全文获取类型
收费全文 | 11610篇 |
免费 | 1587篇 |
国内免费 | 2872篇 |
专业分类
化学 | 11556篇 |
晶体学 | 148篇 |
力学 | 142篇 |
综合类 | 107篇 |
数学 | 41篇 |
物理学 | 4075篇 |
出版年
2024年 | 42篇 |
2023年 | 248篇 |
2022年 | 411篇 |
2021年 | 480篇 |
2020年 | 518篇 |
2019年 | 467篇 |
2018年 | 407篇 |
2017年 | 465篇 |
2016年 | 560篇 |
2015年 | 517篇 |
2014年 | 665篇 |
2013年 | 1146篇 |
2012年 | 833篇 |
2011年 | 736篇 |
2010年 | 565篇 |
2009年 | 717篇 |
2008年 | 677篇 |
2007年 | 752篇 |
2006年 | 745篇 |
2005年 | 632篇 |
2004年 | 641篇 |
2003年 | 525篇 |
2002年 | 495篇 |
2001年 | 365篇 |
2000年 | 350篇 |
1999年 | 303篇 |
1998年 | 258篇 |
1997年 | 227篇 |
1996年 | 186篇 |
1995年 | 182篇 |
1994年 | 138篇 |
1993年 | 140篇 |
1992年 | 125篇 |
1991年 | 86篇 |
1990年 | 61篇 |
1989年 | 60篇 |
1988年 | 75篇 |
1987年 | 39篇 |
1986年 | 30篇 |
1985年 | 24篇 |
1984年 | 20篇 |
1983年 | 16篇 |
1982年 | 22篇 |
1981年 | 12篇 |
1980年 | 17篇 |
1979年 | 18篇 |
1978年 | 17篇 |
1977年 | 14篇 |
1976年 | 18篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
41.
Gel polymer electrolyte (GPE) films comprising of poly(vinylidenefluoride), propylene carbonate, ethylene carbonate and zinc trifluoromethane sulfonate are prepared and characterized. The composition of GPE is optimized to contain minimum liquid components with a maximum specific conductivity of 3.94×10−3 S cm−1 at (25±1) °C. A detailed investigation on the properties such as ionic conductivity, transport number, electrochemical stability window, reversibility of Zn/Zn2+ couple and Zn/gel electrolyte interfacial stability have been carried out. The ionic conductivity follows a VTF behaviour with an activation energy of about 0.0014 eV. Cationic transport number varies from 0.51 at 25 °C to 0.18 at 70 °C. Several cells have been assembled with GPE as the electrolyte, zinc as the anode, γ-MnO2 as the cathode and their charge–discharge behaviour followed. Capacity values of 105, 82, 64 and 37 mAh/g of MnO2 have been achieved at 10, 50, 100 and 200 μA/cm2 discharge current densities, respectively. The discharge capacity values are almost constant for about 55 cycles for all values of current densities. Cyclic voltammetric study of MnO2 electrode in Zn/GPE/MnO2 cell clearly shows intercalation/deintercalation of Zn2+. 相似文献
42.
43.
D. Behera T. Mohanty S. K. Dash T. Banerjee D. Kanjilal N. C. Mishra 《Radiation measurements》2003,36(1-6):125-129
Swift heavy ions (SHI) with electronic energy loss exceeding a value of 14.4 keVnm−1 create amorphized latent tracks in YBCO type superconductors. In the low fluence regime of an ion beam where tracks do not overlap, a decrease of the superconducting transition temperature as probed through resistivity studies, is not expected due to availability of percolating current paths. The present study however shows Tc decrease by about 1–3 K in thin films of YBCO when irradiated by 250 MeVAg ions at 79 K at a fluence of 5×1010–1×1012 ionscm−2. The highest fluence used in the present study is three times less than the fluence where track overlapping becomes significant. The Tc tends to increase towards the preirradiation value on annealing the films at room temperature. To explain this unusual result, we consider the effect of ion irradiation in inducing materials modification not only through creation of amorphized latent tracks along the ion path, but also through creation of atomic disorder in the oxygen sublattice in the Cu–O chains of YBCO by the secondary electrons. These electrons are emitted radially from the tracks during the passage of the SHI. Considering the correlation between the charge state of copper and its oxygen coordination, we show in particular that the latter process is a consequence of the inelastic interaction of the SHI induced low-energy secondary electrons with the YBCO lattice, which result in chain oxygen disorder and Tc decrease. 相似文献
44.
采用显微Raman光谱方法对红外目标模拟器中重掺杂Si微电阻桥单元的热传导特性进行研究,根据Si桥的实际特性建立相应的Raman散射模型,通过测量Raman峰位的移动得到高功率激光辐照下测量点的温度.对Si桥桥面分别进行了沿某些特殊线段的逐点线扫描和覆盖全部桥面的面扫描,得到各点的温升及其分布.用基于有限元分析的软件结合Si桥结构参数对各测量点的温升进行了模拟计算,其结果在热导分布的基本趋势上与实验相一致.实验细致地揭示了热导分布的局域起伏,反映出实际器件的不均匀性,为改进器件设计、优化器件性能提供了实验依据.
