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991.
《Particuology》2016
The nanosize grain growth characteristics of spherical single-crystal titanium oxide (TiO2) during the rapid gaseous detonation reaction are discussed. Based on the experimental conditions and the Chapman–Jouguet theory, the Kruis model was introduced to simulate the growth characteristics of spherical TiO2 nanoparticles obtained under high pressure, high temperature and by rapid reaction. The results show that the numerical analysis can satisfactorily predict the growth characteristics of spherical TiO2 nanoparticles with diameters of 15–300 nm at different affecting factors, such as concentration of particles, reaction temperature and time, which are in agreement with the obtained experimental results. We found that the increase of the gas-phase reaction temperature, time, and particle concentration affects the growth tendency of spherical nanocrystal TiO2, which provides effective theoretical support for the controllable synthesis of multi-scale nanoparticles. 相似文献
992.
A novel refractometer based on tapered Mach–Zehnder modal interferometer (MZI) is proposed and experimentally demonstrated. This sensor is composed of a pair of Peanut-Shape structures and an embedded taper – the former excites high-order cladding modes, while the latter enhances the evanescent field. As the effective refractive index (RI) of cladding is based on the changes of surrounding RI, thus extinction ratio will change due to the alteration of the distribution of power in the fiber which is induced by various differences of core and cladding for RI. As a result, the maximum RI sensitivity of 240.78 extinction ratio/RIU (refractive index unit) is achieved within the range from 1.3334 to 1.4081. 相似文献
993.
QI GuoPeng JIANG Feng SUN XueWen & ZHAO SuoQi School of Chemical Engineering Tianjin University Tianjin China State key Laboratory of Heavy Oil Processing Petroleum University of China Beijing China 《中国科学:化学》2010,(5)
The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted π electrons of 1-dodecene to shift toward 1-carbon,thus forming a carbonium ion.The carbonium ion further reacted with benzenes to form a complex.Due to unstabilit of the complex,a deuterated ring proton was transferred into an electronegative 1-carbon of the side chain to substitute for the A... 相似文献
994.
995.
Sergio García-Fonseca Ana Ballesteros-GómezSoledad Rubio Dolores Pérez-Bendito 《Journal of chromatography. A》2010,1217(16):2376-2382
A supramolecular solvent made up of reverse micelles of decanoic acid, dispersed in a continuous phase of THF:water, was proposed for the simple, fast and efficient microextraction of OTA in wheat prior to liquid chromatography-fluorescence determination. The method involved the stirring of 300 mg-wheat subsamples (particle size 50 μm) and 350 μL of supramolecular solvent for 15 min, subsequent centrifugation for 15 min and the direct quantitation of OTA in the extract, previous 5.7-fold dilution with ethanol/water/acetic acid (49.5/49.5/1), against solvent-based calibration curves. No clean-up of the extracts or solvent evaporation was needed. Interactions between the supramolecular solvent and major matrix components in the wheat (i.e. carbohydrates, lipids and proteins) were investigated. The reverse micelles in the extractant induced gluten flocculation but only in the coacervation region of lower analytical interest (i.e. at percentages of THF above 11%). The quantitation of OTA was interference-free. Representativity of the 300 mg-wheat subsamples was proved by analysing a reference material. OTA recoveries in wheat ranged between 84% and 95% and the precision of the method, expressed as relative standard deviation, was 2%. The quantitation limit of the method was 1.5 μg kg−1 and was below the threshold limit established for OTA in raw cereals by EU directives (5.0 μg kg−1). The method developed was validated by using a certified reference material and it was successfully applied to the determination of OTA in different wheat varieties from crops harvested in the South of Spain. OTA was not detected in any of the analysed samples. This method allows quick and simple microextraction of OTA with minimal solvent consumption, while delivering accurate and precise data. 相似文献
996.
Unlike thermal processes such as distillation, pervaporation relies on the relative rates of solute permeation through a membrane and is a combination of evaporation and gas diffusion. The analytical pervaporation systems consist of a membrane module suitable for liquid sample introduction and a vacuum (or a sweeping gas) on the permeate side. It has been used in a wide range of applications including the analysis of various organic and inorganic compounds, and sample concentration. It has been directly interfaced with gas chromatography, spectrophotometry, capillary electrophoresis, electrochemical detectors, liquid chromatography, and mass spectrometry. A wide range of liquids, slurries, and solids samples has been analyzed using these techniques. This review highlights the basic principles of the pervaporation and the state of its current development as applied to analytical chemistry. 相似文献
997.
Muhammad Akhyar Farrukh Noureen Siraj Iftikhar Imam Naqvi 《Journal of Saudi Chemical Society》2010,14(2):209-212
Iron has been determined in apple and vegetables spectrophotometrically, by complexing it with xylenol orange. 1:1 complex formed in a highly acidic medium is measured for its absorbance at its λmax of 585 nm. The results have been compared by employing atomic absorption technique. Apples and vegetable samples were collected from local markets of Pakistan. Statistical manipulations, t-test and F-test, were performed and it was found that the results from the two techniques have an excellent agreement. 相似文献
998.
Javier Mazzaferri 《Optics Communications》2010,283(10):2056-2060
Multiresolution analysis is very useful for characterization of textures, segmentation tasks, and feature enhancement. The development of optical methods to perform such procedures is highly promissory for real-time applications. Usually, the optical implementations of multiresolution analysis consist in the decomposition of the input scene in different frequency bands, obtaining various filtered versions of the scene. However, under certain circumstances it could be useful to provide just one version of the scene where the different filters are applied in different regions. This procedure could be specially interesting for biological and medical applications in situations when the approximate localization of the scale information is known a priori. In this paper we present a fully optical method to perform multiresolution analysis with spatial localization. By means of the proposed technique, the multi-scale analysis is performed at once in a unique image. The experimental set-up consist of a double-pass convergent optical processor. The first stage of the device allows the multiple band decomposition, while the second stage confines the information of each band to different regions of the object and recombines it to achieve the desired operation. Numerical simulations and experimental results, which prove the very good performance of the method, are presented. 相似文献
999.
In this paper, temperature-dependent birefringence theory of liquid crystal is used to investigate the temperature effect on the threshold voltage. An expression for describing the non-linear relationship between the threshold voltage and temperature is deduced. In addition, we theoretically discuss the temperature effect on the transmitted ratio of the namatic twisted liquid crystal without the applied voltage and with the applied voltage. It is found that the transmitted ratio is decreased linearly as temperature is increased when the liquid crystal is not applied with voltage, but the transmitted ratio is increased linearly as temperature is increased when the liquid crystal is applied with voltage. The threshold voltages and the transmitted ratio are measured at different temperatures. The experimental data are consistent with the theoretical calculated results. 相似文献
1000.
Ahmed H. Ayyad 《Applied Surface Science》2010,256(13):4081-4083
The temperature coefficient of surface excess entropy dSs/dT of pure liquid metals (Al, Ga and Bi) has been calculated in the framework of Skapski's nearest-neighbor interaction-broken-bond model. It is found that this coefficient varies by 47.2%, 69% and 85% for pure liquids Al, Bi and Ga, respectively, in the temperature range between the melting temperature Tm and Tm + 400 K. The value of the coefficient for pure liquid Ga is an order of magnitude larger than that of Al and Bi. The largest increase in dSS/dT with temperature occurs in the first 100 K away from Tm, being the largest for liquid Ga which is about 43%. This variation is experimentally inaccessible and therefore lacking in the literature and has never been reported. 相似文献