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11.
卡尔曼滤波法用于ICP-AES分析时,在白色噪音情况下能给出准确的分析结果,当试样的某些组分未知时,测量噪音将不是白色的,分析结果将不准确。本文提出了一种加权增量卡尔曼滤波法来解决这个问题。 相似文献
12.
介绍了在瑞士ARL公司生产的ICP-3520AES型电感耦合等离子体原子发射光谱仪上存在的一种疑难故障的分析与排除过程,对同类型仪器的故障分析有借鉴作用。 相似文献
13.
《Surface and interface analysis : SIA》2003,35(3):327-328
This International Standard specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers for elemental and chemical‐state analysis at surfaces. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. This International Standard further specifies a method to establish a calibration schedule, to test for the kinetic energy scale linearity at one intermediate energy, to confirm the uncertainty of the scale calibration at one low and one high kinetic energy value, to correct for small drifts of that scale and to define the expanded uncertainty of the calibration of the kinetic energy scale for a confidence level of 95%. This uncertainty includes contributions for behaviours observed in interlaboratory studies but does not cover all of the defects that could occur. This International Standard is not applicable to instruments with kinetic energy scale errors that are significantly non‐linear with energy, to instruments operated at relative resolutions poorer than 0.2% in the constant ΔE/E mode or poorer than 1.5 eV in the constant ΔE mode, to instruments requiring tolerance limits of ±0.05 eV or less or to instruments equipped with an electron gun that cannot be operated in the energy range 5–10 keV. This standard does not provide a full calibration check, which would confirm the energy measured at each addressable point on the energy scale and should be performed according to the manufacturer's recommended procedures. Crown Copyright © 2003. Published by John Wiley & Sons, Ltd. 相似文献
14.
《Surface and interface analysis : SIA》2004,36(7):624-631
In this paper Al, Zn and Al–43.4Zn–1.6Si (AlZn) alloy‐coated steel have been treated with the organofunctional silane γ‐mercaptopropyltrimethoxysilane (γ‐MPS). The influence of different metal substrates on the structure and composition of the silane films was investigated with XPS and AES. The films were obtained by dipping the substrates in the silane solution followed by a blow‐dry procedure in nitrogen gas. The results show that the surface concentration of the deposited silane is independent of the metal substrate and that the thickness of the silane film is non‐uniform. The AES measurements indicate that the silane film covers the entire substrate surface and XPS analysis of the silane‐treated substrate surfaces at different take‐off angles indicates that the γ‐MPS molecule is randomly orientated. Also, the results show that the silane is well hydrolysed under the solution conditions used. Finally, in the zinc‐containing silane‐metal systems, i.e. the silane‐treated AlZn and Zn substrates, the results indicate that the γ‐MPS molecules can bond to the substrate surfaces via the thiol group of the molecule. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
15.
Recent developments in quantitative surface analysis by Auger (AES) and x-ray photoelectron (XPS) spectroscopies are reviewed and problems relating to a more accurate quantitative interpretation of AES/XPS experimental data are discussed. Special attention is paid to consideration of elementary physical processes involved and influence of multiple scattering effects on signal line intensities. In particular, the major features of core-shell ionization by electron impact, Auger transitions and photoionization are considered qualitatively and rigorous approaches used to calculate the respective transition probabilities are analysed. It is shown that, in amorphous and polycrystalline targets, incoherent scattering of primary and signal Auger and photoelectrons can be described by solving analytically a kinetic equation with appropriate boundary conditions. The analytical results for the angular and energy distribution, the mean escape depth, and the escape probability as a function of depth of origin of signal electrons as well as that for the backscattering factor in AES are in good agreement with the corresponding Mote Carlo simulation data. Methods for inelastic background subtraction, surface composition determination and depth-profile reconstructions by angle-resolved AES/XPS are discussed. Examples of novel techniques based on x-ray induced photoemission are considered. 相似文献
16.
17.
用ICP-AES法测定了东太平洋深海锰结核样品中二十多种主,次及微量元素,结果表明,表面瘤状和表面光滑两种类型锰结核的化学元素含量有较明显的区别,如表面光滑的锰结核TiO2含较高,而表面瘤状的锰结核Mn/Fe之值较高等。 相似文献
18.
Comprehensive studies have been carried out on the extraction behaviour of thorium matrix vis-a-vis 17 trace metallic elements using a novel extractant viz. Cyanex-923. The near total extraction of thorium and quantitative separation of these metals has been established using inductively coupled argon plasma–atomic emission spectrometry (ICP–AES). The recovery of few representative elements has been confirmed by radio-active tracer studies. The studies carried out here have enabled determination of μg/l amounts of all analyte elements with a precision of better than 1% RSD with prior chemical separation from as low as 1 g thorium sample in just five chemical extractions. 相似文献
19.
《Surface and interface analysis : SIA》2004,36(12):1523-1532
The effects of three non‐chromate‐based deoxidizers, namely NaBrO3/HNO3, (NH4)4Ce(SO4)4/H2SO4 and Fe(III)/HF/HNO3, on the Al alloy 7475‐T7651 were investigated. Several analytical methods were employed, including SEM, AES, transmission electron microscopy (TEM), electron energy‐loss spectroscopy (EELS) and glow discharge optical emission spectrometry (GDOES), to study the effects on the surface of this alloy after each treatment compared with the as‐received and alkaline‐cleaned alloy surfaces. The untreated alloy was found to have a thick oxide of 200–320 nm, consisting mainly of MgO. Alkaline cleaning results in an etching effect that thins the oxide and also deposits a thin silicate layer on the surface. In the case of the deoxidizers, there is significant removal of the native oxide of the alloy by the NaBrO3/HNO3 deoxidizer. There is also evidence of intermetallic attack on the alloy. The (NH4)4Ce(SO4)4/H2SO4 deoxidizer, which is a low‐etch‐rate deoxidizer, resulted in a slight thinning of the oxide. However, the effect was not significantly greater than with alkaline cleaning alone. The most effective deoxidizer in reducing the oxide thickness of the alloy is Fe(III)/HF/HNO3, in which the etch rate was sufficiently high to remove completely the native oxide. In this case, equilibrium between oxide removal and the formation of new oxides on the alloy surface was achieved. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
20.
Volkmar Nejedl Michael Panzner Stefan Baunack Ulrich Franz Arnold Luft Klaus Wetzig 《Mikrochimica acta》1998,130(1-2):89-95
The laser induced modification of iron surfaces with atmospheric species was investigated by means of Auger electron spectroscopy (AES) and scanning electron microscopy (SEM). Different laser systems were used for irradiating iron samples in a wide range of the laser processing parameters up to small foci and ultra short pulses.A nitriding of iron connected with an oxidation of the near surface region was observed in the wavelength range between 193 nm and 10.6 m using large foci (0.1 cm2) and short pulses (10...1400ns). In case of small foci (7·10–6cm2) with ns-pulses (50 ns) an enrichment of the iron melt with nitrogen and an advanced oxidation of the surrounding area of the laser spot were detected. When using shorter pulses (200 fs, 40 ps) no indications for a nitriding were found. 相似文献