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51.
Francisco‐Javier Sayas 《Numerical Methods for Partial Differential Equations》2003,19(5):555-570
This article presents and analyzes a simple method for the exterior Laplace equation through the coupling of finite and boundary element methods. The main novelty is the use of a smooth parametric artificial boundary where boundary elements fit without effort together with a straight approximate triangulation in the bounded area, with the coupling done only in nodes. A numerically integrated version of the algorithm is also analyzed. Finally, an isoparametric variant with higher order is proposed. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 555–570, 2003 相似文献
52.
53.
现代热力学的完整分类系统--非平衡非耗散热力学新领域 总被引:1,自引:0,他引:1
在同一体系中同时有多个不可逆过程时,不可逆过程之间会有相互影响,原来的非自发过程有可能在其他自发过程的影响下得以进行,这种现象就称为热力学耦合或反应耦合,长期以来,经典热力学把热力学第二定律的等式作为平衡体系的充分必要条件,其中隐含了一个前提性的假定,即经典热力学的对象只限于非耦合的体系,摈弃这一隐含的前提性假定以后,热力学自身就发展成为一个现代热力学的完整学术体系,适用于任何宏观体系(包括极其复杂的生命体系),现代热力学的完整学术体系中包含了一个崭新的非平衡非耗散热力学新领域,由于该领域属于热力学第二定律的等式部分,因此可以定量计算,并得到一系列理论计算的非平衡相图,与文献上报道的激尖低压金刚石合成等的大量实验数据相符。 相似文献
54.
Jiangen Huang Guiqin Zhang Yuanhe Huang Decai Fang Deqing Zhang 《Journal of magnetism and magnetic materials》2006
A one-dimensional (1D) silver (I) complex of nitronyl nitroxide with fairly strong antiferromagnetic interaction, in which the metal ions are diamagnetic, is investigated by means of the ab initio crystal orbital method based on the density functional theory. The calculated values of the magnetic coupling constant (J) are close to the experimental measured J value in the periodic system. The magneto-structural correlation reveals that the existence of an antiferromagnetic coupling pathway along nitronyl nitroxide units via silver (I) ion in this system. The spin population distribution also shows the existence of spin delocalization along the ONCNO–Ag–ONCNO, which affords a rational interpretation for the antiferromagnetic interaction mechanism. 相似文献
55.
Arata Yajima Ayumi Yamaguchi Fumihiro Saitou Tomoo Nukada Goro Yabuta 《Tetrahedron》2007,63(5):1080-1084
A convergent synthetic strategy for abietane diterpenoids via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated cyclization reactions is established. Asymmetric total synthesis of 12-deoxyroyleanone, an antileishmanial diterpene, is described. 相似文献
56.
57.
Adriana Tudose 《Tetrahedron letters》2006,47(48):8529-8533
Simple catalysts formed in situ from palladium acetate and a variety of imidazolium and imidazolinium carboxylates and dithiocarboxylates have been screened in the coupling of aryl halides with trans-2-phenylvinylboronic acid. Imidazol(in)ium carboxylates show an excellent activity, which compares to that displayed by the parent imidazol(in)ium chlorides, whereas imidazol(in)ium dithiocarboxylates are poorly efficient. Interestingly, the base employed exerts a profound influence on the trans/cis stereochemistry of the coupling product. 相似文献
58.
DIELECTRIC EFFECT ON THE RADIO-FREQUENCY CHARACTERISTICS OF A RECTANGULAR WAVEGUIDE GRATING TRAVELING WAVE TUBE 总被引:2,自引:0,他引:2
Zhigang Lu Yubin Gong Yanyu Wei Wenxiang Wang 《International Journal of Infrared and Millimeter Waves》2006,27(8):1095-1108
A new type of partial-dielectric-loaded rectangular waveguide grating slow-wave structure (SWS) for millimeter wave traveling
wave tube (TWT) is presented in this paper. The radio-frequency characteristics including the dispersion properties, the longitudinal
electric field distribution and the beam-wave coupling impedance of this structure are analyzed. The results show that the
dispersion of the rectangular waveguide grating circuit is weakened, the phase velocity is reduced and the position of the
maximum E
z
is basically invariant after partially filling the dielectric materials in the rectangular waveguide grating SWS. Although
the coupling impedance decreases a little, it still keeps above 40 Ω. 相似文献
59.
60.
Hiroki Shigehisa 《Tetrahedron letters》2006,47(41):7301-7306
The first total synthesis of a spiro-isoquinoline alkaloid, (±)-annosqualine, was established by employing an enamide-phenol coupling of a 1-methylene-1,2,3,4-tetrahydroisoquinoline derivative with a hypervalent iodine reagent, where the formation of the phenoxide was recognized to be an essential step for the reaction of the phenolic hydroxyl group with the hypervalent iodine reagent leading to the formation of the desired product. 相似文献