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11.
Structural characterisation of such bio-objects as fibrinogen solution, yeast cells, wheat seeds and bone tissues has been done using two versions of cryoporometry based on the integral Gibbs-Thomson (IGT) equation for freezing point depression of pore liquids and the measurements by 1H NMR spectroscopy (180-200 < T < 273 K) and the thermally stimulated depolarisation current (TSDC) method (90 < T < 273 K) of structured water. The IGT equation was solved using a self-consisting regularization procedure including the maximum entropy principle applied to the distribution function of pore size (PSD). Both methods give clear pictures of changes in the structural characteristics caused, e.g., by hydration and swelling of wheat seeds and yeast cells, coagulation and interaction of fibrinogen with solid nanoparticles in the aqueous media, and the human bone tissue disease. 相似文献
12.
Electronic properties of model quantum-dot structures in zero and finite magnetic fields 总被引:1,自引:0,他引:1
H. Saarikoski E. Räsänen S. Siljamäki A. Harju M.J. Puska R.M. Nieminen 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(2):241-252
We have computed electronic structures and total energies of circularly confined two-dimensional quantum dots and their lateral
dimers in zero and finite uniform external magnetic fields using different theoretical schemes: the spin-density-functional
theory (SDFT), the current-and-spin-density-functional theory (CSDFT), and the variational quantum Monte Carlo (VMC) method.
The SDFT and CSDFT calculations employ a recently-developed, symmetry-unrestricted real-space algorithm allowing solutions
which break the spin symmetry. Results obtained for a six-electron dot in the weak confinement limit and in zero magnetic
field as well as in a moderate confinement and in finite magnetic fields enable us to draw conclusions about the reliability
of the more approximative SDFT and CSDFT schemes in comparison with the VMC method. The same is true for results obtained
for the two-electron quantum dot dimer as a function of inter-dot distance. The structure and role of the symmetry-breaking
solutions appearing in the SDFT and CSDFT calculations for the above systems are discussed.
Received 16 October 2001 and Received in final form 17 January 2002 相似文献
13.
Pirjo Sainio Irma Mäkinen Jaap-Willem Hutter Theo den Ouden Mikael Krysell 《Accreditation and quality assurance》2006,11(3):116-121
The international joint project HYCREF (Contract No. G6RD-CT-2002-00854), funded by the European Commission in the 5th Framework programme, aimed to develop methods to prepare homogeneous and stable reference materials of water, soil, and waste contaminated with mineral oil hydrocarbons and to certify the mineral oil content by gas chromatographic methods. The results of a feasibility study for the preparation of three soil reference materials are discussed in this paper, and for the preparation of three waste reference materials in the second part (Koch et al., Accred Qual Assur submitted for publication). The soil materials were selected to represent different soil types and contamination levels. The project plan set three requirements for these reference materials: uncertainty in the mineral oil content resulting from the certification exercise <5%, a sample inhomogeneity of <3% and a minimum long-term stability of 5 years. For the most part, these requirements were met within this project. 相似文献
14.
Akhlesh Lakhtakia 《Optik》2004,115(4):151-158
15.
E. A. El-Amri M. I. Al-Jarallah F. Abu-Jarad Fazal-ur-Rehman 《Radiation measurements》2003,36(1-6):453-456
The uniformity in radon exhalation rates for 46 tiles of granite, marble and ceramic used as construction materials were determined using “Can Technique” employing CR-39 nuclear track detectors (NTDs). On each tile, two sealed cans, each enclosing one NTD fixed at the center of the tile surface area covered by the can, were mounted at two different locations of each individual tiles. The track production rates on the NTDs representing radon exhalation rates were measured. The radon exhalation rates from the surface of individual tiles showed uniform exhalations within the calculated uncertainties of the measured values. This makes Can Technique an alternative simple method to measure radon exhalation rates. Calibration required to convert track production rates into radon exhalation rates for the used can and NTD was done using an active technique. The correlation between the measurements by the two techniques shows a good linear correlation coefficient (0.83). 相似文献
16.
17.
C. Bréchignac Ph. Cahuzac F. Carlier C. Colliex M. de Frutos N. Kébaïli J. Le Roux A. Masson B. Yoon 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):265-268
We studied shape relaxation of nano-fractal islands,
during annealing, after their growth from antimony cluster
deposition on graphite surface. Annealing at
180°C shows evidence of an increase
of the fractal branch width with time followed by branch
fragmentation, without changing the fractal dimension. The time
evolution of the width of the arm suggests the surface
self-diffusion mechanism as the main relaxation process. With
Monte Carlo simulations, we confirmed the observed behavior.
Comparison is done with our previous results on fragmentation of
nano-fractal silver islands when impurity added to the incident
cluster promotes rapid fragmentation by surface self-diffusion
enhancement [1]. 相似文献
18.
E. S. Dy H. Kasai 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(2):241-245
We study the interaction between tin(II) porphyrin (SnPor) with platinum and
non-precious Group 8B metals (iron, cobalt and nickel) by density functional
theory and discuss the electronic properties of the resulting products. We
also model the interaction of the resulting compounds with water where
applicable. Our studies indicate that, SnPor-Ni possesses electronic
properties similar to SnPor-Pt, suggesting that it may possess similar
photocatalytic properties for reduction reactions, such as converting water
to hydrogen gas. 相似文献
19.
20.
用射频磁控溅射结合传统退火的方法制备LiCo0.8M0.2O2 (M=Ni,Zr)阴极薄膜.X射线衍射、拉曼光谱、扫描电子显微镜等手段表征了不同掺杂的LiCo0.8M0.2O2薄膜.结果显示,700℃退火的LiCo0.8M0.2O2薄膜具有类似α-NaFeO2的层状结构.通过对不同掺杂锂钴氧阴极的全固态薄膜锂电池Li/LiPON/LiCo0.8M0.2O2的电化学性能研究表明,电化学活性元素Ni的掺杂使全固态电池具有更大的放电容量(56μAh/cm2μm),而非电化学活性元素Zr的掺杂使全固态电池具有更好的循环稳定性. 相似文献