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341.
Foam drainage is considered in a froth flotation cell. Air flow through the foam is described by a simple two-dimensional deceleration flow, modelling the foam spilling over a weir. Foam microstructure is given in terms of the number of channels (Plateau borders) per unit area, which scales as the inverse square of bubble size. The Plateau border number density decreases with height in the foam, and also decreases horizontally as the weir is approached. Foam drainage equations, applicable in the dry foam limit, are described. These can be used to determine the average cross-sectional area of a Plateau border, denoted A, as a function of position in the foam. Quasi-one-dimensional solutions are available in which A only varies vertically, in spite of the two-dimensional nature of the air flow and Plateau border number density fields. For such situations the liquid drainage relative to the air flow is purely vertical. The parametric behaviour of the system is investigated with respect to a number of dimensionless parameters: K (the strength of capillary suction relative to gravity), α (the deceleration of the air flow), and n and h (respectively, the horizontal and vertical variations of the Plateau border number density). The parameter K is small, implying the existence of boundary layer solutions: capillary suction is negligible except in thin layers near the bottom boundary. The boundary layer thickness (when converted back to dimensional variables) is independent of the height of the foam. The deceleration parameter α affects the Plateau border area on the top boundary: weaker decelerations give larger Plateau border areas at the surface. For weak decelerations, there is rapid convergence of the boundary layer solutions at the bottom onto ones with negligible capillary suction higher up. For strong decelerations, two branches of solutions for A are possible in the K = 0 limit: one is smooth, and the other has a distinct kink. The full system, with small but non-zero capillary suction, lies relatively close to the kinked solution branch, but convergence from the lower boundary layer onto this branch is distinctly slow. Variations in the Plateau border number density (non-zero n and h) increase individual Plateau border areas relative to the case of uniformly sized bubbles. For strong decelerations and negligible capillarity, solutions closely follow the kinked solution branch if bubble sizes are only slightly non-uniform. As the extent of non-uniformity increases, the Plateau border area reaches a maximum corresponding to no net upward velocity of foam liquid. In the case of vertical variation of number density, liquid content profiles and Plateau border area profiles cease to be simply proportional to one another. Plateau border areas match at the top of the foam independent of h, implying a considerable difference in liquid content for foams which exhibit different number density profiles. Received 3 July 2001  相似文献   
342.
    
A regular Kelvin foam model was used to predict the linear thermal expansion coefficient and bulk modulus of crosslinked, closed‐cell, low‐density polyethylene (LDPE) foams from the polymer and gas properties. The materials used for the experimental measurements were crosslinked, had a uniform cell size, and were nearly isotropic. Young's modulus of biaxially oriented polyethylene was used for modeling the cell faces. The model underestimated the foam linear thermal expansion coefficient because it assumed that the cell faces were flat. However, scanning electron microscopy showed that some cell faces were crumpled as a result of foam processing. The measured bulk modulus, which was considerably smaller than the theoretical value, was used to estimate the linear thermal expansion coefficient of the LDPE foams. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3741–3749, 2004  相似文献   
343.
    
A new class of hydrogels made from poly(vinyl alcohol) (PVA) and amino acid was formed into porous tissue engineering scaffolds by the colloidal gas aphron (CGA) method. CGA microfoams are formed using high speed stirring to generate uniform, micrometer scale bubbles. CGAs offer several advantages over conventional scaffold fabrication techniques including room temperature processing, aqueous conditions and utilization of air bubbles to create uniform pores. This technique eliminates the need for toxic solvents and salt templates. In addition, the novel poly(vinyl alcohol) hydrogels are inherently strong, eliminating the need for crosslinkers.  相似文献   
344.
  总被引:2,自引:0,他引:2  
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345.
    
A constitutive model for evaluating the compressive behavior of Poly(methyl‐methacrylate) (PMMA) open‐cell foams is herein proposed. Specifically, the study investigates the viscoelastic and viscoplastic behaviors of the PMMA open‐cell foams. The constitutive equation is expressed in terms of the following polymer and foam properties: elastic modulus, relative density, as well as the relaxation and densification constants. PMMA open‐cell foams are manufactured using a gas foaming/particulate leaching method and uniaxial compression tests are performed. The mechanical properties and compressive stress‐strain responses obtained from the experiments are compared with those predicted by the proposed constitutive model. The results suggest that the constitutive model is an apt one for assessing and evaluating the compressive behaviors of PMMA open‐cell foams. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 436–443, 2007  相似文献   
346.
    
We report the development of highly chemically crosslinked, ultra low density (~0.015 g/cc) polyurethane shape memory foams synthesized from symmetrical, low molecular weight, and branched hydroxyl monomers. Sharp single glass transitions (Tg) customizable in the functional range of 45–70 °C were achieved. Thermomechanical testing confirmed shape memory behavior with 97–98% shape recovery over repeated cycles, a glassy storage modulus of 200–300 kPa, and recovery stresses of 5–15 kPa. Shape holding tests under constrained storage above the Tg showed stable shape memory. A high volume expansion of up to 70 times was seen on actuation of these foams from a fully compressed state. Low in vitro cell activation induced by the foam compared with controls demonstrates low acute bio‐reactivity. We believe these porous polymeric scaffolds constitute an important class of novel smart biomaterials with multiple potential applications. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012  相似文献   
347.
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349.
    
Highly porous elastomeric nanocomposites were successfully synthesized through copolymerization of 2‐ethylhexyl acrylate (EHA), divinyl benzene (DVB), and up to 9 mol % of a polyhedral oligomeric silsesquioxane bearing one propylmethacryl group and seven cyclohexyl groups (MACH‐POSS) within the external phase of high internal phase emulsions (HIPE). The chemical structures, morphologies, thermal properties, and mechanical properties of the polyHIPE were investigated. The mechanical loss peak temperature and full width at half maximum increased with increasing MACH‐POSS content. These changes indicate that copolymerization with MACH‐POSS limits segmental mobility and produces compositional distributions on the nanometer scale. At 9 mol % MACH‐POSS, the reduction in segmental mobility produced a glass transition temperature above room temperature and a significant increase in modulus that can be ascribed to the relatively glassy nature of the polymer. Inorganic monoliths with porosities of around 86%, O/Si of about 1.6, and less than 10% carbon were produced on pyrolysis of the nanocomposite polyHIPE. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2357–2366, 2008  相似文献   
350.
    
In aqueous systems, partially hydrophobic particles are known to stabilize foams even in the absence of any added surfactant. This paper shows that the same principle can be applied to polymeric systems: particles that are partially wetted by a polymer melt can stabilize a foam of that polymer. The foam stability is attributable to the adsorption of the particles at the air/polymer interface. Remarkably, stable foams are realized even from polymers that are liquid at room temperature, and hence are otherwise unfoamable. The implications of this result to practical foaming operations are discussed.

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