全文获取类型
收费全文 | 17096篇 |
免费 | 1532篇 |
国内免费 | 1172篇 |
专业分类
化学 | 10375篇 |
晶体学 | 594篇 |
力学 | 619篇 |
综合类 | 46篇 |
数学 | 343篇 |
物理学 | 7823篇 |
出版年
2024年 | 26篇 |
2023年 | 189篇 |
2022年 | 344篇 |
2021年 | 391篇 |
2020年 | 470篇 |
2019年 | 370篇 |
2018年 | 328篇 |
2017年 | 376篇 |
2016年 | 645篇 |
2015年 | 466篇 |
2014年 | 600篇 |
2013年 | 1261篇 |
2012年 | 981篇 |
2011年 | 1031篇 |
2010年 | 872篇 |
2009年 | 1099篇 |
2008年 | 1078篇 |
2007年 | 1347篇 |
2006年 | 1262篇 |
2005年 | 889篇 |
2004年 | 881篇 |
2003年 | 719篇 |
2002年 | 545篇 |
2001年 | 443篇 |
2000年 | 413篇 |
1999年 | 359篇 |
1998年 | 374篇 |
1997年 | 275篇 |
1996年 | 335篇 |
1995年 | 281篇 |
1994年 | 240篇 |
1993年 | 184篇 |
1992年 | 152篇 |
1991年 | 103篇 |
1990年 | 99篇 |
1989年 | 62篇 |
1988年 | 56篇 |
1987年 | 33篇 |
1986年 | 40篇 |
1985年 | 50篇 |
1984年 | 40篇 |
1983年 | 11篇 |
1982年 | 16篇 |
1981年 | 24篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1974年 | 3篇 |
1973年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Makoto Sakata Takafumi Itsubo Yutakata Moritomo Yasuo Ohishi 《Journal of Physics and Chemistry of Solids》2004,65(12):1973-1976
The experimental and analytical method of the high-pressure powder experiment at BL10XU, SPring-8, is described. There is no doubt that BL10XU must be one of the most appropriate beam lines for high pressure X-ray diffraction experiment taking advantage of third generation synchrotron source. As an example of the advanced charge density study under high pressure, the structural change of Cs2Au2Br6 by applying pressure is studied by Rietveld/MEM analysis. It reveals that the structural change of Cs2Au2Br6 by applying pressure occurs basically at electron level, such as valence state change and chemical bonding, which may be called the electronic phase transition. 相似文献
42.
43.
44.
P. C. Chen 《中国化学会会志》1995,42(5):755-760
Three ab initio calculations (HF/6-3IG, HF/6-3IG*, and HF/6-3IG**) on 2,4,6-trinitrotoluene were made, The results compare well with xray data, except dihedral angles of NO2 relative to the plane of the benzene ring. The deviations are attributed to packing forces and steric effects in the crystal. The most stable structure was a torsional angle 10° of the methyl top with the benzene ring, unlike toluene. The rotational barriers of the methyl top and the 4-nitro group are small. Hydrogen bonding, dipole moments and total atomic charges arc calculated. 相似文献
45.
对水热处理后得到的USY沸石作进一步的酸处理以及采用改进的氟硅酸盐溶液骨架富硅工艺,分别得到了经XPS剖面分析证实为铝分布均匀的超稳Y沸石HAY-Ⅰ和HAY-Ⅱ。IR分析表明,在酸处理过程中从USY沸石中去掉的那部分非骨架铝类与3690cm~(-1)处羟基有关,仍残留在HAY-Ⅰ沸石中的那部分非骨架铝类与3670cm~(-1)和3600cm~(-1)处羟基有关。XRD和化学分析表明HAY-Ⅰ沸石仍含有约50%的非骨架铝类,而HAY-Ⅱ沸石则基本上不含非骨架铝类,HAY-Ⅱ沸石还显示更高的结晶保留度。DTA分析表明,HAY-Ⅰ和HAY-Ⅱ两种沸石的热稳定性均高于USY沸石。 相似文献
46.
47.
In this paper we report the results of a morphological and structural investigation on film properties of a soluble polydiacetylene, the poly[1,6-bis(3,6-dihexadecyl-N-carbazolyl)-2,4-hexadiyne] (polyDCHD-HS). The red films of this polymer, prepared by standard spin-coating techniques, revealed absence of linear dichroism and birefringence in contrast with the ordered mesophases detected by powder X-ray studies. In order to interpret the optical behavior of this polymer, we performed AFM and SEM studies of polyDCHD-HS films spun on hydrophylic and hydrophobic glass substrates. We found the presence of surfaces organized in rod-like particles, more regularly oriented on the hydrophylic substrate. GIXRD studies, carried out on films sufficiently thick to allow the observation of the diffraction pattern, reveled the presence of a lamellar structure with a spacing of 3.22 nm. The low intensity of the diffraction peaks and the isotropic linear optical properties of the films show that the lamellar mesophases are not extended over large areas. These findings were compared with the data obtained from AFM and SEM studies on films of two other polydiacetylenes, the poly[1-(3,6-dihexadexyl-N-carbazolyl)-6-(N-carbazolyl)-2,4-hexadyine] (polya-DCHD) and the poly[1,6-bis(3,6-dipalmitoyl-N-carbazolyl)-2,4-hexadyine] (polyDPCHD), spun on hydrophylic glass substrate. The results confirmed the presence of nodular morphologies which seem to be a general characteristic of this class of materials. The particles organization appears instead related to the chemical nature of the substituents on the carbazolyl rings. 相似文献
48.
激光标线的原理和实验 总被引:1,自引:1,他引:0
根据几何光学知识分析了激光标线原理.理论和实验表明:激光标线长度与激光光束形状、光学元件形状及材料折射率有关.并讨论了激光标线向两侧扩展的原因. 相似文献
49.
X-ray reflectivity (XRR), X-ray fluorescence (XRF) and small angle X-ray scattering (SAXS) techniques are used to the monitoring of Cu/porous low κ processes, which are developed for the next generation (≤65 nm) integrated circuits. Sensitivity of XRR and XRF is sufficient to detect drifts of the copper barrier layer, copper seed layer and Cu CMP (chemical-mechanical polishing) processes. Their metrology key parameters comply with production requirements. SAXS allows determining the pore structure of low κ films: average pore size and pore size distribution. 相似文献
50.
The mechanism of X-ray waveguide-resonance propagation or the radiation superstream model, which can become the ground of X-ray nanophotonics, is discussed briefly. Some attention is devoted to features consideration of the simplest devices characterized by the waveguide-resonance transportation of X-ray beams. The experimental data showing the user possibilities of a simplest waveguide-resonators application for diffractometry are presented. We discuss the main reasons to improve the metrological characteristics for total reflection X-ray fluorescence (TXRF) analytical method in case when the target exciting beam is formed by a waveguide-resonator. Some problems appearing during the waveguide-resonator application are formulated. 相似文献