全文获取类型
收费全文 | 1975篇 |
免费 | 69篇 |
国内免费 | 81篇 |
专业分类
化学 | 1670篇 |
晶体学 | 12篇 |
力学 | 1篇 |
综合类 | 1篇 |
数学 | 20篇 |
物理学 | 421篇 |
出版年
2024年 | 1篇 |
2023年 | 21篇 |
2022年 | 27篇 |
2021年 | 24篇 |
2020年 | 34篇 |
2019年 | 28篇 |
2018年 | 23篇 |
2017年 | 36篇 |
2016年 | 44篇 |
2015年 | 52篇 |
2014年 | 43篇 |
2013年 | 93篇 |
2012年 | 180篇 |
2011年 | 137篇 |
2010年 | 76篇 |
2009年 | 114篇 |
2008年 | 108篇 |
2007年 | 147篇 |
2006年 | 127篇 |
2005年 | 112篇 |
2004年 | 112篇 |
2003年 | 89篇 |
2002年 | 59篇 |
2001年 | 46篇 |
2000年 | 57篇 |
1999年 | 56篇 |
1998年 | 67篇 |
1997年 | 36篇 |
1996年 | 37篇 |
1995年 | 28篇 |
1994年 | 21篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 25篇 |
1990年 | 21篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有2125条查询结果,搜索用时 93 毫秒
41.
E. D. Matveeva T. A. Podrugina M. V. Prisyazhnoi I. N. Rusetskaya N. S. Zefirov 《Russian Chemical Bulletin》2007,56(4):798-805
Interaction of aliphatic and aromatic aldehydes and ketones with optically active L-α-amino acids or their esters in the three-component catalytic one-pot synthesis of α-aminophosphonates was studied. The
corresponding α-amino phosphonates are formed in high yields as mixtures of diastereomers.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 768–774, April, 2007. 相似文献
42.
A sensitive cathodic stripping voltammetric method is developed for determination of lead(II), with adsorptive collection of complexes with Pyrogallol red (PGR) on to a hanging mercury drop electrode. After accumulation of the complex at −0.80 V vs. Ag/AgCl reference electrode, the potential is scanned in a negative direction from −0.20 to −0.50 V with differential pulse method. Then the reduction peak current for the lead(II)-PGR complex is measured at −0.39 V. The influence of reagent and instrumental variables was completely studied by factorial design analysis. The optimum analytical conditions for the determination of lead(II) were established. Under optimum conditions, lead(II) determined in the range of 0.1-30.0 ng ml−1 with a limit of detection of 0.06 ng ml−1. The method is successfully applied to determination of lead(II) in water sample. 相似文献
43.
Pb8FeIIFeF24 is triclinic: a = 20.118(3) Å, b = 5.597(1) Å, c = 9.440(2) Å, α = 89.75(2)°, β = 105.79(2)°, α = 89.38(2)°, Z = 2. The structure is solved in the unconventional space group C1 , from X-ray single crystal data using 1 641 independent reflections (R = 0.048, Rw = 0.051). It is built up from the stacking of two subnetworks along the a axis: fluorite-like [Pb8F10]n6n+ layers and infinite dimetallic [FeIIFeF14]n6n? double-chains of corner-sharing octahedra running along the b axis. 相似文献
44.
Electrodeposition of fluorine-doped lead dioxide 总被引:3,自引:0,他引:3
The electrocatalytic properties of PbO2 may be increased by incorporation of some ions such as F−. In this review, the preparation of fluorine-doped PbO2 in the presence of some additives of fluorine-containing compounds (F−, potassium salt of nonafluoro-1-butanesulfonic acid C4F9O3SK and Nafion®) is reported. The mechanism of electrodeposition is discussed. The amount of additives in the deposit depends on the experimental conditions: potential, current density and charge of additive species in the plating solution. The physicochemical properties of doped oxide are very different from those of undoped oxide, accounting for the different electrocatalytic activity of the materials. 相似文献
46.
This paper reports voltammetric sequential determination of Pt(II), Pd(II), and Rh(III), by square-wave adsorption stripping voltammetry (SWAdSV), and Pb(II), by square-wave anodic stripping voltammetry (SWASV), in vegetable environmental matrices. Analytical procedures were verified by the analysis of the standard reference materials: Olive Leaves BCR-CRM 062 and Tomato Leaves NIST-SRM 1573a. Precision and accuracy, expressed as relative standard deviation and relative error, respectively, were always less than 6% and the limits of detection (LOD) for each element were below 0.096 g g–1. Once set up on the standard reference materials, the analytical procedure was transferred and applied to laurel leaves sampled in proximity to a superhighway and in the Po river mouth area. A critical comparison with spectroscopic measurements is discussed. 相似文献
47.
The presence of trace metals in car fuels plays an important role in the engine maintenance. In addition, these metals contribute for the environmental contamination in big cities and their control is necessary. Square Wave Stripping Voltammetry (SWSV) is a very sensitive technique for elemental trace determination and was applied for ethanol fuel analysis. The first studies were done searching for the best conditions for copper determination in alcoholic medium, utilizing gold electrodes. During these studies, the possibility of the simultaneous determination of copper and lead in the same experiment was observed. Two procedures for the analysis of these metals were adopted: The direct quantification of metals in alcohol–water mixtures and a second way that involves the evaporation of the organic solvent and re-suspension of the ions with water+electrolyte. Good recovery values were obtained for synthetic samples spiked with known amounts of metals. The results obtained for the two methods were in good agreement. The detection limits for copper and lead in 75% ethanol–water ratio solution were calculated as 120 and 235 ng l−1, respectively, for 15-min deposition time. 相似文献
48.
49.
氢化物原子荧光法测定中草药中痕量铅 总被引:30,自引:6,他引:30
提出了以重铬酸钾为氧化剂、碱性铁氰化钾为络合剂 ,在柠檬酸介质中进行铅的氢化物发生反应。采用断续流动氢化物发生器 ,对原子荧光法测定痕量铅的条件进行了系统研究 ,并考察了共存元素的干扰情况。在最佳测试条件下 ,测得铅的检出限 (3σ)为 0 .19μg·L- 1,相对标准偏差为 0 .92 %。应用于中草药中痕量铅的测定 ,回收率为 95 .1%~ 10 9.5 % ,结果满意 相似文献
50.
用溶液聚合法制备出轻度交联的含铅微凝胶,用光子相关光谱技术测定其在良溶剂中与H2S反应前、后的扩散行为,由外推法得到在浓度无限稀时的分子扩散系数,给出微凝胶的流体力学半径。结果表明:相同量的含铅微凝胶在不同的初始浓度下与H2S反应,生成含PbS纳米微粒的凝胶;但其体积增大不同,这说明H2S与含铅微凝胶的反应既可以在分子内也可以在分子间进行,分子间的反应使含硫化铅微凝胶扩散系数随浓度的变化曲线的线性范围变小。 相似文献