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81.
The secondary metabolites of different Ephedra plants are various. Therefore, the discrimination of different Ephedra plants is significant. An objective, easy-to-use, rapid and pollution-free approach is proposed for discriminating Ephedra plants of different species, habitats and picking times on the basis of diffuse reflectance Fourier transform near infrared spectroscopy (FT-NIRS) measurements and multivariate analysis. The Fourier transform near infrared diffuse reflectance spectra (NIRDRS) were acquired from 37 pulverized samples of Ephedra plants put in glass vials in the near infrared (NIR) region between 10 000 and 4000 cm−1, averaging 64 scans per spectrum at a resolution of 4 cm−1. After spectra processing and data pre-processing, spectral data were analyzed respectively with three multivariate analysis techniques: discriminant analysis (DA), self-organizing map (SOM) and back-propagation artificial neural network (BP-ANN). The proposed method could distinguish not only the Ephedra plants of three species and two habitats but also the plants picked at different times of day without special sample treatment and the use of chemical reagents. The performance indexes of the DA model were 84.2-91.9% and the prediction accuracies of both the SOM and the BP-ANN models reached 93.3-100.0%. 相似文献
82.
83.
Yughandhar Sreedhar Neelam Rekha Dasari P. Reddy Prasad M. Sankar Nayak 《Journal of Saudi Chemical Society》2010,14(2):149-155
A novel analytical reagent 4-(2-hydroxy phenyl ethaminodiol), benzene-1,3-diol(4-2-HPEDB-1,3,D) was synthesized for the determination of molybdenum(VI). The present paper reveals the detailed study of electroanalytical behaviour for [Mo-(4-2-HPEDB-1,3,D)] complex under optimized conditions. The peak obtained for [Mo-(4-2-HPEDB-1,3,D)] prevent the interference of foreign ions which shows the sensitivity of the proposed method. The linearity was maintained at the concentration range of 0.5–200 μg/mL at pH 4.5 with correlation factor 0.9997. The present method was successfully applied for the analysis of molybdenum(VI) in biological fluids and plant material. The results obtained from the proposed method show good agreement with reference method. 相似文献
84.
A novel method using liquid chromatography coupled to electrospray ionization mass spectrometry (LC-ESI-MS) has been optimized and established for the qualitative and quantitative analysis of ten active phenolic compounds originating from the pigeon pea leaves and a medicinal product thereof (Tongluo Shenggu capsules). In the present study, the chromatographic separation was achieved by means of a HiQ Sil C18V reversed-phase column with a mobile phase consisting of methanol and 0.1% formic acid aqueous solution. Low-energy collision-induced dissociation tandem mass spectrometry (CID-MS/MS) using the selected reaction monitoring (SRM) analysis was employed for the detection of ten analytes which included six flavonoids, two isoflavonoids and two stilbenes. All calibration curves showed excellent coefficients of determination (r(2) ≥ 0.9937) within the range of tested concentrations. The intra- and inter-day variations were below 5.36% in terms of relative standard deviation (RSD). The recoveries were 95.08-104.98% with RSDs of 2.06-4.26% for spiked samples of pigeon pea leaves. The method developed was a rapid, efficient and accurate LC-MS/MS method for the detection of phenolic compounds, which can be applied for quality control of pigeon pea leaves and related medicinal products. 相似文献
85.
从“福岛第一核电站事故”看我国核能利用的核安全 总被引:1,自引:0,他引:1
文章简要说明了福岛第一核电站事故的起因、发展和后果,并对核电站全厂断电、反应堆压力容器及安全壳超压、氢爆等导致事故恶化的原因作了分析.文章还就导致福岛核事故的相关因素与我国核电站的安全设计及防范对策进行了分析比较.在吸取福岛核事故的经验教训方面,文章提出了若干值得引发关注的启示,作为我国在建和在役核电站的改进,以及新设计核电站的参考.文章还就我国能源的状况,核能发展的必要性,以及核能发展的方针进行了探讨. 相似文献
86.
通过对13种植物生长调节剂的试验,建立了用于筛选植物生长调节剂的生物检测方法,该方法第1步采用萝卜、黄瓜、小麦、油菜4种幼苗生长法联合筛选,第2步采用萝卜子叶扩张法、黄瓜子叶生根法联合筛选,这样能保证有生长调节剂活性的化合物在普筛中不被漏筛,而且方法简便,测试周期短。 相似文献
87.
《Analytical letters》2012,45(4):567-574
The goal of this study was to develop and validate a high-performance liquid chromatography method for the quantification of two essential oil constituents (myristicin and linalool) from extracts of the three aromatic plants exposed to low-intensity microwave radiation. The analysis was performed by high-performance liquid chromatography using a mobile phase consisting of ultrapure water and acetonitrile. The separations were carried out in the following conditions: isocratic conditions for 30 minutes with 100% acetonitrile and then linear gradient conditions from 100% acetonitrile to 25% acetonitrile for 15 minutes. The developed method was validated in terms of linearity, limits of detection, limits of quantification, precision, accuracy, and robustness. The results show that plants react differently under microwave stress and change their essential oil content as a response. 相似文献
88.
Fifteen new ferrocene derivatives containing 1H‐1,2,4‐triazole moiety were synthesized in various yields by the condensation of ferrocenecarboxaldehyde with 1‐aryl‐3‐(1H‐1,2,4‐triazo‐1‐yl)‐propen‐1‐ones in toluene. Their structures have been confirmed by 1H NMR, IR, MS and elemental analysis. In addition, the crystal structure of 4l was determined. The antifungal and plant growth regulatory activities of the title compounds are discussed. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
89.
合成了10个未见文献报道的三羧酸乙基DHT的酯类化合物,新化合物的水溶性、脂溶性均较DHT好,并有一定抗病毒活性,其中化合物2的活性最高,对TMV的抑制百分率达到90%,优于对比的DHT 相似文献
90.
District heating plants are becoming more common in European cities. These systems make it possible to furnish users with warm water while locating the production plants in the outskirts having the double benefit of lowering the impact of pollution on the center of the city and achieving better conversion performances. In order to amortize the costs throughout the year, the system often includes a combined heat and power (CHP) plant, to exploit the energy during the summer as well, when the demand for warm water decreases. A linear programming model for the optimal resource management of such a plant is presented and some results for a real case are reported. A distribution network design problem is also addressed and solved by means of mixed integer linear programming. 相似文献