Foam drainage is considered in a froth flotation cell. Air flow through the foam is described by a simple two-dimensional
deceleration flow, modelling the foam spilling over a weir. Foam microstructure is given in terms of the number of channels
(Plateau borders) per unit area, which scales as the inverse square of bubble size. The Plateau border number density decreases
with height in the foam, and also decreases horizontally as the weir is approached. Foam drainage equations, applicable in
the dry foam limit, are described. These can be used to determine the average cross-sectional area of a Plateau border, denoted
A, as a function of position in the foam. Quasi-one-dimensional solutions are available in which A only varies vertically, in spite of the two-dimensional nature of the air flow and Plateau border number density fields.
For such situations the liquid drainage relative to the air flow is purely vertical. The parametric behaviour of the system
is investigated with respect to a number of dimensionless parameters: K (the strength of capillary suction relative to gravity), α (the deceleration of the air flow), and n and h (respectively, the horizontal and vertical variations of the Plateau border number density). The parameter K is small, implying the existence of boundary layer solutions: capillary suction is negligible except in thin layers near
the bottom boundary. The boundary layer thickness (when converted back to dimensional variables) is independent of the height
of the foam. The deceleration parameter α affects the Plateau border area on the top boundary: weaker decelerations give larger
Plateau border areas at the surface. For weak decelerations, there is rapid convergence of the boundary layer solutions at
the bottom onto ones with negligible capillary suction higher up. For strong decelerations, two branches of solutions for
A are possible in the K = 0 limit: one is smooth, and the other has a distinct kink. The full system, with small but non-zero capillary suction,
lies relatively close to the kinked solution branch, but convergence from the lower boundary layer onto this branch is distinctly
slow. Variations in the Plateau border number density (non-zero n and h) increase individual Plateau border areas relative to the case of uniformly sized bubbles. For strong decelerations and negligible
capillarity, solutions closely follow the kinked solution branch if bubble sizes are only slightly non-uniform. As the extent
of non-uniformity increases, the Plateau border area reaches a maximum corresponding to no net upward velocity of foam liquid.
In the case of vertical variation of number density, liquid content profiles and Plateau border area profiles cease to be
simply proportional to one another. Plateau border areas match at the top of the foam independent of h, implying a considerable difference in liquid content for foams which exhibit different number density profiles.
Received 3 July 2001 相似文献
A new class of hydrogels made from poly(vinyl alcohol) (PVA) and amino acid was formed into porous tissue engineering scaffolds by the colloidal gas aphron (CGA) method. CGA microfoams are formed using high speed stirring to generate uniform, micrometer scale bubbles. CGAs offer several advantages over conventional scaffold fabrication techniques including room temperature processing, aqueous conditions and utilization of air bubbles to create uniform pores. This technique eliminates the need for toxic solvents and salt templates. In addition, the novel poly(vinyl alcohol) hydrogels are inherently strong, eliminating the need for crosslinkers. 相似文献
In aqueous systems, partially hydrophobic particles are known to stabilize foams even in the absence of any added surfactant. This paper shows that the same principle can be applied to polymeric systems: particles that are partially wetted by a polymer melt can stabilize a foam of that polymer. The foam stability is attributable to the adsorption of the particles at the air/polymer interface. Remarkably, stable foams are realized even from polymers that are liquid at room temperature, and hence are otherwise unfoamable. The implications of this result to practical foaming operations are discussed.