Adsorption of carbon dioxide on microporous carbon adsorbent PAU-10

Carbon dioxide adsorption on the microporous carbon adsorbent PAU-10 within the 177.8—423 K temperature and 0.1—5.13·10⁶ Pa pressure intervals was studied. The isosteres of absolute adsorption are well approximated by straight lines, which do not change their slope on going to temperatures higher than the critical temperature of CO₂. An increase in the differential molar isosteric heat of adsorption (q _st) at 0 < a < 1 mmol g^–1 is explained by the influence of the endothermic effect of adsorption expansion of the adsorbent. In the region of high pressures and nonideal gas phase, q _st is temperature-dependent.     

Polytrimethylsilylpropyne as adsorbent for separation of gases

Polytrimethylpropyne supported on a solid substrate was proposed as a chromatographic adsorbent for the separation of hydrocarbon gases. The heats of adsorption of hydrocarbon gases were determined. The efficiency of application of this sorbent for the selective separation of C₁--C₄ hydrocarbon gases in packed columns was demonstrated.     

ADSORPTION OF DINITROPHENOLS ONTO POLYMERIC ADSORBENTS AND ITS MECHANISM

1 INTRODUCTIONPhenol and many substitUted phenols, such as nitrophenols, chlorophenols and aminophenolset al, are the common organic pollutantS existing in wane water of many chemical plants.Treatment of the wastewater containing phenols is an important project for environmentprotection and has been studied by various methods, such as dialysis ['l, microbial degradation ['1,oxidation l'l, extracting with solvents I4] and adsorption with polymeric adsorbents IS]. Theadsorption method is v…     

新型磁性亲和吸附剂的制备及其在尿激酶纯化中的应用研究

合成了磁性聚乙烯醇和磁性聚甲基丙烯酸甲酯微球,并以它们为基质,用环氧氯丙烷、羰基二咪唑或溴化氰活化后,分别键合氨基乙酸、6-氨基己酸、乙二胺或己二胺为间隔臂,用1-乙基-3-(3-二甲基氨丙基)碳二亚胺盐酸盐或羰基二咪唑为偶联试剂,分别偶联对氨基苯甲脒、L-精氨酸甲酯、胍基乙酸或胍基己酸配体,合成了17种磁性亲和吸附剂,并用于尿激酶粗品的纯化.与前文制备的8种磁性亲和吸附剂作对照,研究了基质、活化试剂、间隔臂分子、偶联试剂及配体等因素对尿激酶纯化效果的影响.这些磁性亲和吸附剂在尿激酶的纯化中取得了较好的效果,大多数磁性亲和吸附剂的活性回收率在40%～70%之间,纯化倍数为15～40,吸附容量为0.08～0.2mg/mL.     

胶原-单宁树脂的制备及其对水溶液中UO2+2的吸附特性研究

以天然牛皮为原料,经胃蛋白酶处理制得水解胶原;通过胶原-黑荆树单宁-醛反应制备了胶原-单宁树脂(C-TR)吸附材料,并表征了材料的形貌,测定了材料的比表面积、热变形温度等性质。系统研究了C-TR对水溶液中UO22 的吸附特性。结果表明,C-TR对UO22 有较强的吸附能力。当温度为303K、pH=5.0、UO22 的初始浓度2.5mmol.L-1时,吸附容量达到1.49mmolU/g。升高温度,平衡吸附量增大。pH对吸附容量的影响较大,适宜的pH范围为5.0-6.0。C-TR对UO22 的吸附平衡符合Freundlich方程。吸附动力学可用拟二级速度方程来描述。C-TR对UO22 的吸附基本不受NaCl影响,该吸附材料可望用于海水中铀的富集和分离。     

用大孔氨甲基聚苯乙烯树脂选择性吸附分离茶多酚和咖啡因

3种市售树脂ADS-5、ADS-8和ADS-17对茶多酚和咖啡因的混合物水溶液的吸附表明,具有弱极性的ADS-8对茶多酚的吸附量最大.随着树脂极性的增加(ADS-5＜ADS-8＜ADS-17),从混合物中对茶多酚的选择性吸附作用增加,表明对茶多酚的吸附可能包含疏水作用和氢键,而对咖啡因的吸附为疏水作用.在此基础上,合成了不同交联度(8%～26%DVB)的大孔氨甲基聚苯乙烯树脂,这些树脂具有疏水基质和可与酚类化合物形成较强氢键的氨基.对茶多酚和咖啡因的混合物溶液的吸附表明,这些树脂对茶多酚具有高吸附量和高吸附选择性.交联度为10%的大孔氨甲基聚苯乙烯树脂对茶多酚具有最大的吸附量,交联度为22%的大孔氨甲基聚苯乙烯树脂对茶多酚具有最大的吸附选择性.     

