首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   129169篇
  免费   7244篇
  国内免费   13569篇
化学   90319篇
晶体学   1352篇
力学   6242篇
综合类   1345篇
数学   23378篇
物理学   27346篇
  2024年   139篇
  2023年   1000篇
  2022年   2428篇
  2021年   2778篇
  2020年   3132篇
  2019年   3076篇
  2018年   2668篇
  2017年   3730篇
  2016年   4215篇
  2015年   3402篇
  2014年   4800篇
  2013年   9434篇
  2012年   8375篇
  2011年   6930篇
  2010年   5943篇
  2009年   8041篇
  2008年   8221篇
  2007年   8653篇
  2006年   7620篇
  2005年   6517篇
  2004年   6199篇
  2003年   5121篇
  2002年   6052篇
  2001年   3743篇
  2000年   3515篇
  1999年   3265篇
  1998年   2916篇
  1997年   2394篇
  1996年   2105篇
  1995年   1991篇
  1994年   1788篇
  1993年   1470篇
  1992年   1383篇
  1991年   993篇
  1990年   878篇
  1989年   740篇
  1988年   605篇
  1987年   440篇
  1986年   416篇
  1985年   393篇
  1984年   369篇
  1983年   204篇
  1982年   340篇
  1981年   240篇
  1980年   255篇
  1979年   279篇
  1978年   214篇
  1977年   145篇
  1976年   137篇
  1973年   77篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
本文引入了一类新的含参广义集值拟变分包含组,应用隐预解算子技巧,建立了该类变分包含组与一类不动点问题的等价性,在适当的条件下,分析了含参广义集值拟变分包含组的解的灵敏性,所得结果推广改进了最新文献中的许多结果.  相似文献   
102.
Al-pillared clays supported rare earths (RE/Al-PILC) are prepared and used as supports of palladium catalysts for deep oxidation of low concentrations of benzene (130-160 ppm). The supports and catalysts are characterized by X-ray powder diffraction (XRD), FT-IR, BET, transmission electron microscopy (TEM) and temperature-programmed reduction (H2-TPR). The results show that Al-pillaring results in a strong increase in the basal spacing (d0 0 1) from about 1.2 to 1.8 nm, and an increase in the BET surface area from 63.6 (±3.2) to 238.8 (±11.9) m2/g. Activity tests of deep oxidation of low concentration benzene show catalysts supported on Al-PILC and RE/Al-PILC are obviously more active than that on raw clay. Pd/6% Ce/Al-PILC, in particular, can catalyze the complete oxidation of low concentration benzene at a temperature as low as about 290 °C.  相似文献   
103.
A series of (di)picolinic acids and their derivates are investigated as novel complexing tridentate or bidentate ligands in the iron‐mediated reverse atom transfer radical polymerization of methyl methacrylate in N,N‐dimethylformamide at 100 °C with 2,2′‐azobisisobutyrontrile as an initiator. The polymerization rates and polydispersity indices (1.32–1.8) of the resulting polymers are dependent on the structures of the ligands employed. Different iron complexes may be involved in iron‐mediated reverse atom transfer radical polymerization, depending on the type of acid used. 1H NMR spectroscopy has been used to study the structure of the resulting polymers. Chain‐extension reactions have been performed to further confirm the living nature of this catalytic system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2912–2921, 2006  相似文献   
104.
