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31.
以MCM-41为硅源,在800~1 100℃下合成了Ba1.2Ca0.64SiO4:0.10Eu,0.06Mn荧光粉,研究了煅烧温度对荧光粉发光性能的影响。实验结果表明,Eu2+的蓝绿光发射带的强度与宽度随煅烧温度的升高先增大后减小,在1 000℃时强度达到最大。最大发射峰位随温度的升高而发生红移,由800℃和900℃时的450 nm移至1 000℃和1 100℃时的480 nm。Mn2+的红光发射起源于Eu2+发射光的激发,其强度随温度的升高而增大。与Mn2+发生能量传递作用的Eu2+主要位于10配位的M(1)格位。 相似文献
32.
Xian Tao Ke‐Cheng Shen Qing‐Yun Tang Meng Feng Jiang‐Tao Fang Yu‐Long Wang Ying‐Zhong Shen 《应用有机金属化学》2012,26(7):323-329
New N‐silver(I) acetylbenzamide complexes of type Ln?AgNC9H8O2 (L = PPh3; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt)3; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were obtained in high yields and characterized by elemental analysis, 1H NMR, 13C{H} NMR, 31P{H} NMR and IR spectroscopy, respectively. The molecular structure of 2b has been determined by X‐ray single‐crystal analysis in which the silver atom is in a distorted tetrahedral geometry and crystallizes as cis–trans. New N‐silver(I) acetylbenzamide complexes have a four‐membered ring, which could influence their chemical and physical properties and modulate volatility. Metal organic chemical vapor deposition experiments were carried out successfully at 400°C and 450°C using 2e as precursor for the deposition of silver films, respectively. The high‐purity silver film obtained at 400°C is dense and homogeneous. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
33.
Synthesis and thermal properties of a new styryl-functionalized pentafulvene glassy carbon precursor
The first preparation of a styryl-functionalized aryl pentafulvene 4 was carried out. In the crystal structure of 4, the packing of fulvene molecules results in the shortest intermolecular contacts between aligned vinyl groups. Thermal reactivity studies of 4 (DSC and TGA, under N2) revealed a small difference between the melting point (120 °C) and the Tonset for cross-linking (125 °C), and provided strong evidence for the production of a network material (net4) due to reactivity of the attached styryl group. Pyrolysis of net4 under N2 gave a glassy carbon product in low yield as revealed by powder X-ray and TGA analyses (carbon yield (TGA) of 38% (900 °C)). 相似文献
34.
Turnpike properties have been established long time ago in finite-dimensional optimal control problems arising in econometry. They refer to the fact that, under quite general assumptions, the optimal solutions of a given optimal control problem settled in large time consist approximately of three pieces, the first and the last of which being transient short-time arcs, and the middle piece being a long-time arc staying exponentially close to the optimal steady-state solution of an associated static optimal control problem. We provide in this paper a general version of a turnpike theorem, valuable for nonlinear dynamics without any specific assumption, and for very general terminal conditions. Not only the optimal trajectory is shown to remain exponentially close to a steady-state, but also the corresponding adjoint vector of the Pontryagin maximum principle. The exponential closedness is quantified with the use of appropriate normal forms of Riccati equations. We show then how the property on the adjoint vector can be adequately used in order to initialize successfully a numerical direct method, or a shooting method. In particular, we provide an appropriate variant of the usual shooting method in which we initialize the adjoint vector, not at the initial time, but at the middle of the trajectory. 相似文献
35.
《Current Applied Physics》2015,15(2):59-63
We have synthesized an efficient Cu2ZnSn(SxSe1−x)4 (CZTSSe) absorbers by using single-step rapid thermal sulfo-selenization process of sputtered stack metallic precursor (Zn/Sn/Cu) films. The structural and morphological studies confirm that the suitability of the rapid thermal sulfo-selenization process for the synthesis of a CZTSSe absorber without any secondary phases with large grains. The annealing atmosphere with a mixed-chalcogen source enhances the grain growth of the CZTSSe absorber as compared with pure Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) absorbers. The CZTSSe thin film solar cell shows the best conversion efficiency of ∼7%. 相似文献
36.
A. Marcilla A. Gómez-Siurana S. Menargues 《Journal of Thermal Analysis and Calorimetry》2007,87(2):519-527
A study of the catalytic degradation of EVA
copolymers under air atmosphere has been carried out using thermogravimety
(TG). Three commercial EVA copolymers and five zeolites and related materials
catalysts have been selected. The degradation process in air atmosphere involves
four main decomposition steps (as observed in TG), being more complex than
the corresponding process in inert atmosphere. The presence of MCM-41, HY
and H-β does not seem to noticeably affect to the overall degradation
temperature, despite the temperature of maximum reaction rate for the second
decomposition step being slightly displaced towards lower temperatures. Contrarily,
the presence of HZSM-5 and HUSY zeolites seems to displace the main stage
of the oxidative degradation process towards higher temperatures. Moreover,
the relative importance of the second and third decomposition step is different
depending on the amount and the nature of the zeolite mixed with the EVA sample.
The results obtained show that the presence of the catalyst also enhances
the formation of the carbonous residue. 相似文献
37.
在100,250和1 000 mL高压釜静态成功合成MCM-22分子筛的基础上,在2,5和200 L高压釜中进行了MCM-22分子筛的动态合成试验,对合成的样品用XRD等技术进行了表征。结果表明,在静态和动态条件下合成的样品,全部为纯相MCM-22分子筛,且结晶度较高,从100 mL到200 L的放大试验是成功的。 相似文献
38.
Polarization spectroscopy in the mid-infrared (IRPS) has been applied to the detection of acetylene molecules making use of the asymmetric C-H stretching vibration at around 3 μm. The infrared laser pulses were produced through difference frequency generation in a LiNbO3 crystal pumped by a Nd:YAG and dye laser system. By directly probing the ro-vibrational transitions with IRPS, sensitive detection of molecules with otherwise inaccessible electronic states was realized with high temporal and spatial resolution by using a pulsed laser and a cross-beam geometry. Detection sensitivities of 2 × 1013 molecules/cm3 (10 ppm in 70 mbar gas mixture) of C2H2 were achieved using the P(1 1) line of the (0 1 0(1 1)0)-(0 0 0 00 00) band. The dependence of the IRPS signal on the pump laser fluence, acetylene mole fraction, and buffer gas pressure of Ar, N2, H2, and CO2 has been studied experimentally. The investigation demonstrates the quantitative nature of IRPS for sensitive detection of polyatomic IR active molecules. In order to fully demonstrate the technique for combustion applications, nascent acetylene molecules were measured in a low pressure methane/oxygen flame. 相似文献
39.
40.
Feng JiangHonglie Shen Chao GaoBing Liu Long LinZhou Shen 《Applied Surface Science》2011,257(11):4901-4905
SnS films have been prepared by a novel two-stage process. It involved sputtering of Sn film on glass substrate and sulfurization of the thin metallic tin precursor layers in a vacuum furnace. The X-ray diffraction results showed that the SnS layers had orthorhombic structure and (0 4 0) preferential growth is more and more obvious with the increase of sulfurization time. The SnS film obtained by this work shows high optical absorption efficiency, and the film has a direct optical band gap of about 1.3 eV. The films show p-type conductivity and the resistivity of SnS film decreased obviously under illumination. 相似文献