Synthesis,Characterization and Application of Amine-Functionalized Hierarchically Micro-Mesoporous Silicon Composites for CO2 Capture in Flue Gas

An efficient CO₂ adsorbent with a hierarchically micro-mesoporous structure and a large number of amine groups was fabricated by a two-step synthesis technique. Its structural properties, surface groups, thermal stability and CO₂ adsorption performance were fully investigated. The analysis results show that the prepared CO₂ adsorbent has a specific hierarchically micro-mesoporous structure and highly uniformly dispersed amine groups that are favorable for the adsorption of CO₂. At the same time, the CO₂ adsorption capacity of the prepared adsorbent can reach a maximum of 3.32 mmol-CO₂/g-adsorbent in the actual flue gas temperature range of 303–343 K. In addition, the kinetic analysis results indicate that both the adsorption process and the desorption process have rapid adsorption/desorption rates. Finally, the fitting of the CO₂ adsorption/desorption experimental data by Avrami’s fractional kinetic model shows that the CO₂ adsorption rate is mainly controlled by the intra-particle diffusion rate, and the temperature has little effect on the adsorption rate.     

In Vitro and In Vivo Human Body Odor Analysis Method Using GO:PANI/ZNRs/ZIF−8 Adsorbent Followed by GC/MS

Among various volatile organic compounds (VOCs) emitted from human skin, trans-2-nonenal, benzothiazole, hexyl salicylate, α-hexyl cinnamaldehyde, and isopropyl palmitate are key indicators associated with the degrees of aging. In our study, extraction and determination methods of human body odor are newly developed using headspace-in needle microextraction (HS-INME). The adsorbent was synthesized with graphene oxide:polyaniline/zinc nanorods/zeolitic imidazolate framework-8 (GO:PANI/ZNRs/ZIF−8). Then, a wire coated with the adsorbent was placed into the adsorption kit to be directly exposed to human skin as in vivo sampling and inserted into the needle so that it was able to be desorbed at the GC injector. The adsorption kit was made in-house with a 3D printer. For the in vitro method, the wire coated with the adsorbent was inserted into the needle and exposed to the headspace of the vial. When a cotton T-shirt containing body odor was transferred to a vial, the headspace of the vial was saturated with body odor VOCs. After volatile organic compounds were adsorbed in the dynamic mode, the needle was transferred to the injector for analysis of the volatile organic compounds by gas chromatography/mass spectrometry (GC/MS). The conditions of adsorbent fabrication and extraction for body odor compounds were optimized by response surface methodology (RSM). In conclusion, it was able to synthesize GO:PANI/ZNRs/ZIF−8 at the optimal condition and applicable to both in vivo and in vitro methods for body odor VOCs analysis.     

Fe3O4@chitosan-bound boric acid composite as pH-responsive reusable adsorbent for selective recognition and capture of cis-diol-containing shikimic acid

Recently, shikimic acid (SA) has aroused great concern as the starting raw material for the synthesis of antiviral drug (Tamiflu) against the spread of influenza virus in the body. In this work, magnetic chitosan composite modified with boric acid and its application in SA recognition and separation was described. Chitosan (CT) with plenty of hydroxyl and amino groups was first coated on the surface of magnetic core Fe₃O₄, then carboxylic groups were grafted to the surface of Fe₃O₄@CT via anhydride modification, followed by the introduction of 3-aminophenylboronic acid (APBA). The uniform morphology and composition analysis of the adsorbent (Fe₃O₄@CT-COOH-BA) were characterized by FT-IR, XRD, XPS, SEM, TEM and UV–visible spectroscopy. The adsorption capacity of as-prepared material was explored in detail by batch mode experiments. The adsorption kinetics fitted well with a pseudo-second order model, and the adsorption isotherms was well described by the Langmuir model with a maximum adsorption capacity of 23.8 mg g⁻¹ at 25 °C. Solution pH plays a crucial role in adsorption process and the optimized pH was 8.0. In addition, Fe₃O₄@CT-COOH-BA could be easily reused through an external magnet and the adsorption capacity reduced by only 4% after five adsorption–desorption cycles. These results prove that boric acid modified magnetic chitosan composite is an effective and practical adsorbent for specific recognition and selective adsorption of cis-diol-containing compounds.     

ADSORBENTS USED IN THE CLEARANCE OF ENDOTOXIN

A series of modified poly (methyl methacrylate, PMMA) resins were prepared and compared their adsorption abilities to endotoxin. The results showed that adsorbents, which were grafted with tertiary amine and long spacing arms, had the best adsorption capacities and good blood compatibility, It is hopeful to be used as adsorbent in hemoperfusion for clinical clearance of endotoxin. The influence of original concentration of endotoxin on adsorption and the adsorption mechanism were also investigated.