We have studied the individual adsorption of Mn and Bi, and their coadsorption on Cu(0 0 1) by low-energy electron diffraction (LEED). For Mn, we have determined the c(2 × 2) structure formed at 300 K, whose structure had been determined by several methods. We reconfirmed by a tensor LEED analysis that it is a substitutional structure and that a previously reported large corrugation (0.30 Å) between substitutional Mn and remaining surface Cu atoms coincides perfectly with the present value. In the individual adsorption of Bi, we have found a c(4 × 2) structure, which is formed by cooling below ∼250 K a surface prepared by Bi deposition of ∼0.25 ML coverage at 300 K where streaky half-order LEED spots appear. The c(4 × 2) structure has been determined by the tensor LEED analysis at 130 K and it is a substitutional structure. In the coadsorption, we found a c(6 × 4) structure, which has been determined by the tensor LEED analysis. It is very similar to the previously determined structure of the c(6 × 4) formed by coadsorption of Mg and Bi, and embedded MnBi4 clusters are arranged in the top Cu layer instead of MgBi4. Large lateral displacements of Bi atoms in the c(6 × 4)-(Mn + Bi) suggest that the Mn atoms undergo the size-enhancement caused by their large magnetic moment.  相似文献   
105.
The consequences of Ge deposition on Br-terminated Si(1 0 0) were studied with scanning tunneling microscopy at ambient temperature after annealing at 650 K. One monolayer of Br was sufficient to prevent the formation of Ge huts beyond the critical thickness of 3 ML. This is possible because Br acts as a surfactant whose presence lowered the diffusivity of Ge adatoms. Hindered mobility was manifest at low coverage through the formation of short Ge chains. Further deposition resulted in the extension and connection of the Ge chains and gave rise to the buildup of incomplete layers. The deposition of 7 ML of Ge resulted in a rough surface characterized by irregularly shaped clusters. A short 800 K anneal desorbed the Br and allowed Ge atoms to reorganize into the more energetically favorable “hut” structures produced by conventional Ge overlayer growth on Si(1 0 0).  相似文献   
106.
主成分分析在地区科技竞争力评测中的应用   总被引:16,自引:0,他引:16  
近年来对于科技竞争力的研究在国内方兴未艾,其中对于科技竞争力的评测是众多学者研究的重点和热点,也是各级决策者最为关心、最为重要的课题之一。本文根据科技竞争力概念和内涵来确定评测指标体系的构成要素,建立了评测指标体系,并利用主成分分析方法对采集来的数据进行分析,得到最终的评测结果。  相似文献   
107.
超尺寸物品装箱问题及其算法   总被引:3,自引:0,他引:3  
本文探讨一类新装箱问题-超尺寸物品装箱问题。针对实际解决该问题的两涉法,我们提出了一个评价效率更高的目标函数,证明了在此目标函数下两步法的渐近最坏比不小于2,并给出了渐近量坏比与拆分次数的关系。最后本文提出了一种不同于两步法的新在线算法MA,证明了在新目标函数下其渐近最坏比不超过7/4。  相似文献   
108.
蕴涵代数与BCK代数   总被引:6,自引:0,他引:6  
系统研究 Fuzzy蕴涵代数与 BCK代数之间的关系 ,给出 MV代数与 BCK代数之间的联系 ,建立正则 FI代数和对合 BCK代数的对偶代数  相似文献   
109.
Let T and S be invertible measure preserving transformations of a probability measure space (X, ℬ, μ). We prove that if the group generated by T and S is nilpotent, then exists in L 2-norm for any u, vL (X, ℬ, μ). We also show that for A∈ℬ with μ(A)>0 one has . By the way of contrast, we bring examples showing that if measure preserving transformations T, S generate a solvable group, then (i) the above limits do not have to exist; (ii) the double recurrence property fails, that is, for some A∈ℬ, μ(A)>0, one may have μ(AT -n AS - n A)=0 for all n∈ℕ. Finally, we show that when T and S generate a nilpotent group of class ≤c, in L 2(X) for all u, vL (X) if and only if T×S is ergodic on X×X and the group generated by T -1 S, T -2 S 2,..., T -c S c acts ergodically on X. Oblatum 19-V-2000 & 5-VII-2001?Published online: 12 October 2001  相似文献   
110.
This note shows that a certain toric quotient of the quintic Calabi-Yau threefold in provides a counterexample to a recent conjecture of Cox and Katz concerning nef cones of toric hypersurfaces. Received: 8 February 2001; in final form: 17 September 2001 / Published online: 1 February 2002  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号