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21.
Sharma D 《Colloids and surfaces. B, Biointerfaces》2011,88(2):610-613
There has been a keen interest for developing a biologically friendly approach for the preparation of silver nanoparticles for their application reasons. A biocompatible, single step method is established for the preparation of silver nanoparticles in lecithin (Egg phosphatidylcholine)/water systems where lecithin itself acts as a reductant for silver nitrate to form the silver nanoparticles. In another attempt, silver nanoparticles were successfully synthesized inside the lecithin vesicles and were found attached to the bilayers of lecithin vesicles. To the best of our knowledge, this is the first report where a biological surfactant has acted as a mild reducing agent for silver nitrate by itself to form silver nanoparticles. 相似文献
22.
Jelly-like phases formed by mixtures of soybean lecithin with pure n-dodecyl-β-D-glucopyranoside (DDPG), commercial alkylpoly-glucoside (APG) or n-dodecyl-β-D-lactobionamide (DLBA) in decane in the presence of small amounts of water were studied by oscillating rheology and FT-IR-spectroscopy.
It was established that the sugar derivatives can modify the rheological properties of lecithin organogels in different ways.
The viscosities, the structural relaxation times and the shear moduli decrease with increasing content of DDPG, while the
same parameters increase for DLBA. For APG the modulus is increasing while the viscosity and the structural relaxation time
are decreasing. By means of FT-IR spectroscopy and examination of the Cole–Cole-plots of the loss modulus vs. the storage
modulus it was shown that the sugar derivatives influence both the strength of the hydrogen bonds between the molecules in
the polymer-like micelles and the micellar dynamics.
Received: 10 November 1997 Accepted: 11 December 1997 相似文献
23.
Zusammenfassung In dieser Arbeit wird ein zweidimensionales Modell für das Kettenschmelzen bei der Hauptumwandlung in Lipid-Doppelschichten vorgestellt. Neben dem gestreckten Zustand sind nur Konformationen mit 2g2-Kinken zugelassen, die kompakte Kinkblöcke formieren.
Summary A two-dimensional lattice model for the chain melting transition in lipid bilayer was built on the assumption that the only non-straight hydrocarbon chain conformations allowed are 2g2-kinks organized in compact blocks.相似文献
24.
《Analytical letters》2012,45(8):629-643
Abstract Two copper ores (containing between 1% and 2% of the metal) were analyzed by UV emission spectroscopy, infrared spectroscopy and X-ray diffraction yielding - per se - inconclusive results. The ores were subsequently classified by particle size into three “granular fractions”. Determination of copper, dissolved from each fraction by anaerobic and aerobic digestion with 5% aqueous sulphuric acid, produced illuminating information on the presence of sulfide-and oxide-type copper compounds. Fractionation was further refined by magnetic separations. 相似文献
25.
Kaname Hashizaki Takashi Chiba Hiroyuki Taguchi Yoshihiro Saito 《Colloid and polymer science》2009,287(8):927-932
While lecithin alone can form spherical or ellipsoidal reverse micelles in oil, we found that urea can promote the growth
of lecithin reverse worm-like micelles in oil. In a mixed system of urea and lecithin, the urea binds to the phosphate group
of lecithin, thus reducing the interface curvature of the molecular assembly and inducing the formation of reverse worm-like
micelles. The regions in which these micelles form increased with lecithin concentration. In addition, the zero-shear viscosity
(η
0) of the reverse worm-like micelles rapidly increased upon the addition of urea, reaching a maximum of 2 million times the
viscosity of n-decane. We examined the change in η
0 in detail by performing dynamic viscoelasticity measurements. Values for η
0 increased with urea concentration because the disentanglement time of reverse worm-like micelles increased with micellar
growth. 相似文献
26.
