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51.
Yoshinobu Kamishima 《Annals of Global Analysis and Geometry》1994,12(1):261-289
A strictly pseudoconvex pseudo-Hermitian manifoldM admits a canonical Lorentz metric as well as a canonical Riemannian metric. Using these metrics, we can define a curvaturelike function onM. AsM supports a contact form, there exists a characteristic vector field dual to the contact structure. If induces a local one-parameter group ofCR transformations, then a strictly pseudoconvex pseudo-Hermitian manifoldM is said to be a standard pseudo-Hermitian manifold. We study topological and geometric properties of standard pseudo-Hermitian manifolds of positive curvature or of nonpositive curvature . By the definition, standard pseudo-Hermitian manifolds are calledK-contact manifolds by Sasaki. In particular, standard pseudo-Hermitian manifolds of constant curvature turn out to be Sasakian space forms. It is well known that a conformally flat manifold contains a class of Riemannian manifolds of constant curvature. A sphericalCR manifold is aCR manifold whose Chern-Moser curvature form vanishes (equivalently, Weyl pseudo-conformal curvature tensor vanishes). In contrast, it is emphasized that a sphericalCR manifold contains a class of standard pseudo-Hermitian manifolds of constant curvature (i.e., Sasakian space forms). We shall classify those compact Sasakian space forms. When 0, standard pseudo-Hermitian closed aspherical manifolds are shown to be Seifert fiber spaces. We consider a deformation of standard pseudo-Hermitian structure preserving a sphericalCR structure.Dedicated to Professor Sasao Seiya for his sixtieth birthday 相似文献
52.
A.K. Tashmukhamedova I.A. Stempnevskaya 《Journal of inclusion phenomena and macrocyclic chemistry》1998,30(2):91-98
The effect of the nature of the substituent in the monosubstituted derivatives of dibenzo-18-crown-6 on the reactivity and direction of the electrophilic substitution reaction of the unsubstituted benzene ring has been determined. This transfer is carried out via the macrocycle and therefore is called transannular transmission. The possible mechanism of this transmission is discussed. 相似文献
53.
The effect of geometry modifications of13C chemical shifts has been investigated in a small subset of molecules using both LO-INDO and Gaussian 70 (4–31) calculations. The Gaussian calculations, while known to give poor absolute shifts, compare well to the reparameterized semi-empirical INDO determinations in calculated shift changes. In virtually all cases the signs of the shift changes were found to be opposite to that of the changes in the calculated electronic energy. 相似文献
54.
The behavior of hexafluoroacetone ethoxycarbonylimine in cyclocondensation with different binucleophiles of the amidine type, viz., amino derivatives of N- and N,S-heterocycles, was studied. A preparative method for the synthesis of previously unknown annelated 2,2-bis(trifluoromethyl)-1,3,5-triazinones was developed. 相似文献
55.
56.
根据在自由基引发剂存在下,8,9-苯并-2-亚甲基-1,4,6-三氧螺(4,4)壬烷(Ⅰ)可能存在的竞争反应,推导了动力学方程式。用红外光谱法测定了单体的消失速率和苯酞的生成速率。实验结果与推导动力学方程式相符。进一步证明了单体(Ⅰ)的增长反应由加成聚合和开环—异构化—加成这两个反应组成。这两个反应对总速率的相对贡献与单体浓度有关。得到了共聚物的结构。 相似文献
57.
Gengliang Yang Zhiwei Li Dexian Wang Zhefeng Zhang Erdong Liu Yi Chen 《Chromatographia》2002,56(7-8):515-518
Summary A high-performance liquid chromatographic method was developed for the chiral separation of a new anti-diabetic agent, N-(trans-4-isopropylcyclohexylcarbonyl)-D-phenylalanine,
and its L-enantiomer. The separation was performed on a Sumichiral OA-3300 column. Optimized mobile phase was 0.025 mol.L−1 ammonium acetate in methanol solution. UV detection was at 210 nm. Baseline chiral separation was obtained within 12 minutes.
The detection limits are 80 pg for the D-enantiomer and 120 pg for the L-enantiomer. RSD of the method was below 1% (n=5). 相似文献
58.
Joan Fraga-DubreuilJean Pierre Bazureau 《Tetrahedron》2003,59(32):6121-6130
The first report of the use of task-specific ionic liquid as synthetic equivalent of ionic liquid-phase matrice for the preparation of a small library of 4-thiazolidinones is reported in this paper. The starting (ethyleneglycol)ionic liquid-phase is functionalized in good yields with 4-(formylphenoxy)butyric acid by using usual esterification reaction conditions (DCC/DMAP as catalyst). The synthesis of the ionic liquid-phase bound 4-thiazolidinones was performed by a one-pot three-component condensation under microwave dielectric heating. The final cleavage under microwave/catalysis strategy provides the expected 4-thiazolidinones in high purity after flash-chromatography purification. According to the ionic liquid-phase organic synthesis (IoLiPOS) methodology, it was found that optimized reaction conditions were performed by standard analytical methods (NMR, TLC). The 1H, 13C NMR spectrum of some representative 4-thiazolidinones and ionic liquid-phase bound benzaldehyde are also reported. 相似文献
59.
Friedrich Bossert Horst Meyer Egbert Wehinger 《Angewandte Chemie (International ed. in English)》1981,20(9):762-769
The aryldihydropyridines first prepared by Hantzsch almost 100 years ago have recently been found to be highly effective calcium antagonists with suitable pharmacological profiles. An illustrative example is dimethyl-l,4-dihydro-2,6-dimethyl-4-(o-nitrophenyl)pyridine-3,5-dicarboxylate (Nifedipine) which is already employed therapeutically. This substance lowers the frequency of attack of angina pectoris and reduces blood pressure. The discovery of the therapeutic activity of this class of substances initiated renewed investigation of the Hantzsch condensation and the synthesis of numerous 4-aryldihydropyridines and related compounds. Qualitative and quantitative structure/activity relationships of these substances can be deduced from their biological data. 相似文献
60.
JIANG Qi-Jun 《结构化学》2005,24(10):1140-1144
1 INTRODUCTION The electron-transfer reaction of C60 derivatives, especially light-induced electron-transfer reaction, has been an active research field for a long time. Many researches are focused on the long-live charge- separated state caused by electron-transfer[1]. And several electron-transfers between electron donor and C60 or intramolecular electron-transfer have been confirmed. As an example, TTF-C60 is proved to be a short-live charge-separated compound[2].Due to the excelle… 相似文献