity, inducing 85% of cell death at a concentration of 2.0 μmol L⁻¹.     

Experimental investigation of the difference in B-term dominated band broadening between fully porous and porous-shell particles for liquid chromatography using the Effective Medium Theory

The difference in B-term diffusion between fully porous and porous-shell particles is investigated using the physically sound diffusion equations originating from the Effective Medium Theory (EMT). Experimental data of the B-term diffusion obtained via peak parking measurements on six different commercial particle types have been analyzed (3 porous and 3 non porous). All particles were investigated using the same experimental design and test analytes, over a very broad range of retention factor values. First, the B-term reducing effect of the solid core (inducing an additional obstruction compared to fully porous particles) has been quantified using the Hashin-Shtrikman expression, showing that the presence of a solid core can account for a reduction of about 11% when the core diameter makes up 63% of the total particle diameter (Halo and Poroshell-particles) and a reduction of 16% when the core diameter makes up 73% (Kinetex). Remaining differences can be attributed to differences in the microscopic structure of the meso-porous material (meso-pore diameter, internal porosity or relative void volume). The much lower B-term diffusion of Halo and Kinetex particles compared to the fully porous Acquity particles (some 20-40% difference, of which about 10-15% can be attributed to the presence of the solid core) can hence largely be attributed to the much smaller internal porosity and the smaller pore size of the meso-porous material making up the shell of these particles.     

电感耦合等离子体质谱法测定中低合金钢中痕量铝

应用电感耦合等离子体质谱法测定了中、低合金钢中痕量铝,并对质谱仪的工作条件作了优化.用微波加热消解技术对样品进行前处理,用混合比例为3比1比1的浓硝酸、浓盐酸及浓氢氟酸的混合酸作为溶解酸.对微波炉的操作程序及参数作出详细叙述.此方法的检出限为ω(Al)1.9×10-6%,对浓度水平为ω(Al)1.4×10-4%的试样进行精密度试验,其结果的标准偏差值均小于6.0%.     

电感耦合等离子体质谱仪同时测定地下水中的溴和碘

研究并建立了电感耦合等离子体质谱仪（ICP-MS）同时测定地下水中溴、碘元素的方法。使用0.025%NH3.H2O作为测定介质,该方法线性范围宽,检出限为：79Br为0.02μg/L;127I为0.4μg/L。加标回收率在94.0%—102.4%之间。     

Synthetic studies on the DEF-rings of FR182877 and hexacyclinic acid

A synthesis of model DEF-rings of the polyketide anti tumor natural products FR182877 and hexacyclinic acid has been achieved. The key steps in the synthesis are an intramolecular Pd(0) catalyzed allylic substitution reaction, which was used to generate a 9-membered carbocycle, and a novel transannular iodocyclization reaction which furnished the DF-rings of both natural products.     

Amplified spontaneous emission in dye-laser systems for single photon amplification

A longitudinally pumped dye-laser amplifier is numerically investigated for the amplification of a very low intensity signal (as low as one photon per pulse), which is easily hindered by the simultaneous amplification of spontaneous emission. From the relevant set of coupled rate equations for population and photon fluxes the spatial dependence of these quantities is accounted for. The equations are solved numerically in some significant practical situations. The results describe the dependence of the amplified-spontaneous-emission (ASE) output flux on the pumping rate, on the spectral narrowing process and on the total spontaneous emission for a pulse in the selected angular width. The performance of dye-laser amplifiers is described by the same set of equations, and the gain characteristics of such systems are analyzed as functions of the pumping rate.