Lecithin-adsorbed magnetic nanoparticles were prepared by three-step process that the thermal decomposition was combined with ultrasonication. Experimental parameters were three items—molar ratio between Fe(CO)5 and oleic acid, keeping time at decomposition temperature and lecithin concentration. As the molar ratio between Fe(CO)5 and oleic acid, and keeping time at decomposition temperature increased, the particle size increased. However, the change of lecithin concentration did not show the remarkable particle size variation. 相似文献
27.
Magnetic nanoparticles were prepared by thermal decomposition and adsorbed with lecithin by applying ultrasonication. The size and saturation magnetization changes of magnetic nanoparticles were observed with different lecithin concentration, and the maximum tolerated dose (MTD) and toxicity of magnetic fluid was investigated through a biological test. As the added lecithin concentration increased in a weight loss test by heating of magnetic particles, the thickness of lecithin-adsorption layer increased non-linearly, and the proper adsorption amount was observed in the lecithin concentration of 20% (w/v). The dispersibility and magnetic property of lecithin-adsorbed magnetic nanoparticles was the most excellent when the ultrasonic holding time was 1.5 h. Also, the maximum tolerated concentration with best cell viability was 32 μg/ml by in vitro test, and lecithin-adsorbed magnetic fluids showed the improved biocompatibility by 1.2 times compared with pure magnetite magnetic fluids. 相似文献
28.
Blanca Sesta Alessandro D''Aprano 《Colloids and surfaces. A, Physicochemical and engineering aspects》1998,140(1-3):119-126
The ionic flux of Na+ K+ ions across monoolein and lecithin bilayers, separating two aqueous electrolyte solutions, has been measured in the presence of 5-decyl-4,7,13,16,21-pentaoxa-1,10-diazabicyclo-(8,8,5)-tricosane, 5-decyl-4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8,8,8)-hexacosane and their parent compounds 4,7,13,16,21-pentaoxa-1,10-diazabicyclo(8,8,5)-tricosane, 4,7,13,16,21,24-hexaoxa-1,10-diaza-bicyclo-(8,8,8)-hexacosane. Under the effects of an electric field, a significant increase of the membrane conductance, proportional to the macrocycle and/or to the electrolyte concentration, was observed. In spite of the high ion selectivity of both classes of cryptands, related to the different stability constants of the metal ion–macrobicyclic receptor complexes, alkyl cryptands show a greater efficiency to activate the ion transport across the lipid membranes than their parent compounds. Such a result has been explained taking into account the different hydrophobicity of the macrobicyclic compounds. Information on the ionic mobility and on the diffusion coefficient of the ionic species moving across the membrane have been obtained analyzing the experimental data in terms of the carrier mechanism based on the Eyring theory. 相似文献
29.
J. Y-K. Hsieh J. G. Turcotte J. Waraska D. Warburton W. Oh 《Journal of separation science》1980,3(8):400-404
A method for the HPLC separation of phosphatidylglycerol (PG), phosphatidylinositol (PI), phosphatidylcholine (PC), and sphingomyelin (SPH) was achieved using five in-series columns packed with LiChrosorb, Partisil, and μ-Porasil adsorbents, a solvent mixture of chloroform/methanol/ammonium hydroxide (50 : 36 : 6.7, by volume), and a Pye LCM2 Moving Wire (FID) detector. The same phospholipid mixture was also separated using four μ-Porasil columns with the same eluent and detector. The latter conditions were found to be suitable for the analysis of phospholipids obtained after centrifuging, extraction, and precipitation of surface-active lipid components of patient amniotic fluid collected at amniocentesis section. The lecithin/sphingomyelin (L/S) ratios, determined by the HPLC method, correlated well with those determined by the TLC technique in four normal pregnancies, whereas results of shake tests did not correlate too well with L/S ratios determined by the above two chromatographic methods. Besides the lecithin/sphingomyelin ratio, the present method was able to supply additional information: the concentrations of phosphatidylglycerol and phosphatidylinositol, for prediction of fetal lung maturity, and the palmitic acid content of amniotic fluid phosphatidylcholine. 相似文献
30.