4－（2－氨基噻唑）－间苯二酚为柱前衍化剂液相色谱／电化学检测Fe、Co、Ni

４－（２－氨基噻唑）－间苯二酚为柱前衍化剂液相色谱／电化学检测Ｆｅ、Ｃｏ、Ｎｉ格日勒，李惠梅，李南强，汪尔康（中国科学院长春应用化学研究所电分析化学开放实验室，北京大学化学系，长春，１３００２２）关键词液相色谱，Ｆｅ，Ｃｏ，Ｎｉ，４－（２－氨基噻唑）...     

溴原子取代对二茂铁液晶化合物介晶性的影响

二茂铁液晶因其独特的稳定性和易于衍生化受到研究人员的青睐[1- 8] 。我们曾经报道过一类单取代二茂铁液晶的合成与介晶性[9] 。这里我们报道另外一类二茂铁单取代液晶 ,并对分子的长度、溴原子取代对介晶性的影响进行探讨。合成路线如下 :1　实验部分ＢｒｕｃｋｅｒＡＣＥ -2 0 0ｓｐｅｃｔｒｏｍｅｔｅｒ,ＣＤＣｌ3作溶剂。ＮｉｃｏｌｅｔＭａｇｎａ-ＩＲ 5 0 0Ｓｐｅｃｔｒｏｍｅｔｅｒ,ＳｅｒｉｅｓⅡ ,ＫＢｒ压片。ＷＲＳ -ＩＡ ,ＣａｒｌｏＥｒｂａ 1 1 0ｂ。Ｐｅｒｋｉｎ -Ｅｌｍｅｒ 7Ｓｅｒｉｅｓ热分析仪 ,分温速度 1 0℃ /ｍｉ…     

The crystallization characteristics of polypropylene and low ethylene content polypropylene copolymer with copolyesters

The crystallization characteristics of polypropylene (PP) and low ethylene content PP copolymers with and without nucleating agents were studied by differential scanning calorimetry (DSC). PP and PP copolymers was blended with three different kinds of co[poly(butylene terephthalate-p-oxybenzoate)] copolyesters, designated B28, B46, and B64, with the copolyester level varying from 5 to 15 wt.%. All samples were prepared by solution blending in hot xylene solvent at 50 °C. The crystallization behavior of samples was then studied by DSC. The results indicate that these three copolyesters accelerate the crystallization rate of PP and PP copolymers in a manner similar to that of a nucleating agent. The acceleration of crystallization rate was most pronounced in these blend systems with a maximum level at 5 wt.% of B28. The observed changes in crystallization behavior are explained by the effect of the composition and the amount of copolyester in the blends.     

TS分子筛催化性能研究Ⅰ．TS－2分子筛催化1，2－丙二醇液相氧化反应的研究

ＴＳ分子筛催化性能研究Ⅰ．ＴＳ－２分子筛催化１，２－丙二醇液相氧化反应的研究①伏再辉尹笃林（湖南师范大学精细催化合成研究所，长沙４１００８１）关键词ＴＳ－２分子筛１，２－丙二醇氧化催化氧化自１９８３年Ｔａｒａｍａｓｓｏ［１］首次合成具有ＺＳＭ－５结构...     

离聚体的结构表征——Ⅴ.含氟离聚体中离子微区稳定性的研究

本文用DSC方法研究了羟酸型含氟离聚体中不同金属离子种类、可离子化基团含量、配位结构单元构型及离子微区大小对离聚体中离子微区稳定性的影响。实验表明:离聚体中金属离子配位能力愈强,羟酸含量愈高,离子微区尺寸愈大,则相应离聚体中离子微区稳定性愈大。铅高聚体>锌离聚体>钙离聚体>钠离聚体。     

Synthesis and Inclusion Properties of the Host Compound 1,3-Dihydro-1,1,3,3-tetraphenylisobenzofuran. X-Ray Crystal Structures of the Free Host and of an Inclusion Compound with 1,4-Dioxane

A novel host molecule, 1, suitable for crystalline lattice-type inclusion, has been synthesized, and its cocrystal formation ability has been investigated. Host 1 proved to be of potential use for organic solvent separation and retrieval, and a promising auxiliary for solidification of certain odorous substances. The crystal structures of the solvent-free host 1, and its complex with 1,4-dioxane (1 : 1), have been determined by single crystal X-ray diffraction. The structure of 1 (guest-free) is triclinic, P , with a = 9.452(2), b = 10.359(3), c = 13.116(3) Å, = 101.80(2), = 106.53(1) and = 104.32(1)°. The spacious, propeller-like molecules are held together by weak van der Waals' forces. The dioxane inclusion compound is monoclinic, P21/a, with a = 15.050(1), b = 8.641(1) and c = 20.658(1) Å, and = 94.56(1)°, and contains two crystallographically independent guest molecules, both located around symmetry centres. The molecular packing seems to be governed by C—H···O type bonds (C···O = 3.31 and 3.48 Å) from the host to the dioxane oxygens.     

薄层液/液界面电子转移动力学的研究进展

薄层循环伏安法是研究液/液界面电荷转移的一种新方法,具有简单、快速、易操作的优点。文章回顾了液/液界面电化学的发展历史,介绍了薄层法的实验原理,对其在电化学中的应用和研究进展进行了评述,总结了界面驱动力与电子转移速率的关系。     

Synthesis and characterization of liquid‐crystalline polyphosphonates containing disubstituted ferrocene esters as mesogens

A series of ferrocene‐containing liquid‐crystalline polyphosphonates with an even number of methylene groups are reported. All the polymers gave birefringent melts. The mesophase was identified as transparent with an increase in the spacer. The effects of pendant substitution and the spacer were studied with thermogravimetric analysis and differential scanning calorimetry. The effects of the phosphonate group in the spacer and the ferrocene ester group in the mesogen were examined. The presence of a steplike mesogenic structure and a pendant phenyl group in the spacer led to reductions in the glass‐transition and melting temperatures. The ferrocene moiety in the mesogen might be one of the reasons for the increased thermal stability and decreased liquid crystallinity. An energy‐minimized structure for the mesogenic and spacer segments was created with computer‐modeling programs, and it suggested the reason for the reductions in the glass‐transition and melting temperatures. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2256–2263, 2002     

PET-HBT嵌段热致性液晶共聚酯的合成

液晶高分子材料具有相当高的强度和模量，被誉为当代超级工程塑料．以对羟基苯甲酸甲酯、1，4-丁二醇为主要原料，经熔融酯交换合成双-对羟基苯甲酸丁二醇酯(BBHB)；以四氯乙烷为溶剂，采用溶液缩聚法将过量的BBHB与对苯二甲酰氯(TPC)合成端基为BBHB的齐聚物(PHBT)；以对苯二甲酸二甲酯与乙二醇为原料，经熔融酯交换合成对苯二甲酸双β-羟乙酯(BHET)，然后采用溶液缩聚法将BHET与少量的TPC合成端基为TPC的齐聚物(PTET)；最后以PHBT与PTET为原料，以四氯乙烷为溶剂，采用溶液缩聚法合成目标共聚酯(PET-HBT)。研究了共聚酯的双折射现象及热行为；用偏光显微镜观察了试共聚酯的织态结构并用FTIR表征了共聚酯的微观结构．