关键词:
Raman光谱
Si桥
温度分布
热导 相似文献
45.
A new method based on anion exchange resin separation and graphite furnace atomic absorption spectrometry (GFAAS) detection
is proposed for the determination of inorganic tin species. The result showed that Sn(IV) was quantitatively retained on the
resin when [HCl] = 9.0 mol · L−1, but Sn(II) could not be adsorbed on the resin under the same condition. Thus, a separation of Sn(II) and Sn(IV) has been
realized. When the concentration of NaOH solution was between 2.0–7.0 mol · L−1, Sn(IV) that adsorbed on the resin could be eluated from the resin completely. Meanwhile, under the atmosphere and the nitrogen
states, the translation between Sn(II) and Sn(IV) was investigated. Under the optimal conditions, the detection limit of Sn(IV)
is 0.40 μg · L−1 with RSD of 2.3% (n = 5, c = 2.0 μg · L−1). The proposed method was applied to the speciation analysis of tin in different water samples and the recovery of total
Sn was in the range of 98.7–101.7%. In order to verify the accuracy of the method, a certified reference water sample was
analyzed and the results obtained were in good agreement with the certified value. 相似文献
46.
V. A. Petrosyan 《Russian Chemical Bulletin》1995,44(8):1353-1364
The results of studies on electrosynthesis involving carb- and heteroanions generated by cathodic deprotonation of acids (CDA), carried out in the laboratory headed by the author, are surveyed. These studies resulted in the elaboration of efficient electrochemical versions of the known Michaelis-Becker, Wittig-Horner, and Perkin reactions; electrochemical analogs of homolytic aromatic substitution, alkylation, heterocyclization,etc. were developed. Based on CDA, convenient and promising methods for preparing variousN-, O-, P-, S-, andC-alkylated and arylated substances have been developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1411–1422, August, 1995.The author is grateful to Professor V. A. Dorokhov, Professor V. P. Litvinov, and researchers from the laboratories of N. D. Zelinsky Institute of Organic Chemistry headed by them, who participated in joint studies.The work was carried out with financial support from the International Science Foundation (Grant No. MHYOO). 相似文献
47.
48.
H. Hora 《Czechoslovak Journal of Physics》2003,53(3):199-217
The anomaly of ion emission at laser irradiation of targets measured by Badziak et al. was analyzed on the background of the extensive research in the past. In contrast to the irradiation with lasers of longer than 100 ps pulse duration, a drastic decrease of the maximum ion energies was measured with ps pulses. Very strange was the observation that the number of emitted fast ions was intensity independent. The usual ponderomotive or relativistic self-focusing theory and related processes could not explain the results. Instead a direct interaction within the skin depth of the irradiated target was concluded. This model confirms the plane geometry nonlinear force interaction in the ps range producing fast plasma blocks moving perpendicular off or into the target. The block moving into the target opens a new scheme of laser fusion by modifying the experiments of Norreys et al. The use of relatively low subrelativistic laser intensities for the new scheme of laser fusion is evaluated on the background of the long years studies of nonlinear force driven plasma blocks and earlier interpenetration fusion reactions for providing the parameters for expected fusion gains much higher than the experiment of Norreys et al. for a fusion power scheme. 相似文献
49.
J.L. Shui 《Applied Surface Science》2006,253(5):2379-2385
Spongy-like reticular structure is a unique morphology fabricated by electrostatic spray deposition (ESD) technique. The effects of solvent, substrate temperature, precursor feeding rate, static electric field strength, and deposition time on tailoring the reticular structure were investigated. Scanning electron microscopy was used to observe the film morphology. MnOx or LiMn2O4 were selected as the model materials. It is found that in addition to the conventional solvent butyl carbitol, other kinds of solvents such as ethylene glycol and propylene glycol can also be used to obtain reticular films at a suitable substrate temperature. Porous films with a low cross-linking degree pore structure can be prepared by increasing precursor feeding rate or decreasing substrate temperature. Increasing the deposition time or the electric field strength helps to obtain reticular films with more homogeneous pore size distribution. In addition, the addition of a high boiling-point solvent in mixed alcohol solvent results in the increase of proper substrate temperature. It is concluded that the fluidity of the spray droplets on the surface of a hot substrate is an important factor to form a reticular film. 相似文献
50.
为了探索低温可调控ZnO薄膜沉积技术,提出了一种新的ZnO薄膜制备方法,即离化团簇束(ICB)法,并自行设计研制了应用该方法制备ZnO薄膜的专门装置.采用超音速喷嘴获得高速锌原子团簇束,用Hall等离子体源产生氧离子束离化锌原子团簇,获得了较高的离化率.在沉积过程中,可以通过调节衬底偏压、氩氧比、衬底加热温度等参数,来控制成膜的质量;应用这个装置成功地在硅衬底上制备的ZnO薄膜,经XRD和EDS检测,薄膜的c轴取向一致,Zn、O原子百分比接近于1:1,成膜质量好. 